合肥光源交错刀片型光位置检测器的研制

为了减小同步光尺寸对同步光位置检测器灵敏度的影响,合肥光源新研制了一种交错刀片型光位置检测器,并使用成熟的商业化产品Libera Photon进行后续的数据处理和输出。基于传统计算光位置信号的差比和方法,提出了比值和对数比两种新的计算方法,理论模拟了3种计算方法下交错刀片型光位置检测器的性能。在线标定结果与理论计算结果相符,并在机器研究光束线进行了初步的应用研究。     

Growth,spectroscopic and laser properties of Yb<Superscript>3<Emphasis Type="Bold">+</Emphasis></Superscript>-doped GdAl<Subscript>3</Subscript>(BO<Subscript>3</Subscript>)<Subscript>4</Subscript> crystal: a candidate for infrared laser crystal

Yb³⁺:GdAl₃(BO₃)₄ (hereafter Yb³⁺:GAB) crystals with large sizes and good optical quality have been grown by the top-seed solution growth (TSSG) method. The polarized absorption and emission spectra have been investigated at room temperature. For the σ-polarization, the intensities of both absorption and emission spectra are stronger than those for the π-polarization, the σ-absorption cross section of Yb³⁺ in GAB being 3.43×10^-20 cm² at 977 nm, and the σ-emission cross section being 0.98×10^-20 cm² at 1045 nm. The fluorescence lifetime of the ² F _5/2→² F _7/2 transition was measured to be 800 μs in the 5% doped sample used for our laser experiments, 993 μs in a 10% doped sample and 569 μs in a 0.5% doped sample. The laser parameters were estimated as: β_min=0.022, I_sat=10.4 kW/cm² and I_min=0.23 kW/cm². About 0.4 W laseroutput at the wavelength of 1043 nm was achieved when the Yb³⁺:GAB crystal was pumped by a 974 nm laser diode, with 27.4% slope efficiency. PACS 42.55.-f; 42.70.Hj; 78.20.-e; 81.10.Dn     

用于全光铯原子磁力仪的激光器稳频技术研究

全光铯原子磁力仪是采用光学的方法实现微弱磁场检测,激光频率稳定性直接影响磁力仪的灵敏度。分析了二向色性原子蒸气激光频率锁定(Dichroic atomic vapor laser lock DAVLL)技术用于稳定激光器频率的原理,及其在全光原子磁力仪中的应用优势,发现通常的二能级原子模型不适用于分析铯原子D2线的稳频。实验测量了不同磁场下铯原子D2线基态Fg=4和Fg=3跃迁的DAVLL光谱,发现16mT是实现DAVLL稳频的最佳磁场;在此磁场附近,基态Fg=4跃迁鉴频曲线零点相对于Fg=4→Fe=5跃迁会产生6MHz/mT的线性频移,基态Fg=3跃迁鉴频曲线零点相对于Fg=3→Fe=4线会产生-9MHz/mT的线性频移。     

一种局部模式的RGB差值序列交叉区域取样节点定位算法

鉴于当前无线传感器网络移动节点定位技术中存在的实时性差和定位不准确的问题,设计了一种交叠区域采样模式的WSN移动节点定位算法OASM_MNL(overlapping area sampling mode of mobile node localization)。该算法通过获取的信号在能够直接和移动节点通信的信标节点的信号交叠区域里面进行局部采样;通过距离比例因子对平均跳距进行权值化,优化了中跳距的计算公式;通过差值序列对样本点滤波,在此基础上把差值序列绝对值作为加权标准,计算出移动节点的坐标。仿真结果表明,与E-CDL、MCL等常见的移动节点定位算法相比,新算法定位误差降低幅度超过,定位效果良好。     

Theoretical and experimental investigations on the structures of purified clay and acid-activated clay

The purified and acidified montmorillonite clay were characterized by XRD, BET and TPD. These results show that acidified clay is provided with more surface area and acid sites. For NH₃-TPD, molecular NH₃ desorption on purified clay and acidified clay occurs at temperatures with 873 and 1000 K, respectively. It is shown for the existence for strong acid sites. By two reactions of the tetrahydropyranylation of n-propanol and the esterification of cyclo-2-pentene with acetic acid, it is shown that the acidified clay displays better catalytic activity for above two organic reactions. By density-functional theory (DFT) method, we have analyzed the structures of different substituted montmorillonite and the effect sorption behavior of Na⁺ in different montmorillonite models. The result shows that the process of substitution will occur apart from octahedral aluminums. The adsorption of NH₃ on clay surfaces have been investigated using TPD and DFT. This is shown that acid sites locate at round the octahedral aluminums, and substitution of Al³⁺ for tetrahedral Si will be favorable to NH₃ adsorption.     

