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11.
Size‐Controlled Formation of Noble‐Metal Nanoparticles in Aqueous Solution with a Thiol‐Free Tripeptide 下载免费PDF全文
Stefano Corra Dr. Urszula Lewandowska Dr. Edmondo M. Benetti Prof. Dr. Helma Wennemers 《Angewandte Chemie (International ed. in English)》2016,55(30):8542-8545
A combinatorial screening revealed the peptide H‐His‐d ‐Leu‐d ‐Asp‐NH2 ( 1 ) as an additive for the generation of monodisperse, water‐soluble palladium nanoparticles with average diameters of 3 nm and stabilities of over 9 months. The tripeptide proved to be also applicable for the size‐controlled formation of other noble‐metal nanoparticles (Pt and Au). Studies with close analogues of peptide 1 revealed a specific role of each of the three amino acids for the formation and stabilization of the nanoparticles. These data combined with microscopic and spectroscopic analyses provided insight into the structure of the self‐assembled peptidic monolayer around the metal core. The results open interesting prospects for the development of functionalized metal nanoparticles. 相似文献
12.
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14.
In the paper anomalous diffusion appearing in a porous medium composed of two porous components of considerably different diffusion characteristics is examined. The differences in diffusivities are supposed to result either from two medium types being present or from variations in pore size (double porosity media). The long-tail effect is predicted using the homogenization approach based on the application of multiple scale asymptotic developments. It is shown that, if the ratio of effective diffusion coefficients of two porous media is of the order of magnitude smaller or equal O(
2), where is a homogenization parameter, then the macroscopic behaviour of the composite may be affected by the presence of tail-effect. The results of the theoretical analysis were applied to a problem of diffusion in a bilaminate composite. Analytical calculations were performed to show the presence of the long-tail effect in two particular cases.Notations
c
i
the concentration of chemical species in water within the medium i
-
D
i
the effective diffusion coefficient for the medium i
-
D
ij
eff
the macroscopic (or effective) diffusion tensor in the composite
-
ERV
the elementary representative volume
-
h
the thickness of the period
-
l
a chracteristic length of the ERV or the periodic cell
-
L
a characteristic macroscopic length
-
n
the volumetric fraction of the material 2
- 1–n
the volumetric fraction of the material 1
-
N
the unit vector normal to
-
t
the time variable
-
x
the macroscopic (or slow) space variable
-
y
the microscopic (or fast) space variable
-
c
1c
,C
2c
,D
1c
,D
2c
the characteristic quantities
-
T,T
1L
,T
2L
,T
1l
,T
2l
the characteristic times
-
c
1
*
,c
2
*
,D
1
*
,D
2
*
,t
*
the non-dimensional variables
-
the homogenization parameter
- 1
the domain occupied by the material 1
- 2
the domain occupied by the material 2
-
the interface between the domains 1 and 2
-
the total volume of the periodic cell
-
/xi
the gradient operator
-
the gradient operator 相似文献
15.
In the times of dynamically developing regenerative medicine, more and more attention is focused on the use of natural polymers. This is due to their high biocompatibility and biodegradability without the production of toxic compounds, which means that they do not hurt humans and the natural environment. Chitosan and its derivatives are polymers made most often from the shells of crustaceans and are biodegradable and biocompatible. Some of them have antibacterial or metal-chelating properties. This review article presents the development of biomaterials based on chitosan and its derivatives used in regenerative medicine, such as a dressing or graft of soft tissues or bones. Various examples of preparations based on chitosan and its derivatives in the form of gels, films, and 3D structures and crosslinking products with another polymer are discussed herein. This article summarizes the latest advances in medicine with the use of biomaterials based on chitosan and its derivatives and provides perspectives on future research activities. 相似文献
16.
