Spin sublevel-selective and position-dependent isotope effects in T1(ππ*) → S0 intersystem crossing of polycyclic para-diazines

ODMR measurements are combined with phosphorescence quantum yield data to show that deuterium isotope effects on the nonradiative decay rates of quinoxaline and dibenzoquinoxaline are spin sublevel-selective as well as position-dependent.     

Das Verhalten von Oberfläche zu Oberflächendruck von Fettsäure-Einzelschicten auf Mehrfachkomponenten-Substraten

Ohne Zusammenfassung     

THE EFFECT OF ALA AND RADIATION ON PORPHYRIN/HEME BIOSYNTHESIS IN ENDOTHELIAL CELLS

To study porphyrin biosynthesis in human microvascular endothelial cells, HMEC-1 cells, a transformed human microvascular endothelial cell line, were incubated with 5-aminolevulinic acid (ALA), the precursor of endogenous porphyrins, and porphyrin accumulation was measured spectro-fluorometrically. The HMEC-1 cells accumulated porphyrin in a concentration-related and a time-dependent fashion. Protoporphyrin was the predominant porphyrin accumulated in the cells. The effect of light on protoporphyrin accumulation was evaluated by exposing the ALA-loaded HMEC-1 cells to ultraviolet-A (UVA) and blue light, followed by another incubation with ALA for 2–24 h. Enhancement of protoporphyrin accumulation in irradiated HMEC-1 cells was observed 2–24 h after irradiation, which was associated with a decrease in ferrochelatase protein and activity. Porphyrin accumulation from ALA after irradiation was significantly decreased when catalase (750–3000 U/mL, 29.3–44.3% suppression) or superoxide dismutase (270 U/mL, 36.4% suppression) was present during irradiation. These data demonstrate that HMEC-1 cells were capable of porphyrin biosynthesis, and that exposure of protoporphyrin-containing HMEC-1 cells to UVA and blue light, which includes the Soret band spectrum, decreased the ferrochelatase activity and its protein. These changes were mediated, at least in part, by reactive oxygen species.     

Two-level hierarchically preconditioned conjugate gradient methods for solving linear elasticity finite element equations

In this paper we study and compare some preconditioned conjugate gradient methods for solving large-scale higher-order finite element schemes approximating two- and three-dimensional linear elasticity boundary value problems. The preconditioners discussed in this paper are derived from hierarchical splitting of the finite element space first proposed by O. Axelsson and I. Gustafsson. We especially focus our attention to the implicit construction of preconditioning operators by means of some fixpoint iteration process including multigrid techniques. Many numerical experiments confirm the efficiency of these preconditioners in comparison with classical direct methods most frequently used in practice up to now.     

Surface roughness dependence of the first-order probability density function for integrated speckle

The surface roughness dependence of the first-order probability density function (PDF) of an integrated speckle pattern, produced in the condition of circular detection aperture and gaussian scattering spot, was theoretically investigated. The mutual intensity J_A(x₁, y₁; x₂, y₂) containing two roughness parameters, dispersion of surface height ø² lateral correlation length x_c, was calculated. The exact first-order probability density function was analytically derived and numerically calculated by means of the Karhunen-Loeve expansion and fast Fourier transform (FFT). As a diffuse object became smooth, the first order probability density function was changed from negative exponential to sharp peak gaussian centered around mean intensity.     

Sorption of water and organic solutes in polyimide films and its effects on dielectric properties

The effect of structure on the sorption kinetics of water and of various organic solutes into polyimide (PMDA-ODA) thin films was studied. The major techniques employed include measurements of sorption kinetics, density, and dielectric relaxation. More solute uptake, lower densities and higher diffusivities were observed for films cured at lower temperatures. By measuring both changes of mass and of density, the volume expansion of the polymer due to each solute was obtained; this was found to be proportional to the molar volume of the solute. The two dielectric relaxation peaks (denoted by γ₁ and γ₂) due to water (and other solutes) were studied in detail to obtain the relevant activation energies and the separate dipole moments. While water and methylene chloride appear in both γ₁ and γ₂ configurations, methyl and ethyl alcohol appear mainly as γ₂, while acetic acid is primarily γ₁. It was concluded that the γ₁ configurations are relatively homogeneously distributed throughout the polymer, involving loose bonding to the polymer structure, while the γ₂ configurations involve small clusters, probably chains of molecules. © 1993 John Wiley & Sons, Inc.     

Neutral K1(890) and ρ0 meson production in e+e− annihilation at ;s=29GeV

The production of neutral K¹(890) and ρ⁰ mesons was studied in e⁺e^? annihilation at $\text{s}\text{=29}\text{GeV}$ using the High Resolution Spectrometer at PEP. Differential cross sections are presented as a function of the scaled energy variable z and compared to π⁰ and K⁰ production. The measured multiplicities are 0.84±0.08 ?⁰ mesons and $\text{0.57±0.09 K}{}^{10}\text{(890)}$ mesons per event for a meson momentum greater than 725 MeV/c. The ratios of vector meson to pseudoscalar meson production for (u,d), s and c quark are compared to predictions of the Lund model.