Surface modifications of ITO electrodes for polymer light-emitting devices

Surface modifications were performed on the indium tin oxide (ITO) substrates for polymer light-emitting devices, using the different treatment methods including solvent cleaning, hydrochloric acid treatment and oxygen plasma. The influence of modifications on the surface properties of ITO electrodes were investigated by X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), contact angle, and four-point probe. The surface energies of the ITO substrates were also calculated from the measured contact angles. Experimental results demonstrate that the surface properties of the ITO substrates strongly depend on the modification methods, and oxygen plasma more effectively improves the ITO surface properties compared with the other treatments. Furthermore, the polymer light-emitting electrochemical cells (LECs) with the differently treated ITO substrates as device electrodes were fabricated and characterized. It is observed that the surface modifications on ITO electrodes have a certain degree of influence upon the injection current, luminance and efficiency, but hardly upon the turn-on voltages of current injection and light emission which are close to the measured energy gap of electroluminescent polymer. Oxygen plasma treatment on the ITO electrode yields the better performance of the LECs, due to the improvement of interface formation and electrical contact of the ITO electrode with the polymer blend in the LECs.     

A study of optical properties of a four-level atomic system via vacuum-induced coherence effects

This paper studies the effects of vacuum-induced coherence(VIC) in a four-level atomic system.The effects of VIC lead to the coherent hole burnings exhibited in the system at some certain points of the Rabi frequency.This is also the reason for the enhancement of the coherent population trapping.In addition,optical bistability occurs in the evolution curves of absorption versus the phase of Rabi frequencies.     

氧族元素对D-A和D-π-A共聚物光吸收谱红移的第一性原理研究

D-A型共聚物作为有机聚合物太阳能电池的电子给体材料近年来引起广泛关注. 本文以苯并二噻吩(BDT)为电子给体单元, 苯并噻二唑(BT)为电子受体单元来模拟D-A共聚体; 并用噻吩环作为π桥, 构造出D-π-A(PBDT-DTBX, X = O, S, Se, Te)结构. 采用第一性原理的密度泛函理论, 系统地计算相应的电子结构和光吸收谱. 比较不同氧族元素和噻吩π-键桥对聚合物光吸收谱的影响. 研究结果表明: D-A共聚体中当X位元素以O, S, Se, T_e 替换时, 其体系的最高占有分子轨道(HOMO)能级变化不大, 最低未占有分子轨道(LUMO)能级逐渐靠近费米能级, 带隙逐渐减小. 在可见光区有两个较强的吸收峰, 随着X位元素原子序数增大, 位于4.0 eV左右的光吸收峰位基本不变, 另一光吸收峰强度明显增大并发生红移. 与D-A结构相比, D-π-A结构的带隙均有所减小, 其中X为Te时带隙最小; 光吸收峰强度随着氧族元素原子序数的增大也明显增大并发生红移. 通过比较光吸收系数和相应态密度, 结果表明, 4.0 eV 左右的光吸收峰主要是BDT单元的贡献, 氧族元素的改变主要影响519.4-703.9 nm范围的光吸收.     

酯基取代的吲哚衍生物的红外和荧光光谱研究

Tryptophan derivatives have long been used as site-specific biological probes. 4-Cyanotryptophan emits in the visible region and is the smallest blue fluorescent amino acid probe for biological applications. Other indole or tryptophan analogs may emit at even longer wavelengths than 4-cyanotryptophan. We performed FTIR, UV-Vis, and steady-state and time-resolved fluorescence spectroscopy on six ester-derivatized indoles in different solvents. Methyl indole-4-carboxylate emits at 450 nm with a long fluorescence lifetime, and is a promising candidate for a fluorescent probe. The ester-derivatized indoles could be used as spectroscopic probes to study local protein environments. Our measurements provide a guide for choosing esterderivatized indoles to use in practice and data for computational modeling of the effect of substitution on the electronic transitions of indole.