首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1037篇
  免费   71篇
  国内免费   119篇
化学   872篇
晶体学   12篇
力学   19篇
综合类   15篇
数学   114篇
物理学   195篇
  2024年   1篇
  2023年   18篇
  2022年   32篇
  2021年   44篇
  2020年   60篇
  2019年   48篇
  2018年   30篇
  2017年   34篇
  2016年   71篇
  2015年   65篇
  2014年   57篇
  2013年   59篇
  2012年   102篇
  2011年   109篇
  2010年   63篇
  2009年   75篇
  2008年   65篇
  2007年   66篇
  2006年   59篇
  2005年   36篇
  2004年   28篇
  2003年   14篇
  2002年   14篇
  2001年   8篇
  2000年   11篇
  1999年   8篇
  1998年   3篇
  1997年   5篇
  1996年   7篇
  1995年   6篇
  1994年   6篇
  1993年   2篇
  1992年   3篇
  1991年   2篇
  1990年   1篇
  1989年   3篇
  1988年   1篇
  1986年   2篇
  1984年   2篇
  1983年   1篇
  1981年   1篇
  1979年   1篇
  1975年   1篇
  1964年   3篇
排序方式: 共有1227条查询结果,搜索用时 15 毫秒
81.
Asymmetric mode transformation in waveguide is of great significance for on-chip integrated devices with one-way effect, while it is challenging to achieve asymmetric nonlinear-mode-conversion (NMC) due to the limitations imposed by phase-matching. In this work, we theoretically proposed a new scheme for realizing asymmetric NMC by combining frequency-doubling process and periodic PT symmetric modulation in an optical waveguide. By engineering the one-way momentum from PT symmetric modulation, we have demonstrated the unidirectional conversion from pump to second harmonic with desired guided modes. Our findings offer new opportunities for manipulating nonlinear optical fields with PT symmetry, which could further boost more exploration on on-chip nonlinear devices assisted by non-Hermitian optics.  相似文献   
82.
采用固相反应法成功制备出一批Y123与Y211的摩尔比为1∶0.47的混合物,并在此混合物的基础上掺入CeO2,掺入的比例x分别为0.5wt%、1.0wt%、2.0wt%、3.0wt%、4.0wt%。采用了X-射线衍射仪对样品的晶格结构进行了分析,测量结果表明:x=1.0wt%时掺杂效果最好,同时也充分说明Y123的晶格结构与其超导电性之间存在着一种内在的必然关联。并通过对其测试临界转变温度以及转变宽度,测量结果也充分验证了上述结论。  相似文献   
83.
以脱脂、除蛋白后的人乳为原料,联合运用阴离子交换色谱(AEC)、凝胶渗透色谱(GPC)和多孔石墨化碳色谱(PGC)等多种分离纯化技术制备了18种中性人乳寡糖,并采用电喷雾碰撞诱导串联质谱(ESI-CIDMS/MS)技术对其结构进行了鉴定.结果表明,所制备的中性人乳寡糖主要为三至九糖,含有半乳糖(Gal)、葡萄糖(Glc)、N-乙酰葡萄糖胺(GlcNAc)和岩藻糖(Fuc).所有寡糖的还原端均含有乳糖核心(Galβ1-4Glc),非还原端均含有乳糖胺(Galβ1-3/4GlcNAc),并且Fuc以α1-2,α1-3和α1-4连接于主链的Gal,Glc和GlcNAc上.  相似文献   
84.
Both surface tension and solubility parameter are decided by molecular interactions. There are several empirical equations describing their connection. However, at least two limitations exist for them: polymers cannot be treated and only apolar or weakly polar solvents can be fitted. We found when only the dispersive properties were considered, for 37 solvents and 22 polymers, a linear relationship exists between γ d and γ/δ2/3 d , fitted by a new equation. Compared with the previous equations, the value of the new equation is that most solvents and common polymers could be treated simultaneously. This equation will be of value for estimating the accuracy of reported surface tension data or solubility parameters of polymers.  相似文献   
85.
86.
A thermal analysis study of the effect of phosphate, in the concentration range 0.7–4.5%, on the hydration reaction of 3 CaO · SiO2(C3S) is reported. The results are compared with strength development of phosphate cement reported by Nurse.  相似文献   
87.
A new capillary coating of alternate -zirconium phosphate lysozyme fabricated for open-tubular electrochromatography enantioseparation. The chiral compounds D, L-tryptophan tested were enantiomerically resolved. The influences brought by experimental parameters, such as organic modifier, temperature, applied voltage and pH of running buffer on the performance of the column, were investigated.  相似文献   
88.
Xu L  Fanguy JC  Soni K  Tao S 《Optics letters》2004,29(11):1191-1193
The phenomenon of evanescent-wave scattering (EWS) is used to design an optical-fiber humidity sensor. Porous solgel silica (PSGS) coated on the surface of a silica optical-fiber core scatters evanescent waves that penetrate the coating layer. Water molecules in the gas phase surrounding the optical fiber can be absorbed into the inner surface of the pores of the porous silica. The absorbed water molecules form a thin layer of liquid water on the inner surface of the porous silica and enhance the EWS. The amount of water absorbed into the PSGS coating is in dynamic equilibrium with the water-vapor pressure in the gas phase. Therefore the humidity in the air can be quantitatively determined with fiber-optic EWS caused by the PSGS coating. The humidity sensor reported here is fast in response, reversible, and has a wide dynamic range. The possible interference caused by EWS to an optical-fiber gas sensor with a reagent-doped PSGS coating as a transducer is also discussed.  相似文献   
89.
A two-dimensional optical storage (TwoDOS) format with binary modulation is being developed in which channel bits are arranged on a two-dimensional hexagonal lattice [W. M. J. Coene, in Optical Data Storage, Vol. 88 of OSA Trends in Optics and Photonics Series (Optical Society of America, Washington, D.C., 2003), pp. 90-92]. The aim is to increase the capacity by a factor of 2 and the data rate by a factor of 10 over third-generation Blu-ray Disc technology. Following a route similar to that used in one-dimensional conventional optical storage [Jpn. J. Appl. Phys. 42, 1074 (2003)] could lead to a further increase in capacity by the addition of another dimension to writing data, such as the use of multiple levels instead of the two levels (pit and land) used in the binary TwoDOS disk format. We present a nonlinear signal-processing model for signal waveform generation as a function of the M-ary channel symbols, as well as simulated signal readouts for multilevel TwoDOS.  相似文献   
90.
We study a Si-based diode with a p+nn+ structure for picosecond semiconductor closing switch and discuss the physical process, which underlies the operation principle of high-power closing switch based on a delayed breakdown diode (DBD). From the results of numerical simulations and theoretical analysis, single device has demonstrated reliable operation at 2.3 kV, 89 ps risetime, and high output dV/dt(30 kV/ns). As a contribution to the optimal design, some conclusions about trade-off are drawn by changing structure parameters and physical parameters.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号