Improved calculation of distributions sensitive to the three gluon vertex ine + e −→4-jets using a coherent parton shower simulator

The calculation of hadron distributions ine ⁺ e ^?→4-jets using the 4-parton matrix element diverges unless cuts are imposed on the parton phase space. Experimentally cuts can be applied only on the hadron spectrum and not at the 4-parton level. Test observables for the three gluon vertex relying on jet-jet angular correlations are found to be particularly sensitive to these parton cuts. The contribution from the parton phase space below the cut region is calculated to modified logarithmic approximation accuracy using a Monte Carlo simulator HERWIG and is found to be of order 45%. This modifies the predictions of the tests so that differences between QCD and ‘QED’ are diminished significantly. A tagging method based on the average energy of particles in a jet is found to be best at identifying both gluon jets with a possible 9:1 success to failure ratio and it allows the presence of the three gluon vertex to be verified.     

Fluctuation spectroscopy of granularity in superconducting structures

We suggest to use "fluctuation spectroscopy" as a method to detect granularity in a disordered metal close to a superconducting transition. We show that with lowering temperature T the resistance R(T) of a system of relatively large grains initially grows due to the fluctuation suppression of the one-electron tunneling but decreases with further lowering T due to the coherent charge transfer of the fluctuation Cooper pairs. Under certain conditions, such a maximum in R(T) turns out to be sensitive to weak magnetic fields due to a novel Maki-Thompson-type mechanism.     

Patterns of the Formation of Antimicrobial Micro/Nanocomposites during the Oxidation of Bimetallic Al/Zn Nanoparticles

Russian Journal of Physical Chemistry A - Porous composites of different phase composition are synthesized via oxidation in a water–ethanol mixture of bimetallic Al/Zn nanoparticles obtained...     

The space of Lorentz metrics

The set of allC ² Lorentz metrics on a non-compact four-manifold is given the Whitney fineC ² topology. It is shown that this provides the correct framework within which to discuss the global properties of spacetime manifolds in general, and the singularity theorems in particular. The main result is a theorem showing that the Robertson-Walker big bang (global infinite density singularity in the finite past) is stable under sufficiently small, but otherwise arbitrary, finiteC ² perturbations of the metric tensor.Based, in part, on a thesis submitted to the Mathematics Department of the University of Pittsburgh.     

Electrical Explosion of Wires for Manufacturing Bimetallic Antibacterial Ti–Ag and Fe–Ag Nanoparticles

Russian Physics Journal - Using a simultaneous electrical explosion of two twisted wires, bimetallic Ti–Ag and Fe–Ag nanoparticles are synthesized, where the component ratios are...     

Chalcogen–chalcogen-bond activation by an ambiphilic,doubly reduced organoborane

The 9,10-dimethyl-9,10-dihydro-9,10-diboraanthracene dianion salt Li₂[1] instantaneously reacts with the dichalcogens O₂(tBu)₂, S₂Me₂, S₂(pTol)₂, Se₂Ph₂, and Te₂Ph₂ under reductive cleavage of the chalcogen–chalcogen bonds to give lithium chalcogenides and neutral 1. In solution, the products are involved in rapid association/dissociation equilibria. In the crystalline state, 1 and Li[O(tBu)] form a diadduct, whereas Li[SMe] gives a B?B-bridged monoadduct. In the three remaining cases, the crystal lattices contain monoadducts of 1 with one tri- and one tetracoordinate boron atom.     

Kristallstruktur des Zinkamids Zn[N(SiMe3)2]2

Crystal Structure of the Zinc Amide Zn[N(SiMe₃)₂]₂ X‐ray quality crystals of Zn[N(SiMe₃)₂]₂ (monoclinic, P2₁/c) are obtained by sublimation of the zinc amide Zn[N(SiMe₃)₂]₂ at —30 °C in vacuo (300 torr). According to the result of the X‐ray structural analysis, Zn[N(SiMe₃)₂]₂ contains an almost linear N‐Zn‐N unit with two short N‐Zn bonds.     

One tool to bring them all: Au-catalyzed synthesis of B,O- and B,N-doped PAHs from boronic and borinic acids

The isoelectronic replacement of C C bonds with ⁻B N⁺ bonds in polycyclic aromatic hydrocarbons (PAHs) is a widely used tool to prepare novel optoelectronic materials. Far less well explored are corresponding B,O-doped PAHs, although they have a similarly high application potential. We herein report on the modular synthesis of B,N- and B,O-doped PAHs through the [Au(PPh₃)NTf₂]-catalyzed 6-endo-dig cyclization of BN–H and BO–H bonds across suitably positioned C C bonds in the key step. Readily available, easy-to-handle o-alkynylaryl boronic and borinic acids serve as starting materials, which are either cyclized directly or first converted into the corresponding aminoboranes and then cyclized. The reaction even tolerates bulky mesityl substituents on boron, which later kinetically protect the formed B,N/O-PAHs from hydrolysis or oxidation. Our approach is also applicable for the synthesis of rare doubly B,N/O-doped PAHs. Specifically, we prepared 1,2-B,E-naphthalenes and -anthracenes, 1,5-B₂-2,6-E₂-anthracenes (E = N, O) as well as B,O₂-containing and unprecedented B,N,O-containing phenalenyls. Selected examples of these compounds have been structurally characterized by X-ray crystallography; their optoelectronic properties have been studied by cyclic voltammetry, electron spectroscopy, and quantum-chemical calculations. Using a new unsubstituted (B,O)₂-perylene as the substrate for late-stage functionalization, we finally show that the introduction of two pinacolatoboryl (Bpin) substituents is possible in high yield and with perfect regioselectivity via an Ir-catalyzed C–H borylation approach.

Singly and doubly B,E-doped PAHs were synthesized using a protocol that starts from easy-to-handle boronic and borinic acids and offers the possibility to choose between the preparation of B,O- and B,N-PAHs in the final reaction step.