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21.
Uncovering the Stoichiometry of Pyrococcus furiosus RNase P,a Multi‐Subunit Catalytic Ribonucleoprotein Complex,by Surface‐Induced Dissociation and Ion Mobility Mass Spectrometry 下载免费PDF全文
Xin Ma Lien B. Lai Stella M. Lai Akiko Tanimoto Prof. Mark P. Foster Prof. Vicki H. Wysocki Prof. Venkat Gopalan 《Angewandte Chemie (International ed. in English)》2014,53(43):11483-11487
We demonstrate that surface‐induced dissociation (SID) coupled with ion mobility mass spectrometry (IM‐MS) is a powerful tool for determining the stoichiometry of a multi‐subunit ribonucleoprotein (RNP) complex assembled in a solution containing Mg2+. We investigated Pyrococcus furiosus (Pfu) RNase P, an archaeal RNP that catalyzes tRNA 5′ maturation. Previous step‐wise, Mg2+‐dependent reconstitutions of Pfu RNase P with its catalytic RNA subunit and two interacting protein cofactor pairs (RPP21?RPP29 and POP5?RPP30) revealed functional RNP intermediates en route to the RNase P enzyme, but provided no information on subunit stoichiometry. Our native MS studies with the proteins showed RPP21?RPP29 and (POP5?RPP30)2 complexes, but indicated a 1:1 composition for all subunits when either one or both protein complexes bind the cognate RNA. These results highlight the utility of SID and IM‐MS in resolving conformational heterogeneity and yielding insights on RNP assembly. 相似文献
22.
This paper makes the first attempt of extending implicit AUSM‐family schemes to multiphase flow simulations. Water faucet, air–water shock tube and oscillating manometer problems are used as benchmark tests with the generic four‐equation two‐fluid model. For solving the equations implicitly, Newton's method along with a sparse matrix solver (UMFPACK solver) is employed, and the numerical Jacobian matrix is calculated. Comparison between implicit and explicit AUSM‐family schemes is presented, indicating that similarly accurate results are obtained with both schemes. Furthermore, the water faucet problem is solved using both staggered and collocated grids. This investigation helps integrate high‐resolution schemes into staggered‐grid‐based computational algorithms. The influence of the interface pressure correction on the simulation results is also examined. Results show that the interfacial pressure correction introduces numerical dissipation. However, this dissipation cannot eliminate the overshoots because of the incompatibility of numerical discretization of the conservative and non‐conservative terms in the governing equations. The comparison of CPU time between implicit and explicit schemes is also studied, indicating that the implicit scheme is capable of improving the computational efficiency over its explicit counterpart. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
23.
The reaction 125Te(d, p)126Te has been studied at a bombarding energy of 7.5 MeV in order to get information about the 126Te nuclear level scheme. Forty-two levels were observed below an excitation energy of 5.1 MeV. The angular distributions of 25 of the emitted proton groups were compared with DWBA calculations to determine the angular momentum of the captured neutrons. Contributions from more than one ln value were observed for two of the transitions. Transition strengths were extracted and compared to pairing-theory calculations. 相似文献
24.
A novel supramolecular host for the uranyl carbonate complex has been designed and synthesized. The modified cyclodextrin host binds uranyl carbonate in water with a stability of 253 M(-1). 相似文献
25.
[reaction: see text] The 2,2,2-trichloroethyl (TCE) group was utilized as the first protecting group for aryl sulfates. Aryl sulfates, protected with the TCE group, were prepared in high yield by reacting phenols with chlorosulfuric acid TCE ester. Deprotection was accomplished using Pd/C-ammonium formate or with Zn-ammonium formate to give aryl sulfate monoesters in high yield. This approach to aryl sulfate synthesis was successfully applied to the construction of estrone sulfate derivatives, which could not be prepared by previous methodologies. 相似文献
26.
Lien Y de Vries SM van Druten NJ van Exter MP Woerdman JP 《Physical review letters》2001,86(13):2786-2789
We have measured the photon number probability distribution of a laser in which the inversion is not slaved to the field. For the experiments, we have used a Nd(3+):YVO(4) laser which has a sufficiently slow inversion to allow measurement of the photon fluctuations at a time scale much shorter than that of the relaxation oscillations. The photon distribution function becomes highly nonstandard (i.e., non-Poissonian) in such a laser; this is consistent with available theoretical work. We point out the relevance of our results for the case of the semiconductor microlaser. 相似文献
27.
28.
Z. Szeglowski Dinh Thi Lien S. N. Timokhin A. B. Yakushev I. Zvara 《Journal of Radioanalytical and Nuclear Chemistry》2001,247(2):451-452
The seconds living mercury isotopes have been isolated from nuclear reaction products arising in the bombardment of 147Sm target with 40Ar ions at the U-400 cyclotron of JINR-Dubna. 相似文献
29.
This paper investigates asymptotic stability problem for neutral system with interval time-varying delays and two classes of uncertainties. Delay-dependent and delay-independent criteria are proposed to guarantee the asymptotic stability for our considered systems. Lyapunov–Krasovskii functional and Leibniz–Newton formula are applied to find the delay-dependent stability results. Linear matrix inequality (LMI) approach is used to solve the proposed conditions. Finally, some numerical examples are illustrated to show the improvement of this paper. 相似文献
30.
Steve Lien‐Chung Hsu Kuen‐Shian Lin Chi Wang 《Journal of polymer science. Part A, Polymer chemistry》2008,46(24):8159-8169
Polybenzoxazole (PBO) fibers with a submicron diameter were successfully prepared by electrospinning its precursor, polyhydroxyamide (PHA), solutions to obtain the PHA fibers first, followed by appropriate thermal treatments for cyclization reaction. BisAPAF‐IC PHA with two different molecular weights (MWs) were synthesized from a low temperature polymerization of 2,2′‐bis(3‐amino‐4‐hydroxyphenyl) hexafluoropropane (BisAPAF) and isophthaloyl chloride (IC). Using dimethylacetamide (DMAc) and tetrahydrofuran (THF), solvent effects on the electrospinnability of PHA solutions were investigated. For balancing the solution properties, it was found that DMAc/THF mixture with a weight ratio of 1/9 was the best cosolvent to prepare smooth PHA fibers; uniform PHA fibers with a diameter of 325–720 nm were obtained by using 20 wt % PHA/(DMAc/THF) solutions. For a fixed PHA concentration, solutions with a lower MW of PHA yielded thinner electrospun fibers under the same electrospinning condition. After obtaining the electrospun BisAPAF‐IC PHA fibers, subsequent thermal cyclization up to 350 °C produced the corresponding thermally stable BisAPAF‐IC PBO fibers with a diameter of 305–645 nm. The structure of the precursor fibers and the fully cyclized fibers were characterized by FTIR. For the cyclized BisAPAF‐IC PBO fibers, thermogravimetric analysis showed a 5% weight loss temperature at 523 °C in nitrogen atmosphere. The interconnected fiber structure in the BisAPAF‐IC PBO fiber mats was irrelevant to the curing process, but resulted from the jet merging during the whipping process as revealed by the high speed camera images. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 8159–8169, 2008 相似文献