全文获取类型
收费全文 | 1029篇 |
免费 | 114篇 |
国内免费 | 66篇 |
专业分类
化学 | 713篇 |
晶体学 | 3篇 |
力学 | 44篇 |
数学 | 112篇 |
物理学 | 337篇 |
出版年
2023年 | 9篇 |
2022年 | 18篇 |
2021年 | 19篇 |
2020年 | 20篇 |
2019年 | 15篇 |
2018年 | 16篇 |
2017年 | 18篇 |
2016年 | 27篇 |
2015年 | 30篇 |
2014年 | 32篇 |
2013年 | 58篇 |
2012年 | 86篇 |
2011年 | 123篇 |
2010年 | 59篇 |
2009年 | 54篇 |
2008年 | 83篇 |
2007年 | 64篇 |
2006年 | 67篇 |
2005年 | 61篇 |
2004年 | 52篇 |
2003年 | 37篇 |
2002年 | 29篇 |
2001年 | 22篇 |
2000年 | 36篇 |
1999年 | 23篇 |
1998年 | 9篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 9篇 |
1994年 | 5篇 |
1993年 | 14篇 |
1992年 | 9篇 |
1991年 | 8篇 |
1990年 | 7篇 |
1989年 | 3篇 |
1988年 | 7篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1974年 | 2篇 |
1935年 | 4篇 |
排序方式: 共有1209条查询结果,搜索用时 15 毫秒
11.
Reported are fiber de-multiplexers based on side-polished fibers with a long interaction length and intra-core fiberBragg gratings. In conjunction with the silicon processing technologies, we demonstrate fiber filters and advantages ofour approaches are addressed. 相似文献
12.
Ross W. Mair David G. Cory Sharon Peled Ching-Hua Tseng Samuel Patz Ronald L. Walsworth 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,135(2):478-486
Pulsed-field-gradient NMR techniques are demonstrated for measurements of time-dependent gas diffusion. The standard PGSE technique and variants, applied to a free gas mixture of thermally polarized xenon and O2, are found to provide a reproducible measure of the xenon diffusion coefficient (5.71 × 10−6m2s−1for 1 atm of pure xenon), in excellent agreement with previous, non-NMR measurements. The utility of pulsed-field-gradient NMR techniques is demonstrated by the first measurement of time-dependent (i.e., restricted) gas diffusion inside a porous medium (a random pack of glass beads), with results that agree well with theory. Two modified NMR pulse sequences derived from the PGSE technique (named the Pulsed Gradient Echo, or PGE, and the Pulsed Gradient Multiple Spin Echo, or PGMSE) are also applied to measurements of time dependent diffusion of laser polarized xenon gas, with results in good agreement with previous measurements on thermally polarized gas. The PGMSE technique is found to be superior to the PGE method, and to standard PGSE techniques and variants, for efficiently measuring laser polarized noble gas diffusion over a wide range of diffusion times. 相似文献
13.
Model or variable selection is usually achieved through ranking models according to the increasing order of preference. One of methods is applying Kullback–Leibler distance or relative entropy as a selection criterion. Yet that will raise two questions, why use this criterion and are there any other criteria. Besides, conventional approaches require a reference prior, which is usually difficult to get. Following the logic of inductive inference proposed by Caticha [Relative entropy and inductive inference, in: G. Erickson, Y. Zhai (Eds.), Bayesian Inference and Maximum Entropy Methods in Science and Engineering, AIP Conference Proceedings, vol. 707, 2004 (available from arXiv.org/abs/physics/0311093)], we show relative entropy to be a unique criterion, which requires no prior information and can be applied to different fields. We examine this criterion by considering a physical problem, simple fluids, and results are promising. 相似文献
14.
M.-K. Lee Y.-C. Tseng C.-H. Chu 《Applied Physics A: Materials Science & Processing》1998,67(5):541-543
2 tungsten lamp at 1.83 mA excited by a 0.85-mW 675-nm laser diode. We also demonstrate that the dark current could be greatly
reduced through rapid thermal oxidation and rapid thermal annealing.
Received: 4 August 1997/Accepted: 28 May 1998 相似文献
15.
16.
An ordinary plating solution for indium hexacyanoferrate (InHCF) thin film deposition, mainly composed of equal concentrations
of In3+ and [Fe(CN)6]3–, usually forms precipitates rapidly when either concentration is higher than few millimolar. This contributes to the plating
solution's instability. Moreover, electrodeposited capacities are limited accordingly. In this work, the plating solution's
stability and the electrodeposition of InHCF were greatly enhanced by adding a large amount of K+ and/or H+. It was found that a 10-mM plating solution added with 1 M HCl and 1 M KCl could be stored as fresh over a one-week period,
whereas an unmodified plating solution became useless within a couple of minutes. Also, such cationic additions, especially
adding H+, increased the electrodeposited capacity ca. 18 times at least, as compared with that obtained from the unmodified plating
solution. Furthermore, related enhancing mechanisms were proposed and verified. To sum up, this study offers a means for better
InHCF electrodeposition and should promote the applications of InHCF films.
Electronic Publication 相似文献
17.
Matrix-assisted laser desorption/ionization (MALDI) mass spectrometry has the potential to become a valuable tool for the compositional analysis of copolymers. For a copolymer composed of structurally very similar building blocks with minor chain length changes, one would expect the relative peak intensities observed in the MALDI mass spectra to reflect its composition, at least within a narrow mass range. However, we show that variations in experimental conditions in MALDI can have a significant effect on the mass spectral appearance of a copolymer. The effects of concentration, laser power, type of matrices and solvents on mass spectra of an ethylene oxide/propylene oxide copolymer are illustrated. These somewhat surprising results show that great care needs to be exercised when interpreting copolymer spectra for compositional analysis, even for copolymers with structurally similar monomers. This work also points out that further studies are needed to better understand and optimize spectral acquisition conditions for reliable copolymer compositional analysis by MALDI. 相似文献
18.
Coupling of gradient capillary electrochromatography (gradient CEC) and capillary zone electrophoresis (CZE) with nuclear magnetic resonance spectroscopy (NMR) was performed using a recently developed capillary NMR interface. This technique was applied for the analysis of pharmaceuticals and food. An analgesic was investigated using isocratic and gradient continuous-flow CEC-NMR. Comparison of the results demonstrated the superiority of gradient CEC over isocratic CEC. Aspartame and caffeine, both ingredients of soft beverages, were separated and analyzed by continuous flow CZE-NMR. The order of elution could be reversed by altering the pH. This reversal led to an increased sample concentration in the NMR detection cell, thus allowing the acquisition of a totally correlated spectroscopy (TOCSY) two-dimensional (2-D) spectrum of the synthetic peptide aspartame. 相似文献
19.
20.
The total energies and one-electron energies for first- and second-row atoms were calculated by using the Hartree–Fock and the Hartree–Fock-Slater Hamiltonian with Xα orbitals, ui(αexp); α was parametrized from EHFS (αexp) = Eexp. The EHF (αexp) total energies are always higher than the Hartree–Fock energies for the atoms. The relation of the calculated ionization potential to the experimental ionization potential depends on the α used to define ui(α), αexp, or αHF. 相似文献