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Anil C.A. Jayasundera Yang Li Philip Lightfoot 《Journal of solid state chemistry》2010,183(2):356-5993
The solvothermal syntheses and crystal structures of three indium fluorides are presented. K5In3F14 (1) and β-(NH4)3InF6 (2) are variants on known inorganic structure types chiolite and cryolite, respectively, with the latter exhibiting a complex and apparently novel structural distortion. [NH4]3[C6H21N4]2[In4F21] (3) represents a new hybrid composition displaying a unique trimeric metal fluoride building unit. 相似文献
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Two new alkaline-earth Nd selenite chlorides MNd10(SeO3)12Cl8 (M=Ca, Sr) were obtained using crystal growth from alkaline-earth chloride melts in quartz tubes. These new compounds crystallize in the orthorhombic system in space group C cca (#68). The compounds were studied by energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction. It was shown that both compounds adopt the same structure type, constructed by complex [M11(SeO3)12]8+ slabs separated by chloride anion layers perpendicular to the longest cell parameter. The SeO3 groups show a pyramidal shape and may be described as SeO3E tetrahedra. Such SeO3 groups decorate the Nd-O skeletons forming the [M11(SeO3)12]8+ slabs. 相似文献
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Ya. D. Lampeka I. M. Maloshtan Ph. Lightfoot R. W. Hay 《Theoretical and Experimental Chemistry》1998,34(6):327-331
We have shown by X-ray diffraction analysis that participation of functional groups on the macrocycle in formation of hydrogen
bonds promotes formation of crystal lattices with previously undescribed linear polymer chains ... Cu ... Hal ... Cu ... Hal
... We have used spectral methods to confirm the presence of a Cu-Hal interaction, which makes these compounds promising for
design of new materials with anisotropic physical properties.
Deceased
Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 34, No. 6, pp. 355–359, November–December 1998. 相似文献
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Aldous DW Stephens NF Lightfoot P 《Dalton transactions (Cambridge, England : 2003)》2007,(22):2271-2282
Nine new vanadium oxyfluorides, containing ten different oligomeric vanadium (oxy)fluoride anions have been prepared by solvothermal synthesis in water-ethylene glycol and using organic cations as co-crystallising agents. Crystal structures are reported for each. Amongst the ten structure types, five represent previously unobserved moieties, including one monomeric unit (cis-[VOF4(H2O)]2-), two dimers ([V2O2F6(H2O)2]2- and [V2O2F8]4-) and two tetramers (both isomers of composition [V4O4F14]6-). Structural relationships between the various units are discussed, together with some rationalisation of their occurrence as a function of synthetic variables. 相似文献
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Conservative methods for the Toda lattice equations 总被引:1,自引:0,他引:1
We are concerned with the numerical integration of the Todalattice equations by using different conservative methods. Numericalexperiments suggest that the global error for isospectral schemesdecreases exponentially with time but it is almost constantfor either symplectic or more general integrators. We providea theoretical explanation for these experimental findings. 相似文献
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