全文获取类型
收费全文 | 2239篇 |
免费 | 284篇 |
国内免费 | 285篇 |
专业分类
化学 | 1717篇 |
晶体学 | 28篇 |
力学 | 127篇 |
综合类 | 23篇 |
数学 | 270篇 |
物理学 | 643篇 |
出版年
2024年 | 5篇 |
2023年 | 31篇 |
2022年 | 66篇 |
2021年 | 63篇 |
2020年 | 66篇 |
2019年 | 75篇 |
2018年 | 70篇 |
2017年 | 57篇 |
2016年 | 79篇 |
2015年 | 102篇 |
2014年 | 110篇 |
2013年 | 146篇 |
2012年 | 187篇 |
2011年 | 183篇 |
2010年 | 132篇 |
2009年 | 119篇 |
2008年 | 138篇 |
2007年 | 132篇 |
2006年 | 123篇 |
2005年 | 112篇 |
2004年 | 100篇 |
2003年 | 83篇 |
2002年 | 102篇 |
2001年 | 76篇 |
2000年 | 53篇 |
1999年 | 65篇 |
1998年 | 39篇 |
1997年 | 36篇 |
1996年 | 34篇 |
1995年 | 19篇 |
1994年 | 33篇 |
1993年 | 28篇 |
1992年 | 19篇 |
1991年 | 17篇 |
1990年 | 15篇 |
1989年 | 11篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1986年 | 9篇 |
1985年 | 13篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 6篇 |
1976年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有2808条查询结果,搜索用时 15 毫秒
141.
通过一锅水热法制备了一系列磷改性Ni-Al-O催化剂(Px-Ni-Al-O),以O2为氧化剂,评价了系列催化剂的乙烷氧化脱氢制乙烯性能。结果表明,助剂P的掺入不仅可以减小NiO晶粒的尺寸,还影响了Ni和Al之间的相互作用。在350~475℃的温度范围内,P改性Ni-Al-O催化剂上乙烯选择性均高于未改性的催化剂,且适量P的引入还可以提高乙烷转化率。当反应温度为475℃时,P0.15-Ni-Al-O催化剂上乙烯选择性和收率分别为61.4%和31.9%。此外,P改性后的催化剂表现出较强的抗积碳性能,连续反应22 h不失活。 相似文献
142.
Xiaotong Fan Dr. Kai Huang Prof. Long Chen Haipeng You Menglei Yao Prof. Hao Jiang Prof. Ling Zhang Prof. Cheng Lian Dr. Xiangwen Gao Prof. Chunzhong Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2023,135(2):e202215342
Supercapacitor represents an important electrical energy storage technology with high-power performance and superior cyclability. However, currently commercialized supercapacitors still suffer limited energy densities. Here we report an unprecedentedly respiring supercapacitor with chlorine gas iteratively re-inspires in porous carbon materials, that improves the energy density by orders of magnitude. Both electrochemical results and theoretical calculations show that porous carbon with pore size around 3 nm delivers the best chlorine evolution and adsorption performance. The respiring supercapacitor with multi-wall carbon nanotube as the cathode and NaTi2(PO4)3 as the anode can store specific energy of 33 Wh kg−1 with negligible capacity loss over 30 000 cycles. The energy density can be further improved to 53 Wh kg−1 by replacing NaTi2(PO4)3 with zinc anode. Furthermore, thanks to the extraordinary reaction kinetics of chlorine gas, this respiring supercapacitor performs an extremely high-power density of 50 000 W kg−1. 相似文献
143.
蒸发效率和传输效率是影响电热蒸发-电感耦合等离子体质谱(ETV-ICP-MS)技术分析性能的关键因素。综述有关气溶胶传输效率的研究进展,在归纳常用的传输系统评价方法的基础上,重点对影响气溶胶传输效率的电热蒸发装置的改进、蒸发过程的探讨、基体改进剂的选择等研究现状进行评述。有关ETV蒸发过程中基体干扰的作用机制仍有待进一步系统研究,这对于校正策略的优化、新型校正技术的创新与集成具有重要的理论指导意义,可推动ETV-ICP-MS在地质、环境、生物等学科的更广泛应用。 相似文献
144.
