A novel method of rapidly modeling optical properties of actual photonic crystal fibres

<正>The flexible structure of photonic crystal fibre not only offers novel optical properties but also brings some difficulties in keeping the fibre structure in the fabrication process which inevitably cause the optical properties of the resulting fibre to deviate from the designed properties.Therefore,a method of evaluating the optical properties of the actual fibre is necessary for the purpose of application.Up to now,the methods employed to measure the properties of the actual photonic crystal fibre often require long fibre samples or complex expensive equipments.To our knowledge, there are few studies of modeling an actual photonic crystal fibre and evaluating its properties rapidly.In this paper,a novel method,based on the combination model of digital image processing and the finite element method,is proposed to rapidly model the optical properties of the actual photonic crystal fibre.Two kinds of photonic crystal fibres made by Crystal Fiber A/S are modeled.It is confirmed from numerical results that the proposed method is simple,rapid and accurate for evaluating the optical properties of the actual photonic crystal fibre without requiring complex equipment.     

128× 128 InSb探测器结构模型研究

热冲击下红外焦平面探测器的高碎裂概率制约着其成品率.为明晰碎裂机理, 基于等效设想, 利用小面阵等效大面阵解决了128×128面阵探测器三维结构建模所需单元数过多的问题, 同时综合考虑材料线膨胀系数的温度依赖性、材料强度的各向异性、表面加工损伤效应, 合理选取InSb材料性能参数, 建立起128×128面阵探测器结构有限元分析模型.模拟结果表明:热冲击下最大Von Mises 应力值出现在N电极区域, 其极值呈非连续分布, 这意味着热冲击下128×128面阵探测器的裂纹起源于N电极区域, 且不止一条.上述结论与碎裂统计分析报告中典型裂纹起源地及裂纹分布这两方面相符合, 这为后续面阵探测器碎裂诱因的研究及结构可靠性设计提供了切实可行的研究思路．     

一种覆盖全通信波段的新型宽带偏振无关双芯光纤定向耦合器的研究

提出了一种新型的双芯光子晶体光纤, 应用全矢量有限元方法分析了光纤各种结构参数对光纤宽带特性和偏振无关特性的影响. 在此基础上优化设计了一种50:50的双芯光子晶体光纤耦合器, 在1.225—1.675 μm波长范围内实现分光比小于1%、两偏振态之间的分光比差小于0.5%的优良特性. 由于引入了仅对偏振特性影响明显的相对独立的中心调制区, 不仅降低了光纤的优化设计难度, 而且实现了与普通单模光纤相匹配的模场特性, 能有效地降低耦合器的接续损耗与制作难度. 研究成果为研制接续损耗低、超宽工作带宽、偏振不敏感等特性的新型光定向耦合器提供了理论基础.     

A Lewis acid-promoted reduction of acylsilanes to α-hydroxysilanes by diethylzinc

We report here the first example of the reduction of acylsilanes to α-hydroxysilanes, in which diethylzinc was used as a highly reactive agent in the presence of Ti(OiPr)₄ or other Lewis acids. The reduction typically proceeds to give synthetically useful α-hydroxysilanes in good yields.     

Preparation of Realgar Nanoparticle Suspension and Its Inhibition Effect on the Proliferation of Human Myelocytic Leukaemia HL-60 Cells

Realgar (As₄S₄) has recently been proved effective in the treatment of leukaemia in clinical trials. However, the poor solubility of realgar makes it difficult to conduct mechanistic study in cellular level. In this work, we prepared realgar nanoparticle (RNP) suspension and examined its effect on the proliferation of human myelocytic leukaemia HL-60 cells. The average diameter of the particles was 143 nm and was stable against coalescence over a 15-month storage. The suspension inhibited cell proliferation dose-dependently at concentrations from 10 to 60 µM (As), a fact shedding light on the mechanism of realgar's clinical effectiveness against hematopoietic malignancies.     

