Micron-Sized Zeolite Beta Single Crystals Featuring Intracrystal Interconnected Ordered Macro-Meso-Microporosity Displaying Superior Catalytic Performance

Zeolite Beta single crystals with intracrystalline hierarchical porosity at macro-, meso-, and micro-length scales can effectively overcome the diffusion limitations in the conversion of bulky molecules. However, the construction of large zeolite Beta single crystals with such porosity is a challenge. We report herein the synthesis of hierarchically ordered macro-mesoporous single-crystalline zeolite Beta (OMMS-Beta) with a rare micron-scale crystal size by an in situ bottom-up confined zeolite crystallization strategy. The fully interconnected intracrystalline macro-meso-microporous hierarchy and the micron-sized single-crystalline nature of OMMS-Beta lead to improved accessibility to active sites and outstanding (hydro)thermal stability. Higher catalytic performances in gas-phase and liquid-phase acid-catalyzed reactions involving bulky molecules are obtained compared to commercial Beta and nanosized Beta zeolites. The strategy has been extended to the synthesis of other zeolitic materials, including ZSM-5, TS-1, and SAPO-34.     

氰基亚胺与亚甲基二氢苯并呋喃二酮类化合物的[3+2]环加成反应:螺吡唑类化合物的合成

采用具有环外双键的二氢苯并呋喃二酮类化合物和氰基亚胺的[3+2]环加成反应,在温和条件下,以高产率(78%~94%)和高非对映选择性(>20∶1dr)构建了一系列具有螺环结构的吡唑类化合物.     

Potential influence on drug efficacy from interaction of tartrazine and trypsin

The extent to which drugs combine with trypsin is influenced by the interaction of tartrazine and trypsin, which may cause overdose or underdose of drugs. Therefore, the interaction of tartrazine and trypsin is investigated by methods of spectrometry in this paper. The binding rate of tartrazine to trypsin is 80.95–95.71% at 310?K, and Hill’s coefficients are almost 1. The effect of tartrazine on trypsin structure was studied by synchronous and circular dichroism. The results showed that the binding of tartrazine and trypsin induced the conformational change of trypsin, and quenched the endogenous fluorescence in trypsin. The results of molecular docking revealed that tartrazine is located in the catalytic active site of trypsin, and is consistent with that of experimental calculation.     

约瑟夫森结的混沌行为及其在保密通信中的应用

约瑟夫森结的混沌行为在研究和应用方面都具有重要的价值。电阻-电容-电感并联约瑟夫森结在直流电流的驱动下会出现混沌行为,采用数值计算的方法,对混沌行为进行了研究。通过电压波形、频谱、对初始条件的敏感依赖以及奇怪吸引子,证实了混沌的存在,在此基础上首次提出了基于约瑟夫森结混沌行为的保密通信方案。     

X射线荧光基本参数法测定Y1—xCexBa2cu3Oy强的钇铈钡铜

本文用Ｘ射线荧光光谱基本参数法测定了Ｙ１－ｘＣｅｘＢａ２Ｃｕ３Ｏｘ系列样品中的钇铈钡铜含量，然后折算成它们的原子比，测量的结果与ＩＣＰ的结果接近，为非破坏地测定高温超导体的实际组分进行了一次尝试。     

Asymptotic structure of Einstein-Gauss-Bonnet theory in lower dimensions

Recently,an action principle for the D→4 limit of Einstein-Gauss-Bonnet gravity has been proposed.It is a special scalar-tensor theory that belongs to the family of Horndeski gravity.It also has well defined D→3 and D→2 limits.In this work,we examine this theory in three and four dimensions in the Bondi-Sachs framework.In both three and four dimensions,we find that there is no news function associated with the scalar field,which means that there is no scalar propagating degree of freedom in the theory.In four dimensions,the mass-loss formula is not affected by the Gauss-Bonnet term.This is consistent with the fact that there is no scalar radiation.However,the effects of the Gauss-Bonnet term are quite significant in the sense that they arise just one order after the integration constants and also arise in the quadrupole of the gravitational source.     

磷酰化氨基酸自聚成肽的FTIR研究

本文通过对傅里叶变换红外光谱（ＦＴＩＲ）技术研究证明了磷酰化氨基酸可以知聚成肽，并由此说明了在仿生化成肽反应过程中，磷（酰化）起着十分重要的作用，同时了说明了ＦＴＩＲ技术为仿生化的过程研究提供了新的研究方法。     

Optimal risk retention under partial insurance

This paper examines the situation where a risk-averse insured determines the optimal amount of deductible (or stop-loss) insurance. The insurer uses two different premium principles, the expected value principle and the exponential principle. The insured has an exponential utility function. Specific numerical results are obtained for the optimal stop-loss limit in the case of a group life insurance plan. The exact results are contrasted with those obtained by using the normal approximation instead of the exact distribution of aggregate claims.