全文获取类型
收费全文 | 2321篇 |
免费 | 60篇 |
国内免费 | 19篇 |
专业分类
化学 | 1434篇 |
晶体学 | 20篇 |
力学 | 84篇 |
数学 | 439篇 |
物理学 | 423篇 |
出版年
2021年 | 24篇 |
2020年 | 27篇 |
2019年 | 34篇 |
2018年 | 24篇 |
2017年 | 16篇 |
2016年 | 40篇 |
2015年 | 48篇 |
2014年 | 33篇 |
2013年 | 100篇 |
2012年 | 79篇 |
2011年 | 99篇 |
2010年 | 58篇 |
2009年 | 37篇 |
2008年 | 69篇 |
2007年 | 88篇 |
2006年 | 102篇 |
2005年 | 120篇 |
2004年 | 92篇 |
2003年 | 96篇 |
2002年 | 79篇 |
2001年 | 50篇 |
2000年 | 43篇 |
1999年 | 25篇 |
1998年 | 21篇 |
1997年 | 35篇 |
1996年 | 35篇 |
1995年 | 35篇 |
1994年 | 33篇 |
1993年 | 35篇 |
1992年 | 42篇 |
1991年 | 36篇 |
1990年 | 27篇 |
1989年 | 31篇 |
1988年 | 29篇 |
1987年 | 17篇 |
1986年 | 21篇 |
1985年 | 41篇 |
1984年 | 35篇 |
1983年 | 35篇 |
1982年 | 35篇 |
1981年 | 32篇 |
1980年 | 37篇 |
1979年 | 26篇 |
1978年 | 37篇 |
1977年 | 27篇 |
1976年 | 34篇 |
1975年 | 29篇 |
1974年 | 40篇 |
1973年 | 39篇 |
1972年 | 16篇 |
排序方式: 共有2400条查询结果,搜索用时 31 毫秒
21.
Alan D. Potoff Bertrand L. Chamberland Lewis Katz 《Journal of solid state chemistry》1973,8(3):234-237
A single crystal study of hydrothermally prepared eight-layer BaMnO3 has been carried out which confirms the (Zhdanov notation) 121121 layer stacking scheme for the BaO3 layers. The MnO6 octahedra share faces in strings of four, and these strings are connected to each other by corner sharing. The compound has an hexagonal unit cell of dimensions a = 5.667 ± 0.003 and c = 18.738 ± 0.009 Å, probable space group . Its structure has been determined from 352 independent reflections, of which 242 were considered observed, collected manually by a counter technique and refined to a conventional R value of 0.079. 相似文献
22.
23.
Twenty years of gibberellin research 总被引:4,自引:0,他引:4
Mander LN 《Natural product reports》2003,20(1):49-69
This review covers research into the chemistry and biology of the gibberellin family of plant bioregulators carried out in the author's laboratory over the past 20 years and has 231 references. 相似文献
24.
Brian F.G. Johnson Jack Lewis Martyn V. Twigg 《Journal of organometallic chemistry》1974,67(3):C75-C76
Photolysis of Ru3(CO)12 in the presence of donor ligands rapidly produces monomeric ruthenium species. 相似文献
25.
Plunkett KN Mohraz A Haasch RT Lewis JA Moore JS 《Journal of the American Chemical Society》2005,127(42):14574-14575
The net charge of a colloidal particle was controlled using light and a new photocleavable self-assembled monolayer (SAM). The SAM contained a terminal ammonium group and a centrally located carboxylic acid group that was masked with an ortho-nitrobenzyl functionality. Once exposed to UV light, the 2-nitrobenzyl group was cleaved, therefore transforming the colloidal particle from a net positive (silica-SAM-NH3+) to a net negative (silica-SAM-COO-) charge. By varying the UV exposure time, their zeta potential could be tailored between +26 and -60 mV at neutral pH. To demonstrate a photoinduced gel-to-fluid phase transition, a binary colloidal suspension composed of silica-SAM-NH3+ and negatively charged, rhodamine-labeled silica particles was mixed to form a gel. Exposure to UV light rendered all of the particles negative and therefore converted the system into a colloidal fluid that settles to form a dense sediment. 相似文献
26.
