探讨有机醇对电感耦合等离子体质谱的增敏效应

探讨了不同种类的常见有机醇对27种环境领域关注的痕量重金属和稀土元素的质谱行为,优化了ICP-MS的入射功率和雾化器流速,以及有机醇的加入量,从物理和化学特性上讨论了增敏效应的作用机理.     

Intensity Correlation Function of a Single-Mode Laser Driven by Two Colored Noises with Colored Cross-Correlation

By using the linear approximation method, the intensity correlation function and the intensity correlation time are calculated in a gain-noise model of a single-mode laser driven by colored cross-correlated pump noise and quantum noise, each of which is colored. We detect that, when the cross-correlation between both noises is negative, the behavior of the intensity correlation function C(t) versus time t, in addition to decreasing monotonously, also exhibits several other cases, such as one maximum, one minimum, and two extrema (one maximum and one minimum), i.e., some parameters of the noises can greatly change the dependence of the intensity correlation function upon time. T3.     

MestReNova软件在有机化合物波谱解析教学中的应用*

以6-甲氧基-7-羟基香豆素的核磁共振氢谱为例,介绍了MestReNova软件在有机化合物波谱解析教学中的具体应用。通过学生对该核磁软件的熟悉和应用,更深理解核磁光谱中所涉及的参数,如化学位移、偶合常数的由来、积分比例与质子数目的关系等,进而提高学生的学习兴趣和学习积极性,在独立处理图谱基础上解析图谱,更好地将理论知识应用到解析实例中,理论知识和实际应用有机融合,有利于培养学生探索能力、解决实际问题的能力,为将来进入科研领域培养思维能力和独立思考能力。     

基于数字微镜技术的阿达玛变换近红外光谱仪

构建了一个基于数字微镜技术的新型阿达玛变换近红外光谱仪.光学信号采用光纤引入,以光栅作为分光元件,利用数字微镜代替传统的机械式阿达玛模板进行光学编码调制,使用单点InGaAs红外探测器检测调制后的光信号,通过快速阿达玛解码还原出原始光谱.通过实验检验了光谱仪的分辨率、信噪比、稳定性以及谱图获取速度等指标.实验结果表明,...     

A Singlet State Generated with SQUIDs in Cavity QED

We propose a scheme to generate a three-qubit three-level singlet state in cavity QED, by placing three Λ-type SQUIDs in a single mode cavity. In this scheme, we make use of the interaction between the SQUIDs and cavity filed, and the classical pulses. The cavity fields are in vacuum state during the whole operation processes of creating the entanglement, and there is no quantum information transformation between the SQUIDs and cavity fields. Because of the advantage of the SQUID-cavity system, the quality factor of the cavity is greatly relaxed.     

The strong decays of <Emphasis Type="Italic">X</Emphasis>(3940) and <Emphasis Type="Italic">X</Emphasis>(4160)

The new mesons X(3940) and X(4160) have been found by Belle Collaboration in the processes \(e^+e^-\rightarrow J/\psi D^{(*)}{\bar{D}}^{(*)}\). Considering X(3940) and X(4160) as \(\eta _c(3S)\) and \(\eta _c(4S)\) states, the two-body open charm OZI-allowed strong decay of \(\eta _c(3S)\) and \(\eta _c(4S)\) are studied by the improved Bethe–Salpeter method combined with the \(^3P_0\) model. The strong decay width of \(\eta _c(3S)\) is \(\Gamma _{\eta _c(3S)}=(33.5^{+18.4}_{-15.3})\) MeV, which is close to the result of X(3940); therefore, \(\eta _c(3S)\) is a good candidate of X(3940). The strong decay width of \(\eta _c(4S)\) is \(\Gamma _{\eta _c(4S)}=(69.9^{+22.4}_{-21.1})\) MeV, considering the errors of the results, it is close to the lower limit of X(4160). But the ratio of the decay width \(\frac{\Gamma (D{\bar{D}}^*)}{\Gamma (D^*{\bar{D}}^*)}\) of \(\eta _c(4S)\) is larger than the experimental data of X(4160). According to the above analysis, \(\eta _c(4S)\) is not the candidate of X(4160), and more investigations of X(4160) is needed.     

丹参素自氧化与促氧化机理

采用过氧化氢电极与电子自旋共振(ESR)技术对不同pH值条件下丹参素的自氧化及Cu2+对丹参素的促氧化反应机理进行了研究.实验结果发现:在碱性条件下(pH=8.5),丹参素自氧化作用异常显著,氧化首先生成O2-·,随后可歧化为H2O2,并且Cu2+对H2O2信号增强也起着显著的促进作用;在弱酸性条件下(pH=6.5),丹参素自氧化过程受到抑制,主要表现为少许Cu2+的促氧化作用;而在生理条件下(pH=7.4),丹参素的自氧化过程缓慢,有少量H2O2生成,并且Cu2+的促氧化作用非常有限.因此,当丹参素作为一种高效抗氧化剂药用时,其自身的自氧化与金属离子促氧化作用都应有所考虑,尤其在偏碱性体液中,更易产生大量的超氧阴离子自由基,并对生物机体造成某种损害.     

Cd掺杂δ-Bi2O3纳米片的制备及其光催化固氮性能

采用一步醇热法制备了Cd掺杂δ-Bi_2O_3,并用X射线衍射(XRD)、透射电子显微镜(TEM)等手段对其微观结构、表面元素、能带结构、光电化学性质等进行表征。结果表明Cd掺杂δ-Bi_2O_3是由二维纳米片组装而成的微球,Cd以Cd2+形式掺杂在δ-Bi_2O_3晶格间隙。由于Cd的掺杂,δ-Bi_2O_3禁带宽减小,光响应范围扩大,光生载流子的传递与分离效率提高。在常温常压下,考察了Cd-δ-Bi_2O_3可见光催化固氮效果,结果表明,光照3 h时,6%Cd-δ-Bi_2O_3的光催化固氮速率为1.6 mmol·g~(-1)·h~(-1)·L~(-1),是δ-Bi_2O_3的10.67倍。Cd的掺杂点会成为光生电子的陷阱,延缓光生电子的表面传递,增强目标分子的化学吸附。     

Copper-catalyzed asymmetric silylative cyclization of cyclohexadienone-containing 1,6-enynes

The first copper-catalyzed asymmetric silylative cyclization of cyclohexadienone-containing 1,6-enynes has been accomplished through a tandem process: regioselective silylcupration of terminal unactivated alkynes and subsequently enantioselective conjugate addition to cyclohexadienones. This reaction proceeded smoothly to afford the cis-hydrobenzofuran and cis-hydroindole frameworks bearing two consecutive chiral carbon centers in high to excellent yields and moderate enantioselectivities. Additionally, the cyclization products could be readily subjected to several transformations for elaborating synthetic utilities.     

高纯锗中浅受主的光热电离光谱

在液氦温度附近, 运用傅里叶变换光谱以及与之相连的磁光光谱系统, 对室温电阻率约为50Ω·cm的p型高纯锗样品进行了高灵敏度的光热电离光谱的研究.从实验上确定了高纯锗样品中浅杂质光热电离的最佳温度范围, 在该温度范围内测量了样品的光热电离光谱, 指出该样品中主要杂质为浅受主硼与铝. 对杂质谱线发生分裂的两种原因, 补偿性杂质导致的快速复合以及随机应力等, 进行了分析讨论. 关键词： 高纯锗 光热电离光谱 元素半导体中的杂质和缺陷能级