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131.
纳米颗粒在纳米医药、细胞成像等领域有着非常广泛的应用,深入理解纳米颗粒与生物膜之间相互作用的微观机制是纳米颗粒合成与应用的重要基础.本文采用粗粒化分子动力学模拟的方法研究了带电配体包裹的金纳米颗粒与相分离的带电生物膜之间的相互作用.结果表明,通过改变金纳米颗粒表面的配体密度、配体带电种类和比例,以及膜内带电脂分子的种类,可以方便地调控纳米颗粒在膜表面或膜内停留的位置和状态.进一步从自由能的角度分析了带电纳米颗粒与带电生物膜之间相互作用的微观物理机制.本文对纳米粒子在纳米医药、细胞成像等领域的应用具有一定的理论参考意义. 相似文献
132.
Acta Mathematicae Applicatae Sinica, English Series - In this paper, we investigate standing waves in discrete nonlinear Schrödinger equations with nonperiodic bounded potentials. By using the... 相似文献
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Jinghu Liang Antonio Bolea Albero Jendrik Füller Christel Müller-Goymann Markus Böl 《PAMM》2016,16(1):95-96
Wound healing in epidermis is a complex physiological process in which new cells are created to repair the damaged tissue. The timing of cell division and growth mechanisms in wound healing are influenced by biological, mechanical and medical factors. In this work we aim to provide a numerical model based on the observations realised in in-vitro experiments for the understanding of wound healing. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
137.
The photoreduction behavior of alkyl viologen compounds in a PVA matrix was investigated. The initial photoreduction of alkyl viologens and related polyviologens follows second-order reaction kinetics, and the respective rate constants, which vary only slightly with alkyl chain length, were determined. While the polymer effect was not remarkable in a PVA matrix, the association behavior of radical cations was similar to that found in a 2-propanol aqueous solution. 相似文献
138.
Y. E. Du Z. Q. Xing Y. F. Liang Z. B. Han 《Russian Journal of Coordination Chemistry》2013,39(1):114-118
A new metal-organic coordination polymer [Zn(Pydc)(Dppz)] n (I) (H2Pydc = 2,6-pyridinedicarboxylic acid, Dppz = dipyrido[3,2-a:2′,3′-c]phenazine) was hydrothermally synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The X-ray diffraction analysis reveals that I crystallizes in the monoclinic system, space group P21/c. The Pydc2? ligands adopt O,N,O′-tridentate chelating and monodentate bridging coordination mode to link two adjacent Zn2+ ions to form a one-dimensional (1D) zigzag chain. The adjacent chains are further linked through hydrogen bonds and π-π stacking interactions, forming a three-dimensional (3D) supramolecular framework. The unit cell parameters for I: a = 7.332(3) Å, b = 36.023(9) Å, c = 7.8838(13) Å, β = 105.65(3)○, V = 2005.1(10) Å3, Z = 4. 相似文献
139.
Well-dispersed graphene materials reduced by Ac under hydrothermal condition were used as conductive additives to improve intrisic disadvantage of promising LiFePO4 battery materials, which was synthesized at surface of graphene sheets. The as-prepared LiFePO4/graphene composites were characterized by X-ray powder diffraction (XRD), scan electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge tests. The results show that, compared with conventional LiFePO4 platelets, the composite deliver excellent electrochemical performances, due to flexible graphene-based porous conducting network. We believe that such a facile process will provide a new pathway for further enhancing its energy storage efficiency. 相似文献
140.
Lipid profiling of human plasma from peritoneal dialysis patients using an improved 2D (NP/RP) LC-QToF MS method 总被引:1,自引:0,他引:1
Min Li Baosheng Feng Yuan Liang Wei Zhang Yu Bai Wen Tang Tao Wang Huwei Liu 《Analytical and bioanalytical chemistry》2013,405(21):6629-6638
An improved online two-dimensional liquid chromatography-quadrupole time-of-flight mass spectrometry (2D LC-QToF MS) system was developed for the lipid profiling of human plasma, in which different lipid classes were separated by the first dimensional normal-phase (NP) LC and different lipid molecular species were separated by the second dimensional reversed-phase (RP) LC. This 2D LC-QToF MS system was built based on a ten-port, two-position valve as the interface, the conditions of which had been optimized and discussed in detail. As two loops were used to trap and transfer the first dimensional elute to the second dimension separately, this new interface suppressed the sample band broadening in the first dimensional column, increased the recovery and repeatability of 2D LC interface, and offered the possibility for the realization of not-stop-flow NP/RP 2D LC system. Finally, 190 endogenous lipid species out of 10 lipid classes were determined within a single run from the plasma of peritoneal patients. This method was also applied to identify the difference in lipid profile between plasma from peritoneal dialysis patients with bad volume status and peritoneal dialysis patients with good volume status. The discovery of 30 potential biomarkers would be helpful to the malnutrition, inflammation, and atherosclerosis syndrome investigation. 相似文献