Preparation of Phosphoric-Carboxylic Cation Exchangers from Wood Cellulose

Phosphorus-containing cellulose cation exchangers were synthesized by reaction of wood cellulose with orthophosphoric acid and the ternary polymer from glycidylmethacrylate, styrene, and maleic anhydride. The effects of the ratio of reactants, temperature, and duration of the reaction on the phosphorylation and exchange capacity of the modified cellulose material were studied.     

On Dispersion in the Mathematical Model of Poroelastic Materials with the Balance Equation for Porosity

This article concerns the nonlinear asymptotic analysis of the mathematical model of a multi-component poroelastic medium with the porosity balance equation. It is proved that there exist soliton-like solutions for porosity and kink-like solutions for phase velocities under conditions similar to the entropy one. It is shown that solutions appear that describe a regime of stable displacement (so-called piston displacement) and a regime similar to the Saffman–Taylor instability. It is established that the diffusion force of interaction between phases of the inner friction type causes a decrease in the amplitudes of the discontinuities. This leads to the damping of initial perturbations of stable states. Such regimes have some properties similar to those of the pendulum model in the vicinity of a stable equilibrium point.     

Norm Series in High-Dimensional Local Fields

In the present paper, the notion of norm series with respect to the norm residue symbol is generalized to high-dimensional local fields. Necessary and sufficient conditions for the existence of norm series are obtained. Bibliography: 12 titles.__________Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 305, 2003, pp. 60–83.     

Polarization modification of PZT thin films by means of electric fields and stress in scanning force microscopy

Polarization switching in scanning force microscopy (SFM) is influenced by both electric fields and stress, whereby the latter can arise inherently from Maxwell stress. We discuss the influence of electric charges and of the polarization asymmetry on the switching behaviour. For single crystallites of PZT(53/47) thin films, the sectors for ferroelectric, ferroelastoelectric and ferroelastic switching are represented in a field-stress map. The influence of stress on the second harmonic of the SFM is also discussed.     

Fabrication and transport properties of multiwall carbon nanotube crossroads

A multiwall carbon nanotube crossroads has been fabricated by a manipulation technique using a glass microcapillary, and the low temperature transport properties investigated. The two-terminal conductance of an individual tube shows Tomonaga–Luttinger liquid behavior G∝T^α at high temperature and dI/dV ∝V ^α at low temperature. However, no evidence of such a power-law behavior is obtained in the four-terminal conductance at the junction, where the conductance shows an almost metallic behavior ‘corrected’ by weak localization. Weak localization would essentially appear in electron states at the junctions of MWNTs.     

Applying Cognition-Based Assessment to Elementary School Students' Development of Understanding of Area and Volume Measurement

As part of a discussion of cognition-based assessment (CBA) for elementary school mathematics, I describe assessment tasks for area and volume measurement and a research-based conceptual framework for interpreting students' reasoning on these tasks. At the core of this conceptual framework is the notion of levels of sophistication. I provide details on an integrated set of levels for area and volume measurement that (a) starts with the informal, preinstructional reasoning typically possessed by students, (b) ends with the formal mathematical concepts targeted by instruction, and (c) indicates cognitive plateaus reached by students in moving from (a) to (b).     

NDMAP: the best material to study the Haldane's prediction

As predicted by Haldane, spin, S=1 one-dimensional (1D) Heisenberg antiferromagnet (HAF) has an energy gap between the singlet ground state and first excited triplet. On application of magnetic field, the triplet state Zeeman splits and the energy of one of the triplet state becomes zero at a critical field, H_c. Above H_c the system recovers magnetism. Then, we expect that a quasi-1D HAF will show a magnetic long-range ordering (LRO) at low temperatures due to the inter-chain coupling. This field-induced LRO has not been observed before due to complication of the crystal structure in the materials studied so far and/or technical difficulty.From a heat capacity measurement on a single crystal of an S=1 quasi-Q1D HAF, Ni(C₅H₁₄N₂)₂N₃(PF₆), we found an anomaly at a temperature in finite fields indicating a field-induced phase transition. A magnetic LRO is confirmed by a neutron diffraction measurement on the same sample. The temperature versus magnetic field phase diagram of this compound is constructed and discussed.