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101.
Karlsson T Hughes CE Schmedt auf der Günne J Levitt MH 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2001,148(2):238-247
We describe a new technique for double-quantum excitation in magic-angle-spinning NMR of powdered solids. The technique is designed to efficiently excite double-quantum coherence in the vicinity of a rotational resonance condition. The offset from rotational resonance allows the double-quantum filtered signals to be observed with high resolution and sensitivity. The method uses rotational excitation of zero-quantum coherence, assisted by radiofrequency pulse cycles. The zero-quantum coherence is converted into double-quantum coherence by a frequency-selective inversion sequence. Experiments on [(13)C(2), (15)N]-glycine demonstrate a double-quantum filtering efficiency of approximately 41% at a sample rotation frequency of 8.300 kHz, which is 1.600 kHz away from the n = 1 rotational resonance. We achieve 32% double-quantum filtering efficiency at a spinning frequency of 9.250 kHz, which is 2.550 kHz away from rotational resonance. 相似文献
102.
Gilbert Levitt 《Commentarii Mathematici Helvetici》1994,69(1):28-38
LetG be a finitely generated group acting on anR-treeT. First assume that the action is free, and minimal (there is no proper invariant subtree), or more generally that it satisfies
a certain finiteness condition. Then it may be described as agraph of transitive actions: the action may be recovered from a finite graph, together with additional data; in particular, every vertexv carries an action (G
v, Tv) whose orbits are dense. For the action (G, T), it follows for instance that the closure of any orbit is a discrete union of closed subtrees: it cannot meet a segment
in a Cantor set.
Now let ℓ be the length function for an arbitrary action ofG. For ɛ>0 small enough, the subgroupG(ɛ)⊂G generated by elementsg withg is independent of ɛ, andG/G(ɛ) is free. Several interpretations are given for the rank ofG/G(ɛ). 相似文献
103.
The conventional type of magnetic well is formed by superposition of two types of magnetic field, axial bumpy field and radial
multipole field. It is used to contain plasma that consists of neutrals, ions and electrons. These particles are in constant
motion in the well and energetic electrons create plasma by violent collisions with neutrals and ions. The confined electrons
are constantly heated by ECR technique in the presence of magnetic field. In this paper it has been shown theoretically that
how the electron motion is influenced in terms of heating, containment and azimuthal uniformity of plasma, by the axial rotation
of the multipole magnetic field [1,2]. Afterwards, the feasibility of achieving a rotating magnetic multipole field is discussed
to some extent. And it is seen that it is not beyond the capability of the scientific community in the present scenario of
the advanced technology. Presently, it can be achieved for lesser field and slightly larger size of the multipole electromagnet
and can be used for improvement of the ECR ion source (ECRIS). 相似文献
104.
The sum of the total curvatures of two orientable orthogonal foliations on the unit sphereS
2⊂R
3 is at least 4Π. The total curvature of a foliation with saddle singularities on a closed hyperbolic surfaceM is at least (12 Log 2–6 Log 3) ... |χ(M)|.
相似文献
105.
The ionization potentials of alkyl and hydrogen halides are found to be excellent linear fractions of the polar and inductive substituent constants, indicating that the effect of alkyl substituents on the electron density of the halogen atoms is inductive. The slopes of the four regression lines vary widely in the order RF ? RCl > RBr > RI, which shows that the susceptibility of the halogen atoms to inductive effects varies in the same order. Values of σI and σ* for alkyl groups not previously available are estimated. 相似文献
106.
107.
Solid-state NMR spectroscopy of molecular hydrogen trapped inside an open-cage fullerene 总被引:3,自引:0,他引:3
Carravetta M Murata Y Murata M Heinmaa I Stern R Tontcheva A Samoson A Rubin Y Komatsu K Levitt MH 《Journal of the American Chemical Society》2004,126(13):4092-4093
Solid-state 1H experiments were performed an open-cage fullerene hosting molecular hydrogen. The anisotropy of the molecular hydrogen rotation was studied by double-quantum magic-angle-spinning NMR. The time scale of the molecular hydrogen rotation was estimated by spin-lattice relaxation measurements as a function of temperature. 相似文献
108.
Hughes CE Pratima R Karlsson T Levitt MH 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2002,159(1):25-35
We examine the double-quantum magic angle spinning NMR spectra of pairs of 13C nuclei coupled to one or more 14N nuclei. The experimental spectra of 13C(2)-glycine and glycyl-[13C(2)]-glycyl-glycine are used to demonstrate the sensitivity of the spectra to the orientation of 14N quadrupole interaction tensors and to the molecular torsional angles. 相似文献
109.
110.
Levitt MH Johannessen OG 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,142(1):190-194
This article analyzes the influence of the radiofrequency mixing scheme on the sign of phase shifts experienced by the nuclear spins. It is an addendum to a previous article on the signs of phases and frequencies in NMR (M. H. Levitt, J. Magn. Reson. 126, 164 (1997)). 相似文献