Properties of matrix-assisted laser desorption. Measurements with a time-to-digital converter.

Some properties of matrix-assisted laser desorption have been studied using single-ion-counting methods and a time-to-digital converter. The methods allow examination of the process for irradiances near the reported threshold for observation with a transient recorder. All measurements were made using bovine insulin as a test compound. We present direct evidence that an irradiance threshold near 10(6) W cm-2 exists for ion production, and that the process is a collective effect, either involving a large number of molecular ions (approximately 10(4) in a successful event or none at all. Above the threshold, the yield is found to scale with a high power (4th to 6th) of the irradiance. Measurements of initial velocity distributions indicate an axial velocity spread corresponding to approximately 50 eV and a radial velocity spread corresponding to approximately 2.4 eV. Thus the ejection or extraction mechanism appears to be strongly asymmetric.     

Time resolved laser-induced plasma dynamics

The structure and evolution of the laser-induced vapor plume and shockwave were measured from femtosecond time resolved shadowgraph images. By changing the wavelength of the probe beam (400 and 800 nm), differences in the opacity of the vapor plume were measured as a function of delay time from the ablation laser pulse. The evolution of the temperature and electron number density during and after the ablation laser pulse were determined and compared for ablation in argon and helium background gases. A laser supported detonation wave (LSD) observed for ablation in argon, blocks the incoming laser energy and generates a high-pressure region above the vapor plume.     

闪光灯泵浦的Nd:KGd(WO4)2激光器

报道了用闪光灯泵浦的掺钕的钨酸钆镓(Nd³⁺:KGd(WO₄)₂激光器.在重复频率1Hz,脉宽120μs的灯泵下,测量了不同透过率下激光输出能量,获得最大输出能量384mJ,斜率效率1.0%,外推阈值0.54J.在调Q运行时,Nd:KGW晶体的斜率效率为0.16%,最大输出能量46mJ.     

一种新型有机电致微腔结构的双模发射

采用结构Glass／DBR／ITO／NPB／NPB：Alq／Alq／Al制作了有机微腔电致发光器件。将空穴传输材料与发光材料以一定比例混合作为发光层，为了便于对比，在不改变有机层的膜厚的情况下同时制作了传统的异质结微腔器件，发现两种器件的发光光谱有很大不同，器件的复合效率与传统的异质结器件相比也得到了很大提高，这是因为将两种有机材料混合能消除界面势垒，提高器件的复合效率，从而提高了器件的发光性能，实现了微腔双模发射，且两个模式的半峰全宽分别为8nm和12nm。通过进一步优化器件结构可以实现微腔白光发射。     

聚合物微腔的研制及其特性分析

采用ＢＭＰＰＶ：ＰＶＫ的混合物作国源介质，将其按一定比例溶于氯仿中，并旋涂在具有９９．５％的反射率的ＤＢＲ上，其上蒸发３００ｎｍ的银膜，形成了面发射型微腔结构，其中ＤＢＲ在入射腔面，银膜为反射腔面，在激发波长３３７．１ｎｍ，频率２０Ｈｚ脉宽１０ｎｓ的氮分子激光器泵浦下，光谱明显等窄化，出现４６０ｎｍ和５３０ｎｍ两个比较强的发光峰，主峰国４６０ｎｍ半宽度为７ｎｍ。     

Molecular deposition film of porphyrin and phthalocyanine bearing oppositely charged substituents

Ｔｈｅｆｏｒｍａｔｉｏｎｏｆａｎｅｗｔｙｐｅｏｆｓｅｌｆ＿ａｓｓｅｍｂｌｅｄｍｕｌｔｉｌａｙｅｒｆｉｌｍｓ,ｍｏｌｅｃｕｌａｒｄｅｐｏｓｉｔｉｏｎ(ＭＤ)ｆｉｌｍｓ[1,2],ｉｓａｆａｓｔｄｅｖｅｌｏｐｉｎｇａｒｅａｏｆｔｈｉｎｆｉｌｍｒｅｓｅａｒｃｈ.Ｔｈｉｓｎｅｗｍｅｔｈｏｄｏｆｆｉｌｍｐｒｅｐａｒａｔｉｏｎｉｓｂａｓｅｄｏｎｉｏｎｉｃａｔｔｒａｃｔｉｏｎｂｅｔｗｅｅｎｏｐｐｏｓｉｔｅｃｈａｒｇｅｄｃｈｒｏｍｏｐｈｏｒｅｓ.ＩｎｃｏｍｐａｒｉｓｏｎｗｉｔｈｔｈｅｃｌａｓｓｉｃＬａｎｇｍｕｉｒ＿Ｂｌｏ…     

若干杂环模型化合物的热氧化稳定性

<正> 自五十年代以来,耐热的杂环高分子取得了很多进展。曾报道聚酰亚胺、聚苯并咪唑、聚苯并噻唑、聚苯并噁唑、聚喹噁林及聚苯并噁嗪酮等都是性能较好的耐热高分子,而有些在工业上已得到应用。我们在进行芳杂环二腈聚合的工作中,曾将上述杂环结构引入二腈,以期获得性能优良的耐热高分子,所得结果已陆续报道。     

INFLUENCE OF COMPOSITIONAL HETEROGENEITY ON MORPHOLOGY AND PROPERTIES OF SEGMENTED COPOLYMERS

Polyethylene terephthalate(PET)/polycaprolactone(PCL) segmented copolymers with different hard segment contents and a blend of two of them were studied by using DSC, WAXS, TEM and IR techniques and dynamic mechanical, stress-strain and isothermal crystallization measurements. Emphasis was laid on the studies of influence of compositional heterogeneity on the morphology and properties of these segmented copolymers. It was found that the solution cast specimens of the more heterogeneous sample exhibit better segregation of segments, high crystallinity and melting temperature. They have higher thermal stability of mechanical properties at small deformations. However, they are less stable against large deformations and may become softer than the more homogeneous ones.