Study of size-fractionated coal-combustion aerosols using instrumental neutron activation analysis

The chemical composition of aerosols emitted during coal combustion was studied as a function of particle size down to 0.01 m. The aerosol collections were carried out in a 81 MW capacity boiler that burned Venezuelan coal in a circulating fluidized bed combustion chamber. The samples were analyzed with upstream of the electrostatic precipitator using a Berner low-pressure impactor, which was quipped with a cyclone pre-cutter to avoid overloading of the first impaction stages. The samples were analyzed by INAA for up to about 40 elements. The elemental concentrations in the particulate matter for each impaction stage were plotted as a function of stage number (particle size). For the elements Na, Al, K, Ca, Sc, Ti, V, Ga, La and Sm, the concentration variation was limited to a factor of 2 to 4, and the concentrations of these elements were lower for the initial and final impactor stages than for the intermediate particle sizes. The variations were also limited to a factor of 2–4 for Mn, Fe, As, Sb and Th, butall these elements showed increasing concentrations with decreasing particle size. Still other elements, such as Ni, Cr, Co, Za, W, Mo and the halogens, were highly enriched (up to 20–100 fold) in the fine particles when compared with the coarse particles.     

On the nucleolus of NTU-games defined by multiple objective linear programs

In this article we derive a class of cooperative games with non-transferable utility from multiple objective linear programs. This is done in order to introduce the nucleolus, a solution concept from cooperative game theory, as a solution to multiple objective linear problems.We show that the nucleolus of such a game is a singleton, which is characterized by inclusion in the least core and the reduced game property. Furthermore the nucleolus satisfies efficiency, anonymity and strategic equivalence.We also present a polynomially bounded algorithm for computation of the nucleolus. Letn be the number of objective functions. The nucleolus is obtained by solving at most2n linear programs. Initially the ideal point is computed by solvingn linear programs. Then a sequence of at mostn linear programs is solved, and the nucleolus is obtained as the unique solution of the last program.Financial support from Nordic Academy for Advanced Study (NorFA) is gratefully acknowledged. Part of this work was done during autumn 1993 at Institute of Finance and Management Science, Norwegian School of Economics and Business Administration.     

Iron orbital occupancies upon valence mixing of charge-ordered GdBaFeIIFeIIIO5

Mössbauer spectra of charge-ordered/valence-mixed GdBaFe₂O₅ have been analyzed in order to determine the orbital occupancies of the minority-spin d electron as a function of temperature. In the charge-ordered state below the Verwey temperature T _V, it occupies the Fe²⁺ d _xz orbital, which is ordered. Above T _V, the electron partially occurs also at the trivalent iron and spreads over two additional orbitals, $d_{x^{2}-y^{2}}$ and $d_{z^{2}}$ . In the valence-mixing state (above T _p) also orbital d _yz participates. The study illustrates how the Mössbauer electric-field gradient, center shift and internal field jointly reflect the distribution of the minority-spin electron culprit behind the Verwey transition.     

Fabrication process parameters significantly affect the perovskite oxygen carriers materials (OCM) performance in chemical looping with oxygen uncoupling (CLOU)

Journal of Thermal Analysis and Calorimetry - The CLOU performance of the CaTixMn0.9?xMg0.1O3 (CMTM) perovskite-type system was investigated, comparing materials produced at laboratory scale...     

Incompressible smoothed particle hydrodynamics for free-surface flows: A generalised diffusion-based algorithm for stability and validations for impulsive flows and propagating waves

The incompressible smoothed particle hydrodynamics (ISPH) method with projection-based pressure correction has been shown to be highly accurate and stable for internal flows and, importantly for many problems, the pressure field is virtually noise-free in contrast to the weakly compressible SPH approach (Xu et al., 2009 [31]). However for almost inviscid fluids instabilities at the free surface occur due to errors associated with the truncated kernels. A new algorithm is presented which remedies this issue, giving stable and accurate solutions to both internal and free-surface flows. Generalising the particle shifting approach of Xu et al. (2009) [31], the algorithm is based upon Fick’s law of diffusion and shifts particles in a manner that prevents highly anisotropic distributions and the onset of numerical instability. The algorithm is validated against analytical solutions for an internal flow at higher Reynolds numbers than previously, the flow due to an impulsively started plate and highly accurate solutions for wet bed dam break problems at zero and small times. The method is then validated for progressive regular waves with paddle motion defined by linear theory. The accurate predictions demonstrate the effectiveness of the algorithm in stabilising solutions and minimising the surface instabilities generated by the inevitable errors associated with truncated kernels. The test cases are thought to provide a more thorough quantitative validation than previously undertaken.     

Gasanalyse

Ohne Zusammenfassung     

易化输运过程的简单化学模型及其在Wyman-Murray扩散中的应用(英文)

A simple chemical kinetic model is developed which describes the behavior of small ligands that can bind reversibly with large carrier molecules with slower intrinsic rates of transport. Under certain conditions, which we describe, the presence of the slower carriers in fact enhances the transport of the ligand. This is the chemical version of Wyman-Murray′ s facilitated diffusion. The simple model illuminates the driven nature of the enhancement of the transport by the carrier molecules: we show that the facilitated transport depends crucially on a"grand canonical" setting in which the free ligand concentrations are kept constant in the presence of the facilitating protein, in contrast to a canonical setting with constant total ligand concentrations. Results from the simple model are compared to previous experimental and theoretical results for Wyman-Murray facilitated diffusion of oxygen and carbon monoxide in muscle. A relation is established between the association-dissociation rates and the down-stream ligand concentration, or back pressure for oxygen, required for the facilitation effect to occur.     

A 480 ms isomeric 29/2−-state of the(p_{1/2}^{ - 2} )_{0^ + } f_{5/2}^{ - 1} (i_{13/2}^{ - 2} )_{12^ + } configuration in203Pb

A new, 480 ms, 29/2^? isomeric level has been found in²⁰³Pb at an excitation energy of 2950.1 keV by bombarding²⁰⁴Hg with α-particles in the energy range 45–55 MeV using the Stockholm 225-cm cyclotron. This 29/2^? state is suggested to be mainly due to the configuration (p ₁ ^2/?2 f ₅ ^2/?1 i ₁₃ ^2/?2 )₁₂. The 29/2^? state decays predominantly by a 153.4 keV M2 transition to a 23/2^? level and by a 1027.5 keV M4 transition to a 21/2⁺ level, followed by two E2 transitions of energies 258.6 keV and 838.7 keV, respectively, to the previously known 13/2⁺, 6.4 s isomeric level. The decay scheme of the 29/2^? isomeric state is based on experimental information obtained from total and delayedγ-ray intensities,γγ-coincidences, excitation functions, lifetime and delayed conversion electron measurements. The presence of the 29/2^? level confirms an essential and expected feature of the shell model for five neutron holes added to the²⁰⁸Pb-core.