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51.
52.
<正>Tetracycline selective electrode using molecularly imprinted polymer particles as quasi-ionophore was constructed the first time, and its performance was carefully characterized.Due to the specific recognition of tetracycline by the particles,the selectivity coefficients for routine interferences were less than 10~(-4).Benefited from the absence of tetracycline in the sensitive membrane and the optimized composition of the inner filling solution,the limit of detection of the electrode was reduced to about 2.5×10~(-8) mol/ L.It exhibited a good electrode slope 57.6 mV/decade near the theoretical Nernstian one,with a wide linear working range from 6.0×10~(-8) to 1.0×10~(-3) mol/L.The fabricated electrode should be used in pH 2-4,response time of which was less than 200 s when the concentration of tetracycline was higher than 1.0×10~(-6) mol/L and no more than 30 min at the concentration of 1.0×10~(-8) mol/L. 相似文献
53.
Generation of short-wavelength radiation by a free-electron laser using up-frequency conversion of an electron bunch density modulation is currently an area of active research. We propose a new scheme for producing the longitudinal electron bunch density modulation similar to the recently proposed echo-enabled harmonic generation but based on an emittance exchange beam line and a multislit mask. Beam line analysis and start-to-end simulation are presented. 相似文献
54.
In strongly correlated electronic systems, the global transport behavior depends sensitively on spin ordering. We show that spin ordering in manganites can be controlled by depositing isolated ferromagnetic nanodots at the surface. The exchange field at the interface is tunable with nanodot density and makes it possible to overcome dimensionality and strain effects in frustrated systems to greatly increasing the metal-insulator transition and magnetoresistance. These findings indicate that electronic phase separation can be controlled by the presence of magnetic nanodots. 相似文献
55.
对相对论返波管实验中射频击穿现象进行了分析和数值模拟研究,发现谐振反射器和慢波结构的局部场增强诱导了场致电子发射,引起了金属表面的射频击穿,通过研究分析,提出采用分布反馈式谐振反射器,并采用梯形倒角非均匀慢波结构替换正弦慢波结构的方法来抑制射频击穿。数值模拟研究表明,在微波功率2 GW时,改进后的反射器最大场强由1.4 MV/cm降低为570 kV/cm,慢波结构表面最大电场由1.1 MV/cm降低到780 kV/cm。改进后的结构在二极管电压765 kV时获得了微波功率2.2 GW、脉宽45 ns的实验结果,微波功率和脉宽得到显著提升。 相似文献
56.
化学计量学方法在三维荧光光谱分析中的应用 总被引:1,自引:0,他引:1
随着分析数据日益复杂,传统的用于光谱分析中的数据处理方法已不能满足分析需要,而化学计量学应用数学、统计学以及计算机等科学的方法与手段,设计和选择最优的量测方法,并通过对数据的解析,可最大限度的获取光谱数据中的有用信息.本文首先介绍了几类常用化学计量学方法分析的三维荧光光谱,其次介绍了常用于光谱分析的化学计量学方法,如统... 相似文献
57.
Aimed to obtain high-quality sinusoidal fringe projection, a new method to correct the output fringe of digital projector is presented. The method is based on the proposed fringe transform model, which describes the relationship of the input and output fringe pattern. Firstly, a series of fringe patterns are projected and from the fringe images, the transform function is calculated by the pattern shifting method. At last, by modifying the input fringe pattern, a standard sinusoidal output fringe can be achieved. Different from the previous methods, the waveform nonlinearity is estimated by varying the intensity of the projected fringe pixel by pixel; thus the waveform nonlinearity can be estimated precisely and the time cost is considerably reduced. Experimental results show that by modification of the input projection patterns the projector can project fringe with high-quality sinusoidal waveform leading to high performance of the projection system. 相似文献
58.
A classification of connected vertex‐transitive cubic graphs of square‐free order is provided. It is shown that such graphs are well‐characterized metacirculants (including dihedrants, generalized Petersen graphs, Möbius bands), or Tutte's 8‐cage, or graphs arisen from simple groups PSL(2, p). 相似文献
59.
第一类弱奇异核Fredholm积分方程由于奇异及本质的不适定性,给求解带来很大难度.本文首先利用克雷斯变换将方程转化,并对转化后的方程进行高斯一勒让德离散,得到一离散不适定的线性方程组,结合正则化方法对该类问题进行数值求解.最后给出了数值模拟,验证了本文方法的可行性及有效性. 相似文献
60.
Ni(OAc)2 was found to be an efficient catalyst for the synthesis of β‐enamino ketones or esters from β‐dicarbonyl compounds and amines under solvent‐free conditions. The reusability of the catalyst was successfully examined without noticeable loss of its catalytic activity. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献