全文获取类型
收费全文 | 2027篇 |
免费 | 557篇 |
国内免费 | 806篇 |
专业分类
化学 | 1651篇 |
晶体学 | 100篇 |
力学 | 104篇 |
综合类 | 55篇 |
数学 | 241篇 |
物理学 | 1239篇 |
出版年
2023年 | 18篇 |
2022年 | 77篇 |
2021年 | 60篇 |
2020年 | 59篇 |
2019年 | 53篇 |
2018年 | 64篇 |
2017年 | 99篇 |
2016年 | 80篇 |
2015年 | 109篇 |
2014年 | 142篇 |
2013年 | 202篇 |
2012年 | 210篇 |
2011年 | 185篇 |
2010年 | 197篇 |
2009年 | 172篇 |
2008年 | 224篇 |
2007年 | 214篇 |
2006年 | 181篇 |
2005年 | 140篇 |
2004年 | 124篇 |
2003年 | 92篇 |
2002年 | 101篇 |
2001年 | 91篇 |
2000年 | 92篇 |
1999年 | 47篇 |
1998年 | 21篇 |
1997年 | 16篇 |
1996年 | 16篇 |
1995年 | 14篇 |
1994年 | 19篇 |
1993年 | 22篇 |
1992年 | 18篇 |
1991年 | 16篇 |
1990年 | 9篇 |
1989年 | 12篇 |
1988年 | 7篇 |
1987年 | 9篇 |
1986年 | 7篇 |
1985年 | 9篇 |
1984年 | 13篇 |
1983年 | 10篇 |
1982年 | 10篇 |
1980年 | 6篇 |
1978年 | 11篇 |
1966年 | 9篇 |
1965年 | 44篇 |
1964年 | 12篇 |
1959年 | 7篇 |
1958年 | 6篇 |
1957年 | 4篇 |
排序方式: 共有3390条查询结果,搜索用时 203 毫秒
41.
郭黎平 《高等学校化学学报》1993,14(1):29-32
本文将自制Y式玻碳电极拉上两性接枝星形聚合物(GPSMA)的LB膜,用循环伏安法研究谈膜的屏蔽效应,讨论了接枝量、成膜条件等对膜缺陷的影响,并提出了减少缺陷的办法。 相似文献
42.
43.
YanHongCHANG TaoJIANG LiangGAO GuoYingZHAO HaiXianzGAO ZhongHaoLI JunChunLI ZhiMinLiu BuXingHAN 《中国化学快报》2003,14(10):1070-1072
Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried out in SC CO2. It has been observed that co-solvent affects conversion and selectivity of the reaction considerably. 相似文献
44.
Molecular switches that are controllable, reversible and readable at molecular level are an essential compo-nent of molecular electronics1 and chemical sensors.2-6 Of particular interest are the molecules which show dramatic and reversible changes in color and/or lumi-nescence in visible spectral region upon exposure to specific substrates. A number of chromophore- spacer-receptor systems that can selectively recognize specific guest molecules at their receptor site and pro-duce measurable col… 相似文献
45.
[structure: see text] Platinum(II) terpyridyl acetylide complex (1) was incorporated into Nafion membranes as a photosensitizer, and the Nafion was immersed in an aqueous or organic solution of 7-dehydrocholesterol, alpha-pinene, or cyclopentadiene. This photosensitizer system can generate singlet oxygen ((1)O(2)) in high quantum yield to oxidize the alkenes in the solution outside the Nafion and can be easily removed from the reaction vessel at the end of the photooxidation. 相似文献
46.
Introduction Luminescent coordinatively unsaturated platinum(II) complexes are appealing from photochemical and pho-tophysical perspective.1,2 In particular, platinum(II) ter-pyridyl complexes have attracted considerable attention due to their rich spectroscopic2a-d and biological proper-ties.2a,e-g However, the development of the photochem-istry of these complexes is limited by their short-lived MLCT excited state in solution at room temperature. The lack of emission originates from low-l… 相似文献
47.
48.
Photosensitized oxidation of trialkylalkenes 2-methyl-2-pentene (1), 1-methylcyclohexene (2), trans-3-methyl-2-pentene (3), cis-3-methyl-2-pentene (4), and 2-methyl-2-butene (5) included in the internal framework of Na-ZSM-5 zeolites was investigated. The zeolite samples having adsorbed the alkenes were suspended in isooctane, and the sensitizer, tetraphenylporphyrin (TPP), was dissolved in the solution. Singlet oxygen produced in the solution diffused into the internal framework of the zeolites and reacted with alkenes. For all the substrates studied, the ene-type allylic hydroperoxides were obtained in a highly regioselective manner. The regiochemistry for 1-4 in favor of the allylic hydrogen abstraction from the largest substituents is in contrast to their photooxidation within the dye-supported zeolite Na-Y, where the secondary hydroperoxides are preferentially produced. The tight confinement of the alkenes within the narrow channels of the ZSM-5 zeolites is likely to be responsible for this selectivity. 相似文献
49.
可生物降解聚合物药物释放数学模拟研究进展 总被引:1,自引:0,他引:1
由于可降解的聚合物作为药物载体可以使得药物释放具有较高的靶向性、药物释放更加平缓 ,特别是可以使一些不稳定、半衰期短的药物在人体内达到可控制释放的效果 ,因此将可降解聚合物应用于药物释放体系中作为药物载体得到了较深入的研究。随着研究的深入 ,通过数学方法模拟或预测聚合物载体的降解过程以及聚合物降解过程中药物的释放行为是控释体系设计与应用的一个重要发展方向。由于影响因素较多 ,将所有因素逐一考虑将使得数学模型过于庞杂而失去实际意义 ,所以一个数学模型通常只考虑最主要几个的影响因素 ,并对药物释放系统进行相应的假设。目前文献中报道的降解 (溶蚀 )控制药物释放体系的数学模型大致可以分为两类 :假设药物释放按照零级过程 (zeroorderprocess)进行的经验模型和考虑影响药物释放的多种物理化学过程(如局部传质、化学反应 )的理论模型。本文综述了这些理论模型及其研究进展 相似文献
50.
Zr柱撑蒙脱土上负载稀土铈及铜铈催化剂的制备与表征 总被引:1,自引:0,他引:1
The Zr-pillaraed montmorillonite supported Ce and Cu-Ce catalysts were prepared by impregnation method. The performance of the catalysts was evaluated via the catalytic oxidation of volatile organic compounds (acetone, ethyl acetate, and toluene). The results showed that after supporting with Ce and Cu-Ce, the catalysts had a better reducibility. Moreover, the surface areas of the samples were increased. In addition,it was found that the Zr-pillared montmorillonite supported Cu-Ce catalysts had a higher activity and the reaction temperature decreased by 150~200 ℃ compared with the sample without Cu-Ce modification. 相似文献