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31.
交通流非参数回归模型 总被引:7,自引:0,他引:7
交通流宏观参数流量、速度和占有率在交通工程和管理中具有非常重要的作用 ,对这三者关系的刻划反映了道路本身特性和交通流的规律。到目前为止 ,基本上采用线性或非线性的参数模型来描述 ,此类模型在应用中具有一定的局限性 ,并交通变量时间序列进行预测 ,数据拟合表明 ,选择适当的核函数或邻近数以及窗宽 ,可以达到比较满意的效果 相似文献
32.
The 10‐thia analog of mesobilirubin‐XIIIα, with the central C(10) CH2 group replaced by sulfur ( 1a ) was synthesized by condensation of neoxanthobilirubic acid ( 3 ) with sulfur dichloride. Thia‐rubin 1a is a brilliant yellow solid, forming bright yellow solutions with uv‐visible absorption maximum from 425–440 nm. 相似文献
33.
34.
Antony F. McDonagh Giovanni Agati David A. Lightner 《Monatshefte für Chemie / Chemical Monthly》1998,129(6-7):649-660
Summary. Quantum yields for Z⇄E photoisomerization of the natural bi-chromophore bilirubin IXα in ammoniacal methanol solution were found to vary with excitation
wavelength, whereas no variation (within experimental error) was observed for xanthobilirubic acid and for symmetrically substituted
bilirubins (bilirubin IIIα, bilirubin XIIIα, and mesobilirubin XIIIα) in the same solvent. The quantum yield for Z⇄E photoisomerization of xanthobilirubic acid bound to human serum albumin was also invariant with excitation wavelength. In
contrast, quantum yields for Z⇄E photoisomerization of the symmetrically-substituted bilirubins did show marked excitation wavelength dependency when they
were bound to human serum albumin. These results show that quantum yields for Z⇄E photoisomerization of bilirubins are markedly sensitive to protein binding and to the nature of pyrrole ring β-substituents.
They also demonstrate that wavelength-dependent photochemistry is characteristic of bilirubins with non-identical pyrromethenone
chromophores, as expected from exciton coupling theory, and that complexation with albumin induces wavelength-dependent photochemistry
in symmetrically substituted bilirubins.
Received January 13, 1998. Accepted January 27, 1998 相似文献
35.
基于惩罚与补贴的再制造闭环供应链网络均衡模型 总被引:1,自引:0,他引:1
为研究我国废旧电子产品(WEEE)立法的问题,分析了供应商、制造商、零售商、需求市场及回收商的行为,分别建立了变分不等式模型,并在此基础上建立了五级再制造闭环供应链网络均衡模型。模型考虑了政府对于制造商的惩罚政策与对于回收商的补贴政策。通过修正投影算法求解算例,仿真分析了旧材料转化率、回收率、惩罚及补贴政策对闭环供应链网络均衡结果的影响。结果表明,随着政府对于回收商的补贴的增加,不但回收商的回收量提高,闭环供应链的新材料需求量、旧材料需求量、销售量均增加;相反,随着政府对于制造商未完成的回收量的罚款增加,回收量、新材料需求量、旧材料需求量、销售量均降低;追求高回收率的政策并不总是有效的;而提高WEEE的旧材料转化率对于闭环供应链有利。 相似文献
36.
37.
Tatsuo Nehira Stefan E. Boiadjiev David A. Lightner 《Monatshefte für Chemie / Chemical Monthly》2008,139(6):591-595
A fluorescent red-shifted exciton-coupling chromophore, N,N′-carbonyl-bridged dipyrrinone, was subjected to fluorescence-detected CD (FDCD) measurements as a primitive structure-elucidating
probe with trans-1,2-cyclohexanediol template in several solvents under various instrumental conditions. With the help of a JASCO ellipsoidal
mirror device FDCD465, a chloroform solution achieved the sensitivity enhancement by 50 times of the transmission CD and 5
times of the conventional FDCD. All FDCD spectra were completely free from the polarization artifacts.
Correspondence: Tatsuo Nehira and David A. Lightner, Graduate School of Integrated Arts and Sciences, Hiroshima University,
Higashi-hiroshima 739-8521, Japan; Department of Chemistry, University of Nevada, Reno, Nevada 89557, USA. 相似文献
38.
A high-yield straightforward conversion of lactams to lactim ethers is shown by the conversion of (10H)-dipyrrin-1-ones to (11H)-dipyrrin-1-ol methyl and ethyl ethers in 90% yield from heating in neat trimethyl or triethyl phosphite at 160°C. Unlike
the parent dipyrrinones, which form intermolecularly hydrogen-bonded dimers in CHCl3, their lactim ethers are shown to be monomeric by vapor pressure osmometry. The latter react with boron trifluoride etherate
to N,N′-bridged BF2 derivatives that exhibit strong fluorescence (φF 0.6–0.8) near 535 nm. X-Ray crystal structures were obtained of the lactim ethyl ether of kryptopyrromethenone and the BF2 derivative of the lactim ethyl ether 2,3-diethyl-7,8-dimethyl-(10H)-dipyrrin-1-one.
Correspondence: David A. Lightner, Department of Chemistry, University of Nevada, Reno, Nevada 89557-0020 USA. 相似文献
39.
While performing biomolecular interaction analysis (BIA), scientistsoften use surface plasmon resonance (SPR) to measure rate constantsof the associated reactions. A mathematical model of a BIAcoreTM,a common SPR device, consists of a convection-diffusion equationin a channel with a reacting surface at the channel ceiling.Asymptotic and singular perturbation techniques are used toanalyse the concentration of the reacting species in two cases:when the reaction occurs much more slowly than diffusion, andwhen the reaction occurs on the same time-scale as diffusion.Linear and nonlinear integral equations result from the analysis;explicit and asymptotic solutions are constructed for physicallyrealizable cases. These expressions provide a direct way toestimate the rate constants from raw data. 相似文献
40.
以二硫化碳和金属钠为基础物质合成了四硫富瓦烯(TTF)锌的配合物(TTF)Zn(NBu4)2。利用该化合物与苯甲酰氯反应得到的稳定化合物C17H10O2S5在甲醇钠溶液中与2,3-二溴丙醇反应成功合成出目标化合物(一种新配体),其化学组成为C6H6OS5。利用IR谱、^1HNMR谱及元素分析对此化合物进行了表征。 相似文献