首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4541篇
  免费   645篇
  国内免费   381篇
化学   3255篇
晶体学   51篇
力学   236篇
综合类   23篇
数学   526篇
物理学   1476篇
  2024年   7篇
  2023年   109篇
  2022年   171篇
  2021年   183篇
  2020年   164篇
  2019年   146篇
  2018年   140篇
  2017年   108篇
  2016年   200篇
  2015年   205篇
  2014年   247篇
  2013年   279篇
  2012年   346篇
  2011年   386篇
  2010年   237篇
  2009年   234篇
  2008年   281篇
  2007年   258篇
  2006年   235篇
  2005年   200篇
  2004年   170篇
  2003年   152篇
  2002年   127篇
  2001年   103篇
  2000年   90篇
  1999年   114篇
  1998年   100篇
  1997年   90篇
  1996年   90篇
  1995年   78篇
  1994年   54篇
  1993年   33篇
  1992年   37篇
  1991年   32篇
  1990年   23篇
  1989年   17篇
  1988年   20篇
  1987年   19篇
  1986年   13篇
  1985年   9篇
  1984年   15篇
  1983年   4篇
  1982年   4篇
  1981年   3篇
  1980年   9篇
  1978年   2篇
  1976年   7篇
  1975年   3篇
  1974年   2篇
  1972年   2篇
排序方式: 共有5567条查询结果,搜索用时 0 毫秒
91.
In this paper, a class of delayed predator-prey model of prey dispersal in two-patch environments is considered. By analyzing the associated characteristic transcendental equation, its linear stability is investigated and Hopf bifurcation is demonstrated. Some explicit formulae determining the stability and the direction of the Hopf bifurcation periodic solutions bifurcating from Hopf bifurcations are obtained by using the normal form theory and center manifold theory. Some numerical simulation for justifying the theoretical analysis are also provided. Finally, biological explanations and main conclusions are given.  相似文献   
92.
聚乙烯-碘化铯中子阴极的最佳化   总被引:1,自引:1,他引:1  
廖华  张焕文  李冀 《光子学报》1999,28(8):735-739
本文的中子阴级由聚乙烯、导电基底(Al)和碘化铯二次电子发射体组成.文中建立了一个此中子阴级的新的物理模型,并采用Monte Carlo方法模拟了中子同阴极作用产生低能二次电子的物理过程.模拟得到的出射二次电子能谱和产额与实验结果和理论分析符合得较好.我们还得到了最大探测效率时各中子阴极组分的最佳厚度.  相似文献   
93.
用157 nm激光制作的光子晶体光纤法布里-珀罗传感器   总被引:4,自引:2,他引:4  
157nm准分子激光用于微加工具有单光子能量高,峰值功率高,材料吸收系数高,分辨率高等优点。利用157nm激光微加工的方法,在光子晶体光纤上融切出微小矩形孔,从而构成腔长为45.6μm的微光纤法布里-珀罗干涉腔,得到的干涉条纹平滑,衬比度约为26dB,并从激光与石英材料的相互作用上分析了形成较好干涉条纹的原因。把这种微腔应用于应变测量,在550μm范围内,腔长增量相对于应变的灵敏度为0.32nm/μm,线形度达0.9994。实验证明该微腔对温度不敏感,800℃范围内腔长变化仅20nm。157nm准分子激光加工光纤法布里-珀罗腔方法简单,一次成型,具有较高的加工效率和精度,有望实现光纤法布里-珀罗腔的规模化批量制造,具有较好的应用前景。  相似文献   
94.
A differential fiber Bragg grating (FBG) sensor with a free active element bulk-modulus for high-pressure (or displacement) measurement is presented. Based on the differential measurement method and an isosceles triangle cantilever structure, problems of cross-sensitivity and chirped signal in FBG sensor are improved both theoretically and experimentally. Preliminary experiments indicate that temperature-compensated measurement results agree well with the theoretical analysis. Displacement measurement sensitivity is 1.75 pm/μm, and the estimated pressure measurement resolution can reach 0.27 MPa in case the wavelength shift measurement resolution is 0.01 nm.  相似文献   
95.