The spectral distribution for the chemiluminescent oxidation of ammonia with hypobromite is significantly different to that for the oxidation of ammonia with N-bromosuccinimide. Therefore, in contrast to the assumptions of several authors, the action of N-bromosuccinimide is not solely derived from the in situ formation of hypobromite. Neither the oxidation of urea with hypobromite nor the oxidation of urea with N-bromosuccinimide involves an initial hydrolysis of urea to ammonia in the alkaline solution. However, these two reactions lead to a common emitter. The addition of xanthene dyes, such as dichlorofluorescein, enhance the chemiluminescence intensity by energy transfer to the efficient fluorophore, but reaction between the sensitiser and hypobromite can result in a significant increase in the background signal. A list of potential interferences has been compiled; particular attention was paid to guanidino compounds, as the chemiluminescence accompanying the oxidation of this functional group has not been previously discussed. 相似文献
27.
Wedin P Martinez CJ Lewis JA Daicic J Bergström L 《Journal of colloid and interface science》2004,272(1):1-9
Stress development during drying of coatings produced from aqueous dispersions of calcium carbonate particles in the presence and absence of organic binders was studied using a controlled-environment stress apparatus that simultaneously monitored drying stress, weight loss, and relative humidity. Specifically, the influence of two organic binders on drying stress evolution was investigated: (1) carboxymethylcellulose, a water-soluble viscosifying aid, and (2) a styrene-butadiene latex emulsion of varying glass transition temperature. The stress histories exhibited three distinct regions. First, a period of stress rise was observed, which reflected the capillary tension exerted by the liquid on the particle network. Second, a maximum stress was observed. Third, it was followed by a period of either stress decay or rise depending on the organic species present. Significant differences in stress histories were observed between coatings containing soluble and nonsoluble binders. Maximum drying stresses (sigmamax) of 0.2-0.5 MPa were observed for coatings produced from pure calcium carbonate or calcium carbonate-latex suspensions, whereas coatings with carboxymethylcellulose exhibited substantially higher sigmamax values of 1-2 MPa. Upon drying, these coatings were quite hygroscopic, such that cyclic variations in relative humidity induced large cyclic changes in residual stress. 相似文献
28.
Kevin Burgess Brian F.G. Johnson Jack Lewis Paul R. Raithby 《Journal of organometallic chemistry》1982,224(4):C40-C44
Organic azides [N3R] react with [Os3(CO)11(NCMe)] and with [Os3(μ-H)2(CO)10] to form [Os3(CO)10(NCMe)(N3COR)] (R Ph) and [Os3(μ-H)(CO)10(HN3R)] (R Ph, n-Bu, CH2Ph, cyclo-C6H11), respectively; the latter may be converted to [Os3(μ-H)2(CO)9(μ3-NR)] by thermolysis; the molecular structure of the phenyl derivative of each class of compound has been confirmed by x-ray analysis. 相似文献
29.
Zareen Ahkter Andrew J. Edwards Scott L. Ingham Jack Lewis Ana M. Martin Castro Paul R. Raithby Gregory P. Shields 《Journal of Cluster Science》2000,11(1):217-226
The reaction of the di-gold cation [Au2(dppx)]2+ with the heptanuclear cluster dianion [Os7(CO)20]2– affords the mixed metal cluster [Os7(CO)20{Au2(dppx)}] (x=m (1), e (2), b (3)). On standing, in solution, this complex undergoes decarbonylation to give the cluster [Os7(CO)19{Au2(dppx)}] (x=m (4), e (5), b (6)). The complexes have been characterised spectroscopically, and an X-ray structure determination of the dppm derivative shows that it contains a metal core based on an Os7 edge-bridged bicapped tetrahedron with the two
3-Au atoms capping adjacent triangular Os3 faces of the central tetrahedron. In an analogous reaction, the carbido anion [Os7(H)C(CO)19]– affords the neutral cluster [Os7C(CO)19{Au2(dppm)}] (7) when treated with [Au2(dppm)]2+ in the presence of base. 相似文献
30.
Bolei Yan Simon W. Lewis Paul J. Worsfold J.Steven Lancaster Anthony Gachanja 《Analytica chimica acta》1991
An overview of liquid phase chemiluminescence (CL) processes is presented and the potential for CL detection in liquid chromatography (LC) is discussed, with particular reference to the luminol and peroxyoxalate reactions. Post column ion displacement from a solid phase reagent [a cation exchange resin in the copper(II) form] followed by catalysis of the luminol reaction is used for the quantification of mixtures of weak acids after separation by ion-exclusion chromatography. Polyaromatic hydrocarbons (PAHs) released during the combustion of biomass fuels are separated by reversed-phase chromatography and quantified by their sensitizing effect on the peroxyoxalate reaction. This procedure is also used for the determination of carboxylic acids in non-aqueous media after selective pre-column derivatization with a fluorescent label (9-anthracenemethanol). 相似文献