同伦分析方法：一种新的求解非线性问题的近似解析方法

本文描述了一种称为“同伦分析方法”（ＨＡＭ）的新的求解非线性问题的近似解析方法之基本思想·不同于摄动展开方法，“同伦分析方法”的有效性不依赖于所研究的非线性方程中是否含有小参数·因此，该方法提供了一个强有力的分析非线性问题的新工具·作为示例，我们应用一个典型的非线性问题来说明该方法的有效性及其巨大潜力·     

异地时钟同步与时间的度量

介绍了庞加莱等人关于"异地时钟同步"和"相继时间段(绵延)相等"的思考,介绍了爱因斯坦"约定"异地时钟"同时"的方案,以及朗道等人对该方案的发展.我们赞同庞加莱的设想,即对光速传播性质的约定是时间测量的基础,并指出对光速的约定相当于对时空对称性的约定.我们在"约定光速的基础上"给出了钟速同步具有传递性的条件,不仅解决了"异地坐标钟钟速同步"的定义问题,而且解决了"相继时间段相等"的定义问题,证实了庞加莱原初的猜想,简化了时间测量的理论基础.     

间接原子吸收法测定花生壳中木犀草素的含量

1引言木犀草素作为一种天然抗氧化剂,其药用价值很高,具有抗氧化、抗肿瘤、抗动脉粥样硬化、降血糖、抑菌等多种保健和药理作用。目前,其测定方法主要有高效液相色谱法、毛细管电泳法、分光光度法、薄层色谱法。本实验利用碱式乙酸铅做木犀草素的络合沉淀剂产生难溶的淡黄色沉淀,通过原子吸收法测定上清液中Pb2 的浓度,从而得到一种间接测定花生壳中木犀草素的方法。本法具有简便、快速、灵敏度高、试剂用量少等优点,用于实际样品测定,结果满意。2实验部分2.1仪器和试剂TAS-986原子吸收分光光度计(北京普析通用仪器有限公司);铅空心阴极灯…     

页岩矿物不同润湿性表征与吸附微观机理

无机矿物作为页岩气吸附的重要载体,其表面性质对甲烷吸附能力有着重要影响,而润湿性作为固体重要表面性质之一,对矿物气体吸附能力的影响不可忽视.文章以蒙脱石和石英作为研究对象,通过对矿物表面甲基化(-CH₃)和羟基化(-OH)处理来改变其润湿性,以探究无机矿物表面润湿性对甲烷吸附能力的影响.采用分子动力学方法研究矿物体系的润湿性,用接触角对润湿性进行定量表征,并构建纳米狭缝,结合巨正则蒙特卡罗方法模拟润湿性改变前后,CH₄在矿物中的吸附变化.研究结果表明,水滴在羟基化矿物表面迅速破裂并铺展在矿物表面,而在甲基化表面铺展程度较小,普遍呈半球形.羟基化蒙脱石和石英表面的润湿接触角分别为12.7°和26.5°,均小于其甲基化表面接触角62.5°和85.7°.甲基化矿物甲烷吸附量均高于其羟基化,气体几乎大都以吸附状态位于孔隙壁面,随着矿物亲水性的减弱,其对甲烷吸附能力增强.     

Analysis and Comparison Constituent of the Essential Oil from Three Different Species of Achillea L. in the Northern Slope of Tianshan Mountains

Moscow University Chemistry Bulletin - The genus Achillea L. (Family: Asteraceae) is a kind of perennial plant, mostly distributed in north western region of China, especially in Tianshan Mountains...     

A Facile Reduction Procedure for Nitroarenes with Cp2TiCl2/Sm System

Nitroarenes can be reduced to the corresponding primary amines in good yields with Cp₂TiCl₂/Sm system under mild and neutral conditions.     

A three-step system calibration procedure with error compensation for 3D shape measurement

System calibration, which usually involves complicated and time-consuming procedures, is crucial for any three-dimensional （3D） shape measurement system based on vision. A novel improved method is proposed for accurate calibration of such a measurement system. The system accuracy is improved with considering the nonlinear measurement error created by the difference between the system model and real measurement environment. We use Levenberg-Marquardt optimization algorithm to compensate the error and get a good result. The improved method has a 50% improvement of re-projection accuracy compared with our previous method. The measurement accuracy is maintained well within 1.5% of the overall measurement depth range.     

Synthesis and Biological Activities of Diosgenin-Triazole Conjugates with a 1,3-Dipolar Cycloaddition Reaction

Chemistry of Natural Compounds - A novel series of diosgenin-triazole conjugates (10a–d, 11a–c, 12a–c, 13a–c) was designed and synthesized as antifungal agents by using a...     

Michael Addition Catalyzed by Chiral Secondary Amine Phosphoramide Using Fluorinated Silyl Enol Ethers: Formation of Quaternary Carbon Stereocenters

A chiral secondary amine phosphoramide was developed and identified as a powerful catalyst for the Mukaiyama–Michael addition of fluorinated enol silyl ethers to tetrasubstituted olefins. The resulting products are obtained with high enantioselectivities and contain a quaternary carbon stereocenter bearing either a difluoroalkyl or monofluoroalkyl group.