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81.
New methods are suggested for the determination of the charge density of acrylamide/acrylate copolymers.13C nuclear magnetic resonance spectroscopy was used to determine the comonomer ratio by comparing the peak intensities of the methine carbon in acrylamide and acrylate monomers. Results were compared with those obtained by conductometric and potentiometric titration and were found to be in good agreement. Differential scanning calorimetry was employed to determine the glass transition temperatures (T
g) of the copolymers. A master curve was established by plottingT
g versus charge density of the copolymers previously determined by NMR and conductometric titration. Compositions of poly(acrylamide-co-acrylate) samples can thus be determined by measuring theT
g and reading the percent composition directly from the master curve. 相似文献
82.
X. B. Zeng A. W. N. Leung X. S. Xia H. P. Yu D. Q. Bai J. Y. Xiang Y. Jiang C. S. Xu 《Laser Physics》2010,20(6):1500-1503
In the present study, we have successfully set up a novel blue light source with the power density of 9 mW/cm2 and the wavelength of 435.8 nm and then the novel light source was used to investigate the effect of light radiation on curcumin-induced
cell death. The cytotoxicity was investigated 24 h after the treatment of curcumin and blue light radiation together using
MTT reduction assay. Nuclear chromatin was observed using a fluorescent microscopy with Hoechst33258 staining. The results
showed blue light radiation could significantly enhance the cytotoxicity of curcumin on the MCF-7 cells and apoptosis induction.
These findings demonstrated that blue light radiation could enhance curcumin-induced cell death of breast cancer cells, suggesting
light radiation may be an efficient enhancer of curcumin in the management of breast cancer. 相似文献
83.
84.
The backward phase flow and FBI-transform-based Eulerian Gaussian beams for the Schrödinger equation
We propose the backward phase flow method to implement the Fourier–Bros–Iagolnitzer (FBI)-transform-based Eulerian Gaussian beam method for solving the Schrödinger equation in the semi-classical regime. The idea of Eulerian Gaussian beams has been first proposed in [12]. In this paper we aim at two crucial computational issues of the Eulerian Gaussian beam method: how to carry out long-time beam propagation and how to compute beam ingredients rapidly in phase space. By virtue of the FBI transform, we address the first issue by introducing the reinitialization strategy into the Eulerian Gaussian beam framework. Essentially we reinitialize beam propagation by applying the FBI transform to wavefields at intermediate time steps when the beams become too wide. To address the second issue, inspired by the original phase flow method, we propose the backward phase flow method which allows us to compute beam ingredients rapidly. Numerical examples demonstrate the efficiency and accuracy of the proposed algorithms. 相似文献
85.
The structure and bonding of the chlorine atom/carbon disulfide (CS(2)/Cl) complex involved in selective photochlorination reactions with alkanes was directly probed using transient resonance Raman spectroscopy. The experimental Raman vibrational frequencies were compared to those computed from density functional theory calculations for probable structures of the CS(2)/Cl complex. Our results indicate that the S [double bond] C [double bond] S...Cl complex species is responsible for the approximately 370 nm transient absorption band observed after ultraviolet photolysis of CCl(4) in the presence of CS(2). We discuss the structure and properties of the S [double bond] C [double bond] S...Cl complex and compare them with those for the related benzene/Cl and pyridine/Cl complexes. 相似文献
86.
We investigate the formation of spiral crack patterns during the desiccation of thin layers of precipitates in contact with a substrate. This symmetry-breaking fracturing mode is found to arise naturally not from torsion forces but from a propagating stress front induced by the foldup of the fragments. We model their formation mechanism using a coarse-grain model for fragmentation and successfully reproduce the spiral cracks. Fittings of experimental and simulation data show that the spirals are logarithmic. Theoretical aspects of the logarithmic spirals are discussed. In particular we show that this occurs generally when the crack speed is proportional to the propagating speed of stress front. 相似文献
87.
Che CM Mao Z Miskowski VM Tse MC Chan CK Cheung KK Phillips DL Leung KH 《Angewandte Chemie (International ed. in English)》2000,39(22):4084-4088
88.
The theory of Eilenberger, modified to take into account the effect of the surface, is applied to the problem of the penetration of a weak magnetic field into a semiinfinite superconductor, and the standard result for the vector potential is derived by linearizing the Eilenberger equations. The dominant term in the asymptotic behaviour is argued to be monotonic for both large and small values of the Ginzburg-Landau parameterk gl . ForT≠ 0, there is a small intermediate range of values ofk gl for which the dominant term is oscillatory, but these oscillations are not related to those found by Eilenberger and Büttner in the isolated vortex problem for smallK gl . From an analysis of these results, we conclude that the absence of the Eilenberger-Büttner oscillations in the field penetration problem cannot be used as an argument against their existence in other problems; in particular, a separate investigation is required for the isolated vortex problem. 相似文献
89.
90.