应用不对称一维光子晶体结构制备窄光谱LED

对周期性的GaAlAs／AlAs模块堆积组成的有缺陷的一维光子晶体的光波传输模式进行了理论与实验研究。由于堆积结构的周期性受到破坏,导致了光子晶体中模密度发生变化,光波的传播也发生了变化。对模密度和光的传播模式分别用流行的光子能态理论和光学传输矩阵进行了计算和模拟。计算发现采用不对称结构的一维光子晶体结构在实际应用中有更大的灵活性。用金属有机物化学汽相沉积方法实现一维光子晶体,并用于裁剪普通的发光二极管电致发光谱,在20mA的激发电流下,半峰全宽为2．8mm,单色性优 于共振腔发光二极管。在较大的激发电流下,带边发射的增强现象也被观测到。     

与量子光场相互作用的运动原子的熵压缩

运用量子信息熵理论,研究了与量子光场相互作用的二能级运动原子的熵压缩,讨论了原子运动和场模结构对原子熵压缩的影响,并且比较了分别从基于信息熵测不准关系和海森伯测不准关系出发得出的结果,表明原子的运动导致了原子熵压缩的周期性演化;随着场模结构参量的增大,熵压缩的演化周期缩短,压缩时间延长;选择适当的系统参量,运动原子能够呈现长时间的持续熵压缩效应。当原子反转为零时,基于海伯堡测不准关系的方差压缩定义不再有效,而熵压缩实现了对原子压缩效应的高灵敏量度。     

矩阵方程X+A*X-nA=I的正定解

In this paper we give some sufficient conditions and some necessary conditions under which the matrix equation X A^*X^-nA=I has a positive definite solution. An iterative method which converges to a positive definite solution of this equation is constructed. And an error estimate formula on this iterative method is also derived.     

Europium(II) oxy­iodide

Yellow single crystals of Eu₄OI₆ were grown from fluxes in Ta ampoules and structurally characterized by X‐ray diffraction. Eu₄OI₆ crystallizes in a hexagonal system and is isotypic with the corresponding chloride and bromide compounds. The O atom and one Eu atom lie on sites with 3m symmetry; the other Eu atom and the two unique I atoms are at sites with m symmetry. The structure is characterized by O‐centered tetrahedra of divalent europium cations [Eu—O = 2.391 (15) and 2.416 (5) Å, and mean Eu—Eu = 3.94 Å] and hexagonal channels along [001] filled with iodide anions.     

SYNERGISTIC EFFECT OF Cu-ZSM-5 ZEOLITE ON FLAME RETARDED PP BY MELAMINE SALT OF DIPENTAERYTHRIOL PHOSPHATE

A novel intumnescent flame melamine salt of dipentaerythriol phosphate (MDP),was prepared from dipentaerythritol (DPE) polyphosphoric acid,and melamine.The flammability,combustion behavior,and thermal degradation and stability of PP-MDP were characterized.When MDP loading was 20 wt%,LOI values of the composites reached up to 27%,and UL94 rating,V-2.PP-MDP containing 1 wt% Cu-ZSM-5 presented the highest LOI value of 30.5% and UL94 rating,V-0,and released lest heat during cone test.TG data showed that the ...     

Supramolecular Complexes Based on [M(CN)8]4– (M = Mo,W) and Aliphatic Amine CuII Tectons

Three heterometallic supramolecular complexes [Cu₂(pn)₄(Mo(CN)₈)·4H₂O] (pn = diaminopropane) ( 1 ), [Cu₂(pn)₄(W(CN)₈)·4H₂O] ( 2 ) and [Cu₂(1,2‐pn)₄(H₂O) (W(CN)₈)·3H₂O] ( 3 ) have been synthesized and structurally characterized by single‐crystal X‐ray diffraction studies. Complexes 1 – 3 exhibit three different networks. In 1 , the copper(II) ion is pentacoordinate with a distorted square‐pyramidal arrangement and the network is formed by the incorporation of coordinative linkage between the μ₂ bridge of [Mo(CN)₈]^4– and copper(II) ions and hydrogen‐bonding interactions. In 2 , the copper(II) ion exhibits a distorted square‐pyramidal arrangement and the network is formed by the hydrogen bonded trinuclear complexesof [Cu₂(pn)₂(W(CN)₈)]. In 3 , the copper(II) ions show twodifferent distorted octahedral arrangements. The network structure of 3 is formed by the hydrogen‐bonded complex chains of [Cu₂(1,2‐pn)₂(W(CN)₈)].     

A binary coding method of RNA secondary structure and its application

According to the three classifications of nucleotides, we introduce a sort of binary coding method of RNA secondary structures. On the basis of this representation, we can reduce a RNA secondary structure into three binary digit sequences. We also propose coding rules based on the exclusive‐OR operation. Associating with the proposed coding rules, we can judge the mutation between bases or between base and base pair, and make sequence alignment easily. © 2009 Wiley Periodicals, Inc. J Comput Chem, 2009     

Uricase based methods for determination of uric acid in serum

The most common methods for determination of uric acid in serum are based on the use of the enzyme uricase. Uric acid is enzymatically oxidized by oxygen to produce hydrogen peroxide, allantoin, and carbon dioxide. The four most often applied uricase methods are critically compared in this review.     

An efficient approach to derive hydroxyl groups on the surface of barium titanate nanoparticles to improve its chemical modification ability

Highly hydroxylated barium titanate (BaTiO(3)) nanoparticles have been prepared via an easy and gentle approach which oxidizes BaTiO(3) nanoparticles using an aqueous solution of hydrogen peroxide (H(2)O(2)). The hydroxylated BaTiO(3) surface reacts with sodium oleate (SOA) to form oleophilic layers that greatly enhance the dispersion of BaTiO(3) nanoparticles in organic solvents such as tetrahydrofuran, toluene, and n-octane. The results of Fourier transform infrared spectroscopy confirmed that the major functional groups on the surface of H(2)O(2)-treated BaTiO(3) nanoparticles are hydroxyl groups which are chemically active, favoring chemical bonding with SOA. The results of transmission electron microscopy of SOA-modified BaTiO(3) nanoparticles suggested that the oleate molecules were bonded to the surfaces of nanoparticles and formed a homogeneous layer having a thickness of about 2 nm. Furthermore, the improved dispersion capability of the modified BaTiO(3) nanoparticles in organic solvents was verified through analytic results of its settling and rheological behaviors.     

Carbon-assisted morphological manipulation of CdS nanostructures and their cathodoluminescence properties

CdS nanostructures with different morphologies and sizes were successfully fabricated through a facile and effective carbon-assisted thermal evaporation method. Through simply changing the positions of silicon substrates, the temperatures and the effects of carbon in different zones were modified, and thus the morphologies of CdS nanostructures were varied from multipods to nanobrushes to nanocups. These nanostructures were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectrometry (EDS), X-ray powder diffraction (XRD) and Raman spectroscopy. Cathodoluminescence (CL) measurement shows that the as-grown CdS nanostructures display different luminescent properties. CdS multipods and nanocups show mainly green emission centered at 496 nm. However, nanobrushes exhibit predominant red emission band peaking at 711 nm. These interesting results show that carbon not only affected the growth process but also influenced the properties of CdS nanostructures.