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471.
Electrochemical study of a dendritic family at the water/1,2-dichloroethane interface 总被引:1,自引:0,他引:1
Calderon M Monzón LM Martinelli M Juarez AV Strumia MC Yudi LM 《Langmuir : the ACS journal of surfaces and colloids》2008,24(12):6343-6350
The transfer of six dendritric molecules, DMs, across the water/1,2-dichloroethane interface was investigated using cyclic voltammetry. From the variation of peak potential with pH, two different mechanisms of transfer were postulated depending on the nature of the molecules. Voltammetric parameters were employed to evaluate the hydrophilic/hydrophobic character and calculate the acid dissociation constant of these molecules. The results were explained taking into account the nature and multiplicity of functional surface groups. 相似文献
472.
Cybulski J Wiśniewska A Kulig-Adamiak A Lewicka L Cieniecka-Rosłonkiewicz A Kita K Fojutowski A Nawrot J Materna K Pernak J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(30):9305-9311
A new group of quaternary ammonium lactate based ionic liquids have been prepared and characterized. Didecyldimethylammonium (DDA) and benzalkonium (BA) D,L- and L-lactates are air-stable, hydrophilic, surface-active salts. They are very effective antibacterial and antifungal agents, especially the DDA lactates, against Streptococcus mutants and Candida albicans. Their activities are comparable or more effective than the original benzalkonium chloride. In addition, they have been shown to be good insect-feeding deterrents. However, they are poor antifungal agents for wood preservation. The toxicity of the DDA and BA lactates has also been studied and the results are presented in this paper. 相似文献
473.
Asensio-Ramos M Hernández-Borges J Ravelo-Pérez LM Rodríguez-Delgado MA 《Electrophoresis》2008,29(21):4412-4421
In this work, NACE with UV detection is combined with SPE using multi-walled carbon nanotubes (MWCNT) as stationary phase to determine a group of seven pesticides (pirimicarb, pyrifenox, penconazol, carbendazim, cyromazine, pyrimethanil and cyprodinil) in mineral water samples using ametryn as internal standard. The optimized BGE, consisting of a mixture of MeOH and ACN (1:2 v/v) with 90 mM SDS and 20.5 mM HClO(4), was satisfactory to get a good resolution of the seven compounds in less than 13 min. On-line preconcentration was carried out by electrokinetic injection of the sample dissolved in 78:22 v/v MeOH/ACN, 1.11 mM HClO(4). Repeatability was studied for the same day (n=4), for nine different days (n=36) and for four different capillaries. RSD values were appropriate in all cases, i.e. in the range 4.3-9.4% between different capillaries. MWCNT of 10-15 nm od, 2-6 nm id and 0.1-10 mum length were used as SPE materials for the preconcentration of these pesticides from water samples. SPE parameters influencing the enrichment were optimized and the most favorable conditions were as follows: the amount of stationary phase, eluent, sample pH and sample volume were 40 mg MWCNT, 10 mL ACN and 10 mL dichloromethane containing 5% v/v formic acid, pH 8.0, and 750 mL, respectively. Mean recovery values ranged between 53 and 94% for Milli-Q water and between 47 and 93% for mineral waters (RSD values were in the range 2-16%). The method allowed the determination of these pesticides at concentrations below the maximum residue limits established by the European Union legislation (LOD in the range 27-58 ng/L). When the cost, amount and type of the carbon nanotubes used in this work are compared with those carbon nanotubes previously used in the literature it is clear that the proposed materials can be used as economical stationary phases, even cheaper than conventional SPE cartridges. 相似文献
474.
Lidia Jasińska J. T. Haponiuk A. Balas 《Journal of Thermal Analysis and Calorimetry》2008,93(3):777-781
Dynamic mechanical and thermal properties of poly(ester urethanes) (PEU) cross-linked with styrene have been studied. The
investigated polyurethanes were obtained from 4,4′-diphenylmethane diisocyanate and unsaturated oligo(alkyleneester)diol based
on cis-2-butene-1,4-diol. The conducted analyses dealt with the correlation between the chemical structure of poly(ester urethanes)
and their ability to phase separate as well as their thermal stability. The products of PEU thermal degradation were characterized
using infrared spectroscopy. 相似文献
475.
Lima LM Vicente E Solano B Pérez-Silanes S Aldana I Monge A 《Molecules (Basel, Switzerland)》2008,13(1):78-85
The unexpected tendency of amines and functionalized hydrazines to reduce ethyl 3-phenylquinoxaline-2-carboxylate 1,4-di-N-oxide (1) to afford a quinoxaline 1c and mono-oxide quinoxalines 1a and 1b is described. The experimental conditions were standardized to the use of two equivalents of amine in ethanol under reflux for two hours,with the aim of studying the distinct reductive profiles of the amines and the chemoselectivity of the process. With the exception of hydrazine hydrate, which reduced compound 1 to a 3-phenyl-2-quinoxalinecarbohydrazide derivative, the amines only acted as reducing agents. 相似文献
476.
