全文获取类型
收费全文 | 7229篇 |
免费 | 1138篇 |
国内免费 | 737篇 |
专业分类
化学 | 4832篇 |
晶体学 | 73篇 |
力学 | 425篇 |
综合类 | 42篇 |
数学 | 658篇 |
物理学 | 3074篇 |
出版年
2024年 | 28篇 |
2023年 | 156篇 |
2022年 | 207篇 |
2021年 | 206篇 |
2020年 | 278篇 |
2019年 | 228篇 |
2018年 | 216篇 |
2017年 | 194篇 |
2016年 | 312篇 |
2015年 | 304篇 |
2014年 | 376篇 |
2013年 | 523篇 |
2012年 | 568篇 |
2011年 | 606篇 |
2010年 | 403篇 |
2009年 | 417篇 |
2008年 | 431篇 |
2007年 | 370篇 |
2006年 | 363篇 |
2005年 | 338篇 |
2004年 | 280篇 |
2003年 | 207篇 |
2002年 | 225篇 |
2001年 | 174篇 |
2000年 | 168篇 |
1999年 | 177篇 |
1998年 | 130篇 |
1997年 | 130篇 |
1996年 | 154篇 |
1995年 | 111篇 |
1994年 | 115篇 |
1993年 | 108篇 |
1992年 | 101篇 |
1991年 | 83篇 |
1990年 | 63篇 |
1989年 | 74篇 |
1988年 | 52篇 |
1987年 | 46篇 |
1986年 | 38篇 |
1985年 | 34篇 |
1984年 | 19篇 |
1983年 | 19篇 |
1982年 | 14篇 |
1981年 | 13篇 |
1980年 | 9篇 |
1979年 | 6篇 |
1976年 | 4篇 |
1973年 | 3篇 |
1970年 | 3篇 |
1957年 | 4篇 |
排序方式: 共有9104条查询结果,搜索用时 15 毫秒
111.
A mesoporous template route to the low-temperature preparation of efficient green light emitting Zn2SiO4:Mn phosphors 总被引:1,自引:0,他引:1
Xiong L Shi J Gu J Li L Huang W Gao J Ruan M 《The journal of physical chemistry. B》2005,109(2):731-735
Green light emitting Zn2SiO4:Mn phosphors have been prepared via a low-temperature solid-state reaction using mesoporous silica SBA-15 template. This mesoporous silica template method features low-temperature formation of phosphors and easy doping. The structure and morphology of the phosphors were characterized by XRD, SEM, TEM, and N2 adsorption/desorption techniques, which confirmed the single crystallinity, ordered mesostructure, closed pore channels, and elongated ropelike morphology. The luminescent properties were examined by photoluminescence spectroscopy at room temperature, and the results of fluorescence decay time measurements show non-single-exponential decay behavior and a decrease of the decay time with an increase of the Mn concentration. 相似文献
112.
Joo J Kwon SG Yu T Cho M Lee J Yoon J Hyeon T 《The journal of physical chemistry. B》2005,109(32):15297-15302
A simple method of synthesizing a large quantity of TiO(2) nanorods was developed. A nonhydrolytic sol-gel reaction between titanium(IV) isopropoxide and oleic acid at 270 degrees C generated 3.4 nm (diameter) x 38 nm (length) sized TiO(2) nanocrystals. The transmission electron microscopic image showed that the particles have a uniform diameter distribution. X-ray diffraction and selected-area electron diffraction patterns combined with high-resolution transmission electron microscopic image showed that the TiO(2) nanorods are highly crystalline anatase crystal structure grown along the [001] direction. The diameters of the TiO(2) nanorods were controlled by adding 1-hexadecylamine to the reaction mixture as a cosurfactant. TiO(2) nanorods with average sizes of 2.7 nm x 28 nm, 2.2 nm x 32 nm, and 2.0 nm x 39 nm were obtained using 1, 5, and 10 mmol of 1-hexadecylamine, respectively. The optical absorption spectrum of the TiO(2) nanorods exhibited that the band gap of the nanorods was 3.33 eV at room temperature, which is 130 meV larger than that of bulk anatase (3.2 eV), demonstrating the quantum confinement effect. Oleic acid coordinated on the nanorod surface was removed by the reduction of the carboxyl group of oleic acid, and the Brunauer-Emmett-Teller surface area of the resulting naked TiO(2) nanorods was 198 m(2)/g. The naked TiO(2) nanorods exhibited higher photocatalytic activity than the P-25 photocatalyst for the photocatalytic inactivation of E. coli. 相似文献
113.
Two new ent‐abietane diterpenoids, macrophynin E ( 1 ) and macrophynin F ( 2 ), and a known related ent‐abietanoid (?)‐lambertic acid ( 3 ), together with four known ent‐kauranoids, were isolated from the roots and aerial parts of Isodon macrophylla, respectively. The structures of the new compounds were elucidated on the basis of spectroscopic‐data analysis and chemical correlations. 相似文献
114.
With fluorometry this paper has proved that alpha-cyclodextrin (CD) and gamma-CD do not form inclusion complexes with procaine, while beta-CD and HP-beta-CD do. Their molar ratios are demonstrated both 1:1 with the equimolar variation method. The constant current coulometric titration method (CCCT) is first proposed and applied in the determination of the CD inclusion constant. To compare with this method, the fluorescence experiment has been done with the satisfactory results. 相似文献
115.
