Oxidation process of polysulfides in charge process for lithium�Csulfur batteries

The oxidation of polysulfides to element sulfur in charge process was studied by solution thermodynamic analysis and means of cyclic voltammetry (CV), X-ray diffraction (XRD), and charge?Cdischarge test. Basing on the solution thermodynamic analysis, the oxidation process of polysulfides to element sulfur would arise only if the charge voltage exceeds 3.36 V in a lithium?Csulfur cell employing 1.0 M LiN(CF₃SO₂)₂ in 1,2-dimethoxy ethane. Furthermore, the minimum of charge voltage which can push the oxidation would fall down with the increasing solubility of elemental sulfur in electrolyte solution. These analyses were confirmed by practical measurements. One new anodic peak corresponding to the oxidation process of polysulfides to solid sulfur was observed by CV. Both XRD patterns and charge?Cdischarge test showed that the element sulfur appeared in the cathode after the battery was charged over 3.4 V. Hence, the lithium?Csulfur cell charged over 3.4 V exhibited an improved cycle life since the capacity degradation between the first cycle and the second was depressed. In order to improve the energy efficiency, carbon disulfide was added in the electrolyte solution of lithium?Csulfur cell to increase the solubility of sulfur.     

Protein‐Affinitive Polydopamine Nanoparticles as an Efficient Surface Modification Strategy for Versatile Porous Scaffolds Enhancing Tissue Regeneration

Porous scaffolds for tissue regeneration are often functionalized with extracellular matrix proteins to enhance surface/cell interactions and tissue regeneration. However, continuous coatings produced by commonly used surface modification strategies may preclude cells from contacting and sensing the chemical and physical cues of the scaffold. Here, it is shown that polydopamine nanoparticles (PDA‐NPs) tightly adhere on various scaffolds to form nanostructures, and the coverage can be finely tuned. Furthermore, the PDA‐NPs have good affinity to a variety of proteins and peptides. Thus, the PDA‐NPs act as an anchor to immobilize signal biomolecules on scaffolds, and consequently promote cell activity and tissue regeneration. β‐Tricalcium phosphate (TCP) scaffolds decorated with PDA‐NPs demonstrate excellent osteoinductivity and bone‐regeneration performance due to the protein affinity of PDA‐NPs and the intrinsic bioactive characteristics of TCP scaffolds. In summary, PDA‐NPs with excellent affinity for protein adhesion represent a versatile platform to modify porous scaffolds while not compromising the biological functions of the scaffolds, and might have potential applications in tissue regeneration.     

Ab initio study of water adsorption on TiO2-terminated (100) surface of SrTiO3 with and without Cr doping

Water molecule adsorption on TiO₂-terminated (100) surface of SrTiO₃ with and without Cr doping is investigated by first principle calculation based on density functional theory. The band gap is shrunk compared with that of bulk due to the existence of defect states on the surface and 3d states of dopants. As a result the absorption energy edge is reduced and locates in the visible region. When adsorbed on the surface, energy levels of water molecules as a whole are lowered with respect to the Fermi energy, but the higher levels are split and electrons are transferred from low levels to high levels due to the decrease of the density of states in low energy region. Weak bonding is formed between water hydrogen atoms and surface oxygen atoms. This bonding causes the electron transferring from substrate to molecule and the occupation of the corresponding states.     

关于刚体转动惯量测定的计时方法研究

本文给出了在刚体转动惯量的测定中测定时间的计时装置，减小了计量时间所带来的误差。     

聚氧化乙烯介质中的掺杂硫化锌纳米晶的制备及光学性质

简述了聚氧化乙烯介质中的铽、铕、铥、钆、钇、镓、锰掺杂的硫化锌纳米晶的制备方法以及紫外吸收光谱、激发光谱和光激发发射光谱.制成的硫化锌纳米晶直径为3.0～3.5nm.     

偶氮侧基聚合物光致异构动力学研究

本文对偶氮侧基聚合物相位共轭光时间特性进行了研究,得到了相位共扼光产生机制─光致异构过程的时间常数.在相位共轭光上升阶段,其时间常数在0.4～0.5s之间,在相让共轭光的衰减过程,衰减满足双指数关系,分段拟合得到较好的结果,且得到快过程的时间常数为0.27s,慢过程的时间常数为0.78s.     

Research on Raman-scattering and Fabrication of Multilayer Thin Film with Different Structures and Components Based on Pt/Ti/Si3N4/SiO2/Si Substrate

选用三水醋酸铅、乙酰基丙酮酸锆、四异丙氧基钛、乙酰丙酮作初始材料,用同样的方法分别制备了锆钛酸铅(PZT)和钛酸铅(PT)两种固体前驱物. 采用改良型的溶胶-凝胶工艺技术,分别在不同的Pt-Ti-Si₃N₄-SiO₂-Si基底上,按照不同的组合方式,制备了三种多层薄膜：PZT、PT/PZT-PZT/PT、PT/PZT/-/PZT/PT. 较详细地讨论了薄膜制备的工艺技术,发现当凝胶通过烧结和干燥后变成固态物质时,薄膜内部存在着较大的残余应力,当薄膜在600 ºC下退火时其内部残余应力可以被减小. 通过拉曼     

Ca(BH4)2络合物电子结构及热力学稳定性的第一性原理研究

利用第一性原理研究了低温及高温相Ca(BH4)2络合物的电子结构、晶格振动及其反应焓。计算结果表明：低温及高温相Ca(BH4)2中Ca+2与[BH4]－以离子键形式相结合,[BH4]－离子中B原子和H原子以共价键形式相结合,对该共价键有贡献的主要是B原子的2p轨道电子,H原子的1s轨道电子。Ca(BH4)2可能的反应路径为：Ca(BH4)2→2CaH2+CaB6+10H2,该反应在300K下反应焓为43.22 kJ/mol H2。拉伸B—H键所对应的声子频率较高,其值为2360～2500cm-1,这可能是导致B—H键断裂释放氢气需要较高温度的主要原因之一。     

The role of refocusing in dynamic X-wave formation during femtosecond laser filamentation in water

<正>With the evolution of a laser pulse in water,the formation of a nonlinear X wave during femtosecond filamentation is investigated based on numerical simulations.In particular,we analyze the far-field angularly resolved spectra obtained for different temporal portions of the ultrashort pulse during its propagation. Our result shows that the refocusing of ultrashort pulse leads to the formation of dynamic X wave which essentially manifests itself as conical emission.     

LD泵浦Nd:YVO_4双波长运转腔内和频491nm激光器

分析了Nd:YVO4激光器实现双波长运转及腔内和频的条件,利用一种LD泵浦Nd:YVO4晶体产生1 064 nm和914 nm双波长激光束,采用一个线性平凹腔结构,利用腔内Ⅰ类临界相位匹配LBO和频,获得了连续波输出的全固态激光器。实验采用端面结构,在5.0 W的808 nm泵浦功率下,获得了最高功率为2.5 mW连续波TEM00的激光输出,光-光转换效率为0.05%。