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Yang Zhao Yue‐Jiao Zhang Jin‐Hui Meng Shu Chen Rajapandiyan Panneerselvam Chao‐Yu Li Sain Bux Jamali Xia Li Zhi‐Lin Yang Jian‐Feng Li Zhong‐Qun Tian 《Journal of Raman spectroscopy : JRS》2016,47(6):662-667
Silver nanoparticles (Ag NPs) enjoy a reputation as an ultrasensitive substrate for surface‐enhanced Raman spectroscopy (SERS). However, large‐scale synthesis of Ag NPs in a controlled manner is a challenging task for a long period of time. Here, we reported a simple seed‐mediated method to synthesize Ag NPs with controllable sizes from 50 to 300 nm, which were characterized by scanning electron microscopy (SEM) and UV–Vis spectroscopy. SERS spectra of Rhodamine 6G (R6G) from the as‐prepared Ag NPs substrates indicate that the enhancement capability of Ag NPs varies with different excitation wavelengths. The Ag NPs with average sizes of ~150, ~175, and ~225 nm show the highest SERS activities for 532, 633, and 785‐nm excitation, respectively. Significantly, 150‐nm Ag NPs exhibit an enhancement factor exceeding 108 for pyridine (Py) molecules in electrochemical SERS (EC‐SERS) measurements. Furthermore, finite‐difference time‐domain (FDTD) calculation is employed to explain the size‐dependent SERS activity. Finally, the potential of the as‐prepared SERS substrates is demonstrated with the detection of malachite green. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
94.
Hu X Jiao X Narayanan S Jiang Z K Sinha S Lurio LB Lal J 《The European physical journal. E, Soft matter》2005,17(3):353-359
We have used measurements of the absolute intensity of diffuse X-ray scattering to extract the interfacial tension of a buried polymer/polymer interface. Diffuse scattering was excited by an X-ray standing wave whose phase was adjusted to have a high intensity at the polymer/polymer interface and simultaneously a node at the polymer/air interface. This method permits the capillary-wave-induced roughness of the interface, and hence the interfacial tension, to be measured independently of the polymer/polymer interdiffusion. 相似文献
95.
对作者所提出的无干涉条纹直接电场重构测量飞秒脉冲的振幅和相位的新方法作出进一步理论分析,并通过实验测量说明该方法的优越性.该方法克服了传统的SPIDER方法的弊病,能得到一组无干涉条纹的图像,排除传统方法必须使用傅里叶变换滤波消除干涉条纹而引进的系统误差,使得该方法能够采用较简便设备且能较准确测量飞秒脉冲强度轮廓和相位.最后给出同一条件下新方法和传统SPIDER方法分别重构的脉冲强度自相关曲线与实验测量结果的比较,以说明新方法的有效性和优越性. 相似文献
96.
H. M. Noor ul Huda Khan Asghar Yi Tan Shuang Shi Dachuan Jiang Shiqiang Qin Jiao Liao Shutao Wen Wei Dong Yao Liu 《Applied Physics A: Materials Science & Processing》2014,115(3):753-757
Small amounts of multicrystalline silicon were melted in an electron beam furnace in different experimental conditions in order to investigate the oxygen evaporation behavior during the electron beam melting (EBM) process. The oxygen content level before and after EBM was determined by secondary ion mass spectroscopy. The oxygen content was reduced from 6.177 to 1.629 ppmw when silicon was melted completely at 15 kW with removal efficiency up to 73.6 %. After that, it decreased continually to <0.0517 ppmw when the refining time exceeded 600 s with a removal efficiency of more than 99.08 %. During the melting process, the evaporation rate of silicon is 1.10 × 10?5 kg/s. The loss of silicon could be reduced up to 1.7 % during oxygen removal process to a desirable figure, indicating EBM is an effective method to remove oxygen from silicon and decrease the loss of silicon. 相似文献
97.
集成芯片LED场地照明灯新型叠片散热器热分析 总被引:1,自引:5,他引:1
针对大功率LED场地照明集成芯片散热问题,提出了一种新型散热器结构。该散热器利用高导热纯铝材料,采用叠片的方式成型。采用实验和有限元模拟相结合的研究方法,对包括直流电源的新型叠片式LED散热器的散热性能进行了研究。结果表明:LED电源达到稳态所需时间较长,最终能够稳定在一个较低的温度范围。叠片式纯铝散热器通过增加散热面积和提高散热器材料的导热系数能有效降低LED结温。所设计的散热器和选择的电源在自然对流条件下能够很好地满足250 W大功率LED散热要求。 相似文献
98.
Configuration-constrained potential-energy-surface calculations have been performed to investigate the K isomerism in the proton-rich A~ 80 mass region. An abundance of high-K states are predicted. These high-K states arise from two and four-quasi-particle excitations, with K~π= 8~+ and K~π= 16~+, respectively. Their excitation energies are comparatively low, making them good candidates for long-lived isomers. Since most nuclei under study are prolate spheroids in their ground states, the oblate shapes of the predicted high-K states may indicate a combination of K isomerism and shape isomerism. 相似文献
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WU GuoXiong State Key Laboratory of Ocean Engineering College of Naval Architecture Ocean Civil Engineering Shanghai Jiao Tong University Shanghai China 《中国科学:物理学 力学 天文学(英文版)》2011,(1)
The sloshing of inviscid liquid of stratified density in a rectangular tank is analyzed.As the flow is no longer irrotional,the governing equation is found to be quite different from the Laplace equation used for the liquid of constant density.In particular it contains terms of mixed temporal and spatial derivatives.The problem is solved based on the variable separation method and Laplace transform for the constant Vaisala-Brunt frequency.It is found that the stratification of density may have small effects... 相似文献