Polyelectrolyte complex films derived from polyethyleneoxide-maