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101.
Veysel T. Yilmaz Ahmet Karadag Carsten Thne Regine Herbst‐Irmer 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):948-949
In the neutral title complex, trans‐bis(2,2′‐iminodiethanol‐N,O)bis(isothiocyanato)nickel(II), [Ni(NCS)2(C4H11NO2)2], the isothiocyanate ions and the diethanolamine molecules act as monodentate and bidentate ligands, respectively. The NiII ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and NNCS—Ni—Namine and NNCS—Ni—Oamine bond angles of 88.78 (10) and 89.44 (10)°, respectively. The Ni—N bond distances are in the range 2.069 (3)–2.096 (2) Å. The molecules are linked by hydrogen bonds to form a three‐dimensional infinite lattice. 相似文献
102.
The effects of bridging analogies teaching strategy and gender on Turkish high school students' misconceptions in mechanics were investigated. After a pilot study with 67 students in a nearby high school, the researchers administered the revised Mechanics Misconception Test to 119 high school students as a pretest. Students in the experimental group were instructed by using bridging analogies teaching strategy. At the end of a 3‐week treatment period, the same test was administered to all students as a posttest. The data were analyzed by using analysis of covariance (ANCOVA). The statistical results showed that bridging analogies teaching strategy was an effective means of reducing the number of misconceptions students held about normal forces, frictional forces, tension, gravity, inertia, and Newton's third law. 相似文献
103.
We study the lift-and-project procedures for solving combinatorial optimization problems, as described by Lovász and Schrijver, in the context of the stable set problem on graphs. We investigate how the procedures' performances change as we apply fundamental graph operations. We show that the odd subdivision of an edge and the subdivision of a star operations (as well as their common generalization, the stretching of a vertex operation) cannot decrease the N0-, N-, or N+-rank of the graph. We also provide graph classes (which contain the complete graphs) where these operations do not increase the N0- or the N-rank. Hence we obtain the ranks for these graphs, and we also present some graph-minor like characterizations for them. Despite these properties we give examples showing that in general most of these operations can increase these ranks. Finally, we provide improved bounds for N+-ranks of graphs in terms of the number of nodes in the graph and prove that the subdivision of an edge or cloning a vertex can increase the N+-rank of a graph.Research of these authors was supported in part by a PREA from Ontario, Canada and research grants from NSERC.Mathematics Subject Classification (2000): 0C10, 90C22, 90C27, 47D20 相似文献
104.
Seda Yurteri Ioan Cianga A. Levent Demirel Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2005,43(4):879-896
1,4‐Dibromo‐2‐(bromomethyl)benzene and 1,3‐dibromo‐5‐(bromomethyl)benzene were used as initiators in the atom transfer radical polymerization of styrene in conjunction with CuBr/2,2′‐bipyridine as a catalyst. The resulting polystyrene (PSt)‐based macromonomers, possessing at one end a 2,5‐dibromophenylene or 3,5‐dibromophenylene moiety, were used in combination with 2,5‐dihexylbenzene‐1,4‐diboronic acid for Suzuki coupling in the presence of Pd(PPh3)4 as a catalyst or with the system NiCl2/2,2′‐bipyridine/triphenylphosphine/Zn for Yamamoto polymerization. Polyphenylenes (PPs) with PSt chains as substitution groups were obtained. The same macromonomers were used in Yamamoto copolycondensation reactions, in combination with a poly(ε‐caprolactone) (PCL) macromonomer, and this resulted in PPs with PSt/PCL side chains. The obtained PPs had good solubility properties in common organic solvents at room temperature similar to those of the starting macromonomers. The new polymers were characterized with 1H (13C) NMR, IR, and gel permeation chromatography. The optical properties of the polymers were monitored with UV and fluorescence spectroscopy. The thermal behaviors of the macromonomers and final PPs were investigated with differential scanning calorimetry and compared. The morphology of PPs containing PSt and PCL blocks was characterized with atomic force microscopy, and a microphase‐separated layered morphology was observed. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 879–896, 2005 相似文献
105.
