Synthesis of Palladium and Nickel Complexes with Octaphenyltetraazaporphyrins

Palladium(II) and nickel(II) complexes with octaphenyltetraazaporphyrin, octakis(4-bromophenyl)tetraazaporphyrin, and octakis(4-nitrophenyl)tetraazaporphyrin were obtained by reactions of octaphenyltetraazaporphyrin, Mg octaphenyltetraazaporphyrin, octakis(4-bromophenyl)tetraazaporphyrin, and octakis(4-nitrophenyl)tetraazaporphyrin with palladium(II) and nickel(II) chlorides in DMF.     

Pattern Search Method for Discrete <Emphasis Type="Italic">L</Emphasis><Subscript>1</Subscript>–Approximation

We propose a pattern search method to solve a classical nonsmooth optimization problem. In a deep analogy with pattern search methods for linear constrained optimization, the set of search directions at each iteration is defined in such a way that it conforms to the local geometry of the set of points of nondifferentiability near the current iterate. This is crucial to ensure convergence. The approach presented here can be extended to wider classes of nonsmooth optimization problems. Numerical experiments seem to be encouraging. This work was supported by M.U.R.S.T., Rome, Italy.     

Complex projections of completely positive quaternionic maps

We show that the complex projection of a completely positive quaternionic map of quaternionic density matrices is a positive map in the space of complex density matrices, and we briefly outline some of its properties. To illustrate this result, we study the complex projection of a one-parameter quaternionic unitary dynamics of a spin-1/2 quantum system. __________ Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 151, No. 3, pp. 360–370, June, 2007.     

Certain constructions of asymptotic analysis related to the Stone-Čcech compactification

The paper considers the representations of attraction sets in topological spaces and their relations with the relaxation of accessibility problems under the conditions of sequentially relaxed constraints. The author studies the structure of approximate (in essence, asymptotic) solutions and generalized elements and establishes the possibility of their real identification for a certain version (related to the Stone-Čech compactification and the Wallman relaxation) of relaxation of the initial problem. __________ Translated from Sovremennaya Matematika i Ee Prilozheniya (Contemporary Mathematics and Its Applications), Vol. 26, Nonlinear Dynamics, 2005.     

Influence of ionizing radiation on the magnetically sensitive properties of planar triacs

Changes in the magnetically sensitive properties of multilayer semiconductors devices, such as planar diffusion triacs, that are related to atomic-displacement-induced defects and ionization by irradiation are considered. It is shown that irradiation may significantly raise the magnetic sensitivity of the triacs. Processes and underlying mechanisms responsible for the improvement of the magnetic sensitivity under the action of a number of galvanomagnetic effects are studied.     

Ab-initio simulation of elastic constants for some ceramic materials

Athermal elasticity for some ceramic materials (α-Al₂O₃, SiC (α and β phases), TiO₂ (rutile and anatase), hexagonal AlN and TiB₂, cubic BN and CaF₂, and monoclinic ZrO₂) have been investigated via density functional theory. Energy-volume equation-of-state computations to obtain the zero pressure equilibrium volume and bulk modulus as well as computations of the full elastic constant tensor of these ceramics at the experimental zero pressure volume have been performed. The present results for the single crystal elasticity are in good agreement with experiments both for the aggregate properties (bulk and shear modulus) and the elastic anisotropy. In contrast, a considerable discrepancy for the zero pressure bulk modulus of some ceramics evaluated from the energy-volume fit to the computational zero pressure volume has been observed.     

Ultrafast creation and annihilation of space-charge domains in a semiconductor superlattice observed by use of Terahertz fields

We report an experimental study indicating ultrafast creation and annihilation of space-charge domains in a semiconductor superlattice under the action of a THz field. Our experiment was performed for an InGaAs/InAlAs superlattice with the conduction electrons undergoing miniband transport. We applied to a superlattice a dc bias that was slightly smaller than a critical bias necessary for the formation of space-charge domains caused by a static negative differential conductivity. Additionally subjecting the superlattice to a strong THz field, resulted in a dc transport governed by the formation of domains if the frequency of the field was smaller than an upper frequency limit (~3 THz). From this frequency limit for the creation and annihilation of domains we determined the characteristic time of the domain buildup. Our analysis shows that the buildup time of domains in a wide miniband and heavily doped superlattice is limited by the relaxation time due to scattering of the miniband electrons at polar optic phonons. Our results are of importance for both an understanding of ultrafast dynamics of pattern formation in nanostructures and the development of THz electronic devices.Received: 25 March 2004, Published online: 23 July 2004PACS: 72.20.Ht High-field and nonlinear effects - 72.30. + q High-frequency effects; plasma effects - 73.21.Cd SuperlatticesK.N. Alekseev: Permanent address: Department of Physical Sciences, P.O. Box 3000, University of Oulu FIN-90014, Finland.     

Study of the Structure and Sorption Properties of Some Types of Cellulose

The pulsed NMR, isopiestic and pycnometric methods are applied to investigate the physicochemical properties of softwood [GOST (State Standard) 9571-89] and hardwood [GOST 28172-89] celluloses, as well as flax cellulose [GOST 10330-76, 9394-76], both in the initial state and subjected to chemical treatment. Possible changes occurring in the supramolecular structure of a polymer are analyzed. The structural and sorption characteristics of the investigated samples are calculated. Their water absorption capacities are determined.     

Formation of Supersonic Zones and Local Separation Zones in Transonic Steady-State Flow Past Surface Roughness in the Free Interaction Regime

Within the framework of free interaction theory numerical methods are used to investigate the occurrence of supersonic zones with shocks in the outer inviscid region for flow past roughness in the lower viscous sublayer, with and without the formation of local separation zones.