Antibacterial cotton helps prevent the growth and spread of harmful microorganisms, reduces the risk of infection, and has a prolonged service life by reducing bacterial degradation. However, most antibacterial agents used are toxic to humans and the environment. Citronellol-poly(N,N-dimethyl ethyl methacrylate) (CD), a highly effective antibacterial polymer, is synthesized from natural herbal essential oils (EOs). CD exhibited efficient, rapid bactericidal activity against Gram-positive, Gram-negative, and drug-resistant bacteria. Citronellol's environmental benignity makes CDs less hemolytic. Notably, negligible drug resistance developed after 15 bacterial subcultures. The CD-treated cotton fabric displayed better antibacterial performance than AAA-grade antibacterial fabric, even after repeated washing. This study extends the practical application of EOs to antibacterial surfaces and fabrics, which is promising for use in personal care products and medical settings. 相似文献
145.
146.
A method is described for the determination of aldicarb and its metabolites (the sulphoxide and sulphone) in urine by gas chromatography with flame photometric detection (GC-FPD). The sample was concentrated with a column containing activated charcoal and Florisil, and then eluted with dichloromethane-acetone (1:1, v/v). The aldicarb and aldicarb sulphoxide in the eluate solution were oxidized to aldicarb sulphone and the total sulphone concentration was determined by GC-FPD after extraction with dichloromethane and clean-up with an activated charcoal column. The detection limit was 0.0024 mg/l. The mean recoveries from spiked urine in the range 0.04-0.12 mg/l were 90.9%, 86.6%, 92.6% for aldicarb, aldicarb sulphoxide and aldicarb sulphone, respectively. 相似文献
147.
建立了碱消解-火焰原子吸收光谱法测定土壤中六价铬的方法.讨论了pH值对六价铬测定的影响.干扰实验的结果表明同等含量的三价铬对六价铬测定无干扰.实验对比了无背景校正、氘灯背景校正、塞曼背景校正三种工作方式,分别对低、中、高三个水平土壤六价铬标准物质进行了测定,结果表明,低含量的土壤样品用塞曼背景校正方式测定的结果更准确,... 相似文献
148.
Aptamer is an oligonucleotide chain with specific binding ability to protein and other targets,which is widely used in ma ny fields.Because of its ability to screen the premise of unknown targets,it can be used to discover some novel tumor markers,i.e.,membrane proteins that are specifically highly expressed on the surface of tumor cells.Tumor markers can be used in many fields such as early diagnosis and treatment,and a new type of tumor marker proved to be effective can significantly improve the therapeutic effect of such tumors.However,further characterization of newly acquired membrane proteins is essential for their clinical use as tumor markers.This review first briefly introduced the process of obtaining novel tumor markers from nucleic acid aptamers.Next,the commonly used protein characterization methods could be used as a technical means to identify membrane protein targets corresponding to tumor cell aptamers,to clarify the principles,advantages and disadvantages of various means,and to analyze the most suitable situations for various experimental methods.Finally,the outlook was made and the characterization methods that should be used in such experiments were summarized. 相似文献
149.
Pua Aileen Goh Rui Min Vivian Ee Kim-Huey Huang Yunle Liu Shao Quan Lassabliere Benjamin Yu Bin 《Chromatographia》2021,84(5):507-515
Chromatographia - The separation of isomers is one of the key issues in analysing complex natural matrices, thus commanding a higher separating power from the applied analytical system. In this... 相似文献
150.
Chromatographia - The application of temperature gradient interaction chromatography (TGIC) as an advanced technique for the characterisation of polymers is discussed, in comparison to other liquid... 相似文献