Yüce MY Demirel AL Menzel F 《Langmuir : the ACS journal of surfaces and colloids》2005,21(11):5073-5078
Surface hydrophobicity of composite films containing polymer and nanoparticles has been studied as a function of composition. We show that the hydrophobicity can be tuned by adjusting the amount of particles in the two-component system. A sharp transition from a polymer-rich surface to a nanoparticles-rich surface was observed with increasing mass fraction of particles in spin-coated thin films. Water drops on the films did not slide down even at tilt angles of 90 degrees . Contact angle hysteresis increased with the mass fraction of particles indicating that the surface roughness increased as the surfaces remained in the Wenzel regime. Contact angle hysteresis data were quantitatively consistent with predictions of a recent theory. 相似文献
106.
S¸efik Süzer Levent Toppare Keith R. Hallam Geoffrey C. Allen 《Fresenius' Journal of Analytical Chemistry》1996,355(3-4):387-389
Electrochemically prepared films of conducting polymers of polypyrrole and polythiophene and their blends with polyamide have been investigated by X-ray photoelectron spectroscopy. In the N1s region of the spectra of films containing polypyrrole the peak corresponding to N+ at 402.0 eV is separated from that of neutral N. The intensity of the N+ peak can be correlated with the electrical conductivity of the films and the spectroscopically derived ratio of F/N+ is close to 4 indicating that one BF-4 dopant ion is incorporated for every oxidized nitrogen center. In the spectra of films of polythiophene and its blends peaks corresponding to S and S+ can not be resolved but again the F/C ratio correlates with the electrical conductivity. 相似文献
107.
Nihal YILMAZ OZGUR 《数学学报(英文版)》2006,22(2):383-392
Using the notion of quadratic reciprocity, we discuss the principal congruence subgroups of the Hecke groups H(√q),q 〉 5 prime number. 相似文献
108.
Yilmaz Simsek 《Applied mathematics and computation》2010,216(10):2976-973
The main purpose of this paper is to construct a family of modified p-adic twisted functions, which interpolate the modified twisted q-Bernoulli polynomials and the generalized twisted q-Bernoulli numbers at negative integers. We also give some applications and examples related to these functions and numbers. 相似文献
109.
In a M/M/N+M queue, when there are many customers waiting, it may be preferable to reject a new arrival rather than risk that arrival
later abandoning without receiving service. On the other hand, rejecting new arrivals increases the percentage of time servers
are idle, which also may not be desirable. We address these trade-offs by considering an admission control problem for a M/M/N+M queue when there are costs associated with customer abandonment, server idleness, and turning away customers. First, we formulate
the relevant Markov decision process (MDP), show that the optimal policy is of threshold form, and provide a simple and efficient
iterative algorithm that does not presuppose a bounded state space to compute the minimum infinite horizon expected average
cost and associated threshold level. Under certain conditions we can guarantee that the algorithm provides an exact optimal
solution when it stops; otherwise, the algorithm stops when a provided bound on the optimality gap is reached. Next, we solve
the approximating diffusion control problem (DCP) that arises in the Halfin–Whitt many-server limit regime. This allows us
to establish that the parameter space has a sharp division. Specifically, there is an optimal solution with a finite threshold
level when the cost of an abandonment exceeds the cost of rejecting a customer; otherwise, there is an optimal solution that
exercises no control. This analysis also yields a convenient analytic expression for the infinite horizon expected average
cost as a function of the threshold level. Finally, we propose a policy for the original system that is based on the DCP solution,
and show that this policy is asymptotically optimal. Our extensive numerical study shows that the control that arises from
solving the DCP achieves a very similar cost to the control that arises from solving the MDP, even when the number of servers
is small. 相似文献
110.
We consider a scale-free network of stochastic HH neurons driven by a subthreshold periodic stimulus and investigate how the collective spiking regularity or the collective temporal coherence changes with the stimulus frequency, the intrinsic noise (or the cell size), the network average degree and the coupling strength. We show that the best temporal coherence is obtained for a certain level of the intrinsic noise when the frequencies of the external stimulus and the subthreshold oscillations of the network elements match. We also find that the collective regularity exhibits a resonance-like behavior depending on both the coupling strength and the network average degree at the optimal values of the stimulus frequency and the cell size, indicating that the best temporal coherence also requires an optimal coupling strength and an optimal average degree of the connectivity. 相似文献