Zhonghua Ji Jingjian Li Gu Yuan Shengmin Cai Jia Liu Chang Liu 《Journal of Electroanalytical Chemistry》2004,570(2):265-273
Polyamides containing N-methyl pyrroles and N-methyl imidazoles are a type of small molecule that can bind and recognize the bases of DNA with high affinity and specificity. Five polyamides were studied at glassy carbon electrode in acetate buffer by cyclic and differential pulse voltammetry to clarify their redox pathways. The polyamide electrochemical responses are compared by peak currents and peak potentials. The slopes of the three anodic Ep vs. pH plots of a typical polyamide are linear and show 0.059, 0.057, 0.056 V per pH in acid media, respectively, which correspond to a mechanism involving the equal number of electrons and protons. A possible mechanism for the redox pathway of various polyamides is proposed: the oxidation product of imidazole ring is acylamide and the results of in situ UV–Vis spectroscopy at Pt web electrode support the proposed mechanism. electrospray ionization mass spectroscopy (ESI-MS) indicates that one or two oxygen atoms are added into polyamide molecule after electrochemical oxidation. 相似文献
116.
Gu CHAOHAO 《数学年刊B辑(英文版)》1980,1(2):177-182
如果一个Yang-Mills场(规范群为任意李群)的场强的所有规范导数均为0,则称这个场为平行的Yang-Mills场.平行规范场是微分几何中对称空间的推广,它是Yang-Mills方程的特解.
本文的主要结果是下列两个定理:
定理1 容有非平凡的平行Yang-Mills场的四维黎曼空间必须是Kahler流形或半对称空间.这里半对称流形是满足
\[R_{ijkl}^ - = 0\](或\[R_{ijkl}^ + = 0\])
的黎曼流形,其中\[R_{ijkl}^ \pm \]分别是曲率张量的自对偶部份及反自对偶部份,而":"表示共变
导数.
定理2 半对称空间如果不是对称空向,则必为Kahler-Einstein空间或共形半平坦Einstein空间.这里共形半平坦是指Weyl张量的反自对偶部份或自对偶部份为0.在附录中作者给出了二维黎曼流形上Yang-Mills方程的所有的整体解. 相似文献
117.
Gu X Sun M Gugiu B Hazen S Crabb JW Salomon RG 《The Journal of organic chemistry》2003,68(10):3749-3761
The recent immunological detection of extraordinarily high levels of carboxyethylpyrrole (CEP) modifications of proteins from the retinas of individuals with age-related macular degeneration provided presumptive evidence for the involvement of docosahexaenoate-derived oxidatively truncated phospholipids in retinal pathology. To facilitate the in vivo detection and characterization of the chemistry and biological activities of these postulated naturally occurring molecules, a family of oxidatively truncated phospholipids was prepared by total syntheses. Their formation in oxidation reactions of a docosahexaenoate ester of 2-lysophosphatidylcholine (DHA-PC) was also demonstrated. Free radical-induced oxidative cleavage of DHA-PC promoted by myeloperoxidase or copper ions generates similar mixtures of these phospholipids. The most abundant products were 1-palmitoyl-2-succinoyl-sn-glycero-3-phosphatidylcholine (4.7%) and 2-(6-carboxy-4-oxohex-5-enoyl)-1-palmitoyl-sn-glycero-3-phosphatidylcholine (1.7%). Both of these oxidatively truncated phospholipids are homologues of biologically active arachidonate-derived phospholipids. A minor product from DHA-PC, 2-(4-hydroxy-7-oxohept-5-enoyl)-1-palmitoyl-sn-glycero-3-phosphatidylcholine (0.4% yield), reacted with the epsilon-amino group of a peptide lysyl residue to produce a CEP derivative in 0.7% yield. These observations support the previous conclusion, based on immunological evidence, that CEPs are generated by the reaction of an oxidatively truncated phospholipid with proteins in the retina and further indicate that CEP protein modifications probably represent only a tiny fraction of the products generated upon oxidative damage of DHA-PC in photoreceptor disk membranes. 相似文献
118.
Liu J Zhao YW Zhao JQ Xia AD Jiang LJ Wu S Ma L Dong YQ Gu YH 《Journal of photochemistry and photobiology. B, Biology》2002,68(2-3):156-164
The photophysical and photochemical properties of hypocrellins (HA and HB) are examined with two-photon excitations at 800 nm using femtosecond pulses from a Ti:sapphire laser. The two-photon excited fluorescence spectra of HA and HB are very similar to those obtained by one-photon excitation, which may indicate that the two-photon induced photodynamic processes of hypocrellins are similar to one-photon induced photodynamic processes. The two-photon excitation cross sections of HA and HB are measured at 800 nm as about 34.8 x 10(-50) cm(4) s/photon and 21.3 x 10(-50) cm(4) s/photon, respectively. The large two-photon cross sections of both HA and HB, suggest that the hypocrellins can be potential two-photon phototherapeutic agents. As an example for two-photon photodynamic therapy of hypocrellins, we also further examine the cell-damaging effects of HA upon two-photon illumination. Our preliminary results of cell viability test indicate hypocrellins can effectively damage the Hela cells under two-photon illumination. 相似文献
119.
消旋反式菊酸α—氰基—4—氟—3—苯氧基苄酯的合成 总被引:1,自引:0,他引:1
含氟拟除虫菊酯的合成是近年来新型高效拟除虫菊酯研究工作的方向之一。该类化合物由于具有高效、低毒、广谱、低残留、无致癌、致畸作用,有的还具有低鱼毒,杀螨的特性,因此倍受注目。西德拜尔公司开发的百治菊酯(Baythroid)(1)便是其中一种高效杀虫剂。 相似文献
120.
The dissociation kinetics of metal ions from native metallothionein (Cd5Zn2-MT) of rat liver has been studied in the presence of external ligands including amino acids, peptide and polyamino polycarboxylic acids at 25°C. The study shows that the solution pH affects the metal dissociation process. Different ligands present different multiphasic kinetics. The possible mechanism of metal dissociation from metallothionein has been proposed. 相似文献