It is commonly taken for granted that long-time solutions of Cattaneo's hyperbolic heat conduction equation tend to overlap
the related parabolic solutions. Usually, for small times considerable qualitative as well as quantitative differences between
the hyperbolic and parabolic solutions are observed which vanish completely for large times. However, in the case of a heat
conducting body with the temperature dependent inner heat generation, the quantitative differences may grow with time. This
arises from the feedback between the temperature and the source capacity. To illustrate this effect, Cattaneo's hyperbolic
equation for the semi-infinite body, with the heat source which capacity is linearly dependent on temperature, is solved analytically
by the Laplace transforms method.
Received on 1 July 1997 相似文献
17.
K. Lewandowska D. Wrbel A. Biadasz R.
wietlik 《Journal of photochemistry and photobiology. A, Chemistry》2008,200(2-3):225-231
Electronic absorption and IR reflection–absorption spectra in non-polarized and in polarized light for lead porphyrin as well as magnesium and lead phthalocyanine dyes when deposited in the form of Langmuir–Blodgett (LB) nanolayers on solid inorganic surfaces (quartz, semiconductor and metal) were measured. Some IR bands of the Langmuir–Blodgett dye layers’ spectra show frequency shifts and changes in the relative intensities as well as in half widths when compared with the vibrational features of powdered dyes dispersed in KBr pellets, which were used as references. The FT-IR spectroscopic examination of the Langmuir–Blodgett layers allowed to estimate electron redistribution at the interface between dye layer and solid substrates. The Langmuir–Blodgett films of different thicknesses (3, 5, 10 layers) were studied at various angles of IR beam incidence and different light polarizations. The most spectacular results were obtained for the grazing incidence (80°) and films of 5 layers for dyes on the Au substrate. The IR spectroscopy was supported with electronic absorption studies (UV–vis) to follow interaction at interface between the dye layers and the substrates as well as to evaluate linear dichroism and to determine arrangement of molecules in the Langmuir–Blodgett films. Molecular arrangement in the Langmuir–Blodgett layers was discussed. It was shown that the dye molecular planes are rather randomly oriented in the Langmuir–Blodgett films with a tendency that the Qy and Qx transition moments in the phthalocyanine macroring are slightly directed along the y-axis (Langmuir–Blodgett dipping direction) and the x-axis direction, respectively. 相似文献
18.
J. Eid J.L. Santailler B. Ferrand A. Basset A. Passero R. Lewandowska C. Balloud J. Camassel 《Superlattices and Microstructures》2006,40(4-6):201
Cubic-silicon carbide crystals have been grown from carbon-rich silicon solutions using the travelling-zone method. To improve the growth process, we investigated the effect of controlling more tightly some of the growth parameters. Using such improved growth conditions, our best sample is a 12 mm diameter and 3 mm long 3C–SiC crystal. It is grown on a (0001) 2 off, 6H–SiC seed and has 111-orientation. The low amount of silicon inclusions results in a reduced internal stress, which is demonstrated by the consideration of μ-Raman spectra collected at room temperature on a large number of samples. 相似文献
19.
Tadeusz Kosztołowicz Katarzyna D. Lewandowska 《Central European Journal of Physics》2012,10(3):645-651
We consider here two different models describing subdiffusion. One of them is derived from Continuous Time Random Walk formalism
and utilizes a subdiffusion equation with a fractional time derivative. The second model is based on Sharma-Mittal nonadditive
entropy formalism where the subdiffusive process is described by a nonlinear equation with ordinary derivatives. Using these
two models we describe the process of a substance released from a thick membrane and we find functions which determine the
time evolution of the amount of substance remaining inside this membrane. We then find ‘the agreement conditions’ under which
these two models provide the same relation defining subdiffusion and give the same function characterizing the process of
the released substance. These agreement conditions enable us to determine the relation between the parameters occuring in
both models. 相似文献
20.
The paper presents the results of density and viscosity measurements in liquid derivatives of benzene and pyridine, well purified, degassed or aerated, depending on temperature, in the whole liquidity range. Gaseous admixtures were found to affect the viscosity of liquids. From one to three Arrhenius regions were observed, depending on the structure and orientational freedom of the molecules. the results are discussed on the background of 1H NMR relaxation time studies with regard to the effect of dipole interactions on the structure of close packing. 相似文献