Two cadmium compounds with adenine and carboxylate ligands: syntheses,structures and photoluminescence

Two cadmium(II) coordination compounds, [Cd₃(CH₃CO₂)₄(ad)₂(CH₃CN)₂]_n (1) and [Cd₃(5-SIP)₂(H-ad)₂(H₂O)₆]_n (2) (H-ad = adenine and 5-SIP = 5-sulfoisophthalate), were synthesized and characterized. Compound 1 features a two-dimensional (2-D) layered structure based on linear trinuclear [Cd₃(CH₃CO₂)₄] units bridged by monoanionic adenine ligands. In 2, the 5-SIP^3? ligands link Cd(II) ions to form a one-dimensional (1-D) ladder, which is further linked by neutral adenine ligands to give a 2-D layered structure. In both structures, the carboxylate ligands link Cd(II) ions to form low-dimensional structures, which are further connected by adenine ligands to give high-dimensional structures. Compounds 1 and 2 exhibit emissions centered at 382 and 416 nm, respectively, which can be attributed to the ligand centered π–π* transition.     

介孔锆柱撑钛酸盐材料的制备、表征及光催化性能

采用单分子层剥离-重堆积技术将聚合羟基锆离子嵌入到钛酸盐板层间,制得层间距为1.92~2.01nm的介孔钛酸盐柱撑复合材料。X-射线衍射（XRD）、热重-示差扫描热分析（TG-DSC）、扫描/透射电镜（SEM/HR-TEM）和N₂吸附等手段对材料物化性质进行了分析。结果表明,客体锆离子主要以[Zr₄（OH）_16-n（H₂O）_8+n]n⁺（记为Zr₄）的形式存在于主体层间域中,且柱撑体系中n_Zr/n_Ti比越小,越有利于获得层间距和比表面积较大的柱撑材料。紫外光降解亚甲基蓝实验表明,柱撑材料对亚甲基蓝降解率为钛酸盐主体的3.5倍,这与柱撑形成的介孔结构以及主客体间的电子耦合有关;350℃热处理后材料对亚甲基蓝的降解率进一步提高,说明主客体间形成了更有效的欧姆接触。     

Silicon-based Lewis acid assisted cinchona alkaloid catalysis: highly enantioselective aza-Michael reaction under solvent-free conditions

The study showed that a combination of an achiral silicon-based Lewis acid and chiral Lewis base, such as iodotrimethylsilane (TMSI) and cinchonine, generated a highly enantioselective catalyst system under solvent-free conditions which gave aromatic β-amino ketones with up to >99% ee. Mechanistic studies demonstrate the enhanced asymmetric induction may be due to the combined and competitive activation of a carbonyl moiety of chalcone with cinchonine and the silicon-based Lewis acid in the aza-Michael reaction.     

SiO2粉末中均苯四甲酸铕稀土配合物的发光性质

采用溶胶-凝胶法，以掺杂方式制备了含有均苯四甲酸铕稀土配合物的SiO2粉末转光材料。讨论了协同发光离子对其发光强度的影响，研究了他们的激发光谱和发射光谱，并与其纯配合物固体粉末进行了比较。     

CTAB-Ti-Co-β沸石的制备、表征及其对环己烯水合催化性能

用十六烷基三甲基溴化铵(CTAB)对Ti-Co-β沸石表面进行修饰,制得了两亲性CTAB-Ti-Co-β沸石。通过XRD、IR、DRSUV-Vis、TG-DTA、SEM和XPS等技术对样品进行了表征。结果表明:所制得的CTAB-Ti-Co-β沸石具有BEA拓扑结构,很高的结晶度,Ti和Co两种杂原子已进入沸石骨架。CTAB-Ti-Co-β沸石同时具有亲水和亲油性,对环己烯水合反应具有较高的催化活性,环己烯的转化率和环己醇的选择性分别高达20.6%和99.7%。