Ravelo-Pérez LM Hernández-Borges J Angel Rodríguez-Delgado M 《Journal of separation science》2008,31(20):3612-3619
In the present work, a GC method with nitrogen-phosphorus detection (NPD) was developed for the simultaneous determination of eight organophosphorus pesticide (OPP) residues (i.e., ethoprofos, diazinon, chlorpyrifos-methyl, fenitrothion, malathion, chlorpyrifos, fenamiphos, and buprofezin) in water samples. Preconcentration of the water samples was carried out using an SPE procedure with multiwalled carbon nanotubes (MWCNTs) of 10-15 nm od, 2-6 nm id, and 0.1-10 microm length as stationary phase. Extraction parameters, such as the amount of MWCNTs, sample volume, pH, and type and amount of the eluent were optimized. The most favorable conditions were as follows: 40 mg MWCNTs, 800 mL water, pH 6.0, and 20 mL dichloromethane, respectively. The MWCNTs-SPE-GC-NPD method was applied to the determination of these pesticides in real water samples: mineral and ground water as well as run-off water from an agricultural area collected shortly before opening out onto the sea. A recovery study was developed with five consecutive extractions of the three types of water spiked at three concentration levels (n = 15). Mean recovery values were in the range of 75-116% for mineral water (RSD < 6.3%), 67-119% for ground water (RSD < 5.8%), and 57-81% for run-off waters (RSDs < 6.9%), except for fenamiphos (mean recovery values between 40 and 84% for the three types of waters, RSDs < 8.9%). LODs were in the low ng/L level (i.e., levels below the maximum residue limits (MRLs) established by the European Union (EU) legislation for these compounds in waters). The proposed method was also applied to the analysis of six water samples (two of each type: mineral, ground, and run-off waters) in which no residues of the selected pesticides were found. Results show that the MWCNTs used in this work have a high adsorbability of the pesticides under study. The main advantage of the use of these MWCNTs is their low cost when compared with those MWCNTs previously used in the literature and with conventional SPE cartridges. 相似文献
477.
Peroxynitrite (ONOOH/ONOO-) which is formed in vivo under oxidative stress is a strong oxidizing and nitrating agent. It has
been reported that several flavonoids, including quercetin, inhibit the peroxynitrite-induced oxidation and/or nitration of
several molecules tested; however, the mechanism of their protective action against peroxynitrite is not univocally resolved.
The kinetics of the reaction of quercetin with peroxynitrite was studied by stopped-flow as well as by conventional spectrophotometry
under acidic, neutral and alkaline pH. The obtained results show that the protective mechanism of quercetin against peroxynitrite
toxicity cannot be explained by direct scavenging of peroxynitrite. We propose that quercetin acts via scavenging intermediate
radical products of peroxynitrite decomposition (it is an excellent scavenger of ·NO2) and/or via reduction of target radicals
formed in the reaction with peroxynitrite. 相似文献
478.
DS Nesterov EN Chygorin VN Kokozay VV Bon R Boča YN Kozlov LS Shul'pina J Jezierska A Ozarowski AJ Pombeiro GB Shul'pin 《Inorganic chemistry》2012,51(16):9110-9122
The heterometallic complex [Co(4)Fe(2)OSae(8)]·4DMF·H(2)O (1) was synthesized by one-pot reaction of cobalt powder with iron chloride in a dimethylformamide solution of salicylidene-2-ethanolamine (H(2)Sae) and characterized by single crystal X-ray diffraction analysis, magnetic measurements, high frequency electron paramagnetic resonance (HF-EPR), and M?ssbauer spectroscopies. The exchange coupling in the Fe(III)-Fe(III) pair is of antiferromagnetic behavior with J/hc = -190 cm(-1). The HF-EPR spectra reveal an unusual pattern with a hardly detectable triplet signal of the Fe(III) dimer. The magnitude of D (ca. 13.9 cm(-1)) was found to be much larger than in related dimers. The catalytic investigations disclosed an outstanding activity of 1 toward oxidation of cycloalkanes with hydrogen peroxide, under mild conditions. The most efficient system showed a turnover number (TON) of 3.57 × 10(3) with the concomitant overall yield of 26% for cyclohexane, and 2.28 × 10(3)/46%, respectively, for cyclooctane. A remarkable turnover frequency (TOF) of 1.12 × 10(4) h(-1) (the highest initial rate W(0) = 3.5 × 10(-4) M s(-1)) was achieved in oxidation of cyclohexane. Kinetic experiments and selectivity parameters led to the conclusion that hydroxyl radicals are active (attacking C-H bonds) species. Kinetic and electrospray ionization mass spectrometry (ESI-MS) data allowed us to assume that the trinuclear heterometallic particle [Co(2)Fe(Sae)(4)](+), originated from 1 in solution, could be responsible for efficient generation of hydroxyl radicals from hydrogen peroxide. 相似文献
479.
Ciapina EM Melo WC Santa Anna LM Santos AS Freire DM Pereira N 《Applied biochemistry and biotechnology》2006,131(1-3):880-886
The production of biosurfactant by Rhodococcus erythropolis during the growth on glycerol was investigated. The process was carried out at 28 degrees C in a 1.5-L bioreactor using glycerol as carbon source. The bioprocess was monitored through measurements of biosurfactant concentration and glycerol consumption. After 51 h of cultivation, 1.7 g/L of biosurfactant, surface, and interfacial tensions values (with n-hexadecane) of 43 and 15 mN/m, respectively, 67% of Emulsifying Index (E (24)), and 94% of oil removal were obtained. The use of glycerol rather than what happens with hydrophobic carbon source allowed the release of the biosurfactant, originally associated to the cell wall. 相似文献
480.
Bonfill M Mangas S Cusidó RM Osuna L Piñol MT Palazón J 《Biomedical chromatography : BMC》2006,20(2):151-153
The identification of the four principal triterpenoid components of Centella asiatica has been achieved by TLC on silica gel plates and mass spectrometry, as a modification of the method described in the European Pharmacopoeia (5th edn). A combination of ethyl acetate and methanol as the mobile phase was found to be successful in separating these compounds from the rest of the main components of the extract. The spots were detected with anisaldehyde solution. The separated compounds were confirmed by MALDI -TOF mass spectrometry. 相似文献