Liao CK  Li ML  Li PC 《Optics letters》2004,29(21):2506-2508
Optoacoustic imaging takes advantage of high optical contrast and low acoustic scattering and has found several biomedical applications. In the common backward mode a laser beam illuminates the image object, and an acoustic transducer located on the same side as the laser beam detects the optoacoustic signal produced by thermoelastic effects. A cross-sectional image is formed by laterally scanning the laser beam and the transducer. Although the laser beam width is generally narrow to provide good lateral resolution, strong optical scattering in tissue broadens the optical illumination pattern and thus degrades the lateral resolution. To solve this problem, a combination of the synthetic aperture focusing technique with coherence weighting is proposed. This method synthesizes a large aperture by summing properly delayed signals received at different positions. The focusing quality is further improved by using the signal coherence as an image quality index. A phantom comprising hair threads in a 1% milk solution was imaged with an optoacoustic imaging system. The results show that the proposed technique improved lateral resolution by 400-800% and the signal-to-noise ratio by 7-23 dB over conventional techniques.  相似文献   
96.
97.
We present a novel technique to fabricate deeply embedded microelectrodes in LiNbO3 using femtosecond pulsed laser ablation and selective electroless plating. The fabrication process mainly consists of four steps, which are (1) micromachining of microgrooves on the surface of LiNbO3 by femtosecond laser ablation; (2) formation of AgNO3 films on substrates; (3) scanning the femtosecond laser beam in the fabricated microgrooves for modification of the inner surfaces; and (4) electroless copper plating. The void-free electroless copper plating is obtained with appropriate cross section of microgrooves and uniform initiation of the autocatalytic deposition on the inner surface of grooves. The dimension and shape of the microelectrodes could be accurately controlled by changing the conditions of femtosecond laser ablation, which in turn can control the distribution of electric field inside LiNbO3 crystal for various applications, opening up a new approach to fabricate three-dimensional integrated electro-optic devices.  相似文献   
98.
Miao  Meng  Liao  Li-Li  Cao  Guang-Mei  Zhou  Wen-Jun  Yu  Da-Gang 《中国科学:化学(英文版)》2019,62(11):1519-1524
Herein we report a novel visible-light-mediated external reductant-free reductive cross coupling for the construction of C sp~2–C sp~3 bonds. A variety of benzylammonium salts underwent selective coupling with(hetero)aryl nitriles to deliver important diarylmethanes under mild reaction conditions. Importantly, photocatalysts can be omitted for many cases, which might involve the electron donor acceptor(EDA) complex. Mechanistic studies indicated benzylic radicals might be involved as the key intermediates. Moreover, the in situ generated NMe_3 via cleavage of C–N bond in ammonium salts acts as the electron donor,thus avoiding the use of external-reductant.  相似文献   
99.
The design of new uranyl-ligands (uranyl-Ls) is of great significance for the separation and utilization of uranium. In this paper, the triazole group was introduced into uranyl-salophen (uranyl-S) to form new asymmetric uranyl-unilateral benzotriazole salophen (uranyl-UBS); we further replaced two oxygen atoms of uranyl-UBS with two sulfur atoms to generate uranyl-unilateral benzotriazole thio-salophen (uranyl-UBTS) as a new receptor. Then, we comprehensively explored coordination models of uranyl-UBS and uranyl-UBTS with R/S-triadimefons (R/S-TDFs) enantiomers as the guests using density functional theory calculations at the B3LYP//RECP/6-311G** level; we then investigated enantioselectivity recognition of the new receptors to the guests R/S-TDFs. The results indicated that the uranium atoms of the receptors uranyl-S, uranyl-UBS and uranyl-UBTS could coordinate with the carbonyl oxygens in guests R/S-TDFs to form complexes of guest-receptors R/S-TDFs-uranyl-Ls that exhibited two stable V-shaped structures with quite different properties. It was found that the coordination ability to the guests R/S-TDFs is uranyl-UBTS > uranyl-UBS > uranyl-S, while the enantioselectivity for the guests is uranyl-UBTS > uranyl-S > uranyl-UBS and, when the receptor is the same, R-TDF has stronger coordination ability than S-TDF. These results provide information and theoretical supports for the experiments of asymmetric uranyl-UBS with R/S-TDFs, and produce a reference for further exploring the coordination characteristics of asymmetric uranyl-salophen with the triazole derivatives.  相似文献   
100.
Fang  Tao  Chen  Xiuting  Wang  Miao  Wang  Yanan  Liao  Lixia  Li  Bin 《Research on Chemical Intermediates》2020,46(12):5459-5477
Research on Chemical Intermediates - In recent years, how to improve photocatalytic performance under visible light has become one of the research hot topics. The nano-TiO2 particles were...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号