Photophysics and photochemistry of tetraanthraporphyrazines; attempts to obtain a new generation of photosensitizers

Linearly benzo-annulated copper porphyrazines, such as octaphenyltetraanthraporphyrazinato-copper and octapentoxytetranaphthoporphyrazinato-copper, with absorption maxima at about 880 nm, were synthesized. These compounds exhibit very low-lying triplets with an energy below the activation energy of singlet oxygen. Therefore they do not generate singlet oxygen. The transient absorption spectra of the T₁—T_x transition were measured. The solvent dependence of the photophysical parameters in the triplet manifold is discussed. On irradiation in the presence of CBr₄, π-cation radicals are formed.     

Ligand field and hyperfine interaction of the [Fe(H2O)6]2+ complex in different compounds

A series of compounds all containing the ferrous hexaquo complex were investigated by Mössbauer spectroscopy at 4.2K and in magnetic fields up to 5T and far infrared techniques. The results are interpreted in terms of a T_2g ligand field model for which normal distortions of the water octahedron are used as parameters. The ferrous hexaquo complex can be described in all compounds by the same covalency, spin-orbit coupling and hyperfine coupling constants.     

Chiral partners and their electromagnetic radiation (Ingredients for a systematic in-medium calculation)

It is argued that the chiral partners of the lowest-lying hadrons are hadronic molecules and not three-quark or quark-antiquark states, respectively. As an example the case of a₁ as the chiral partner of the ρ is discussed. Deconfinement-or as a precursor large in-medium widths for hadronic states-is proposed as a natural way to accommodate for the fact that at chiral restoration the respective in-medium spectra of chiral partners must become degenerate. Ingredients for a systematic and self-consistent in-medium calculation are presented with special emphasis on vector-meson dominance which emerges from a recently proposed systematic counting scheme for the mesonic sector including pseudoscalar and vector mesons as active degrees of freedom.     

Hadronic three-body decays of light vector mesons

The decays of light vector mesons into three pseudoscalar mesons are calculated to leading order in the recently proposed counting scheme that is based on the hadrogenesis conjecture. Fully differential as well as integrated decay widths are presented. Since the required parameters have been fixed by other processes, the considered three-body decays are predictions of the presented approach. The decay width of the omega meson into three pions agrees very well with the experiment. The partial decay widths of the K^* into its three K channels are predicted.     

Perpendicular spin orientation in ultrasmall Fe islands on W(110).

We have studied the magnetism of Ag-coated Fe islands on W(110) by nuclear resonant scattering of synchrotron radiation at the 14.4 keV resonance of (57)Fe. Separated islands with an average diameter of 2.0 nm and monolayer thickness are formed at a Fe coverage of theta = 0.57 bulk monolayers. Time spectra of the nuclear decay were measured in the temperature range from 4.5 to 300 K. We find strong evidence for perpendicular spin orientation, which most likely results from the interplay of shape anisotropy and elastic strain in the islands.     

On the mechanism of rhodamine 6G fluorescence quenching

The fluorescence of the widely used TPF dye rhodamine 6G is quenched by photons of the ruby as well as the Nd-glass laser. Taking into consideration the polarisation of the ground- and excited-state absorptions of rhodamine 6G a simple model of quenching results. The main process is an S₁ absorption with subsequent leave of the ordinary rhodamine 6G singlet system. For Nd-laser photons the cross section of the concerned transition following from our quenching experiments is σS₁→S₂ = 1.2×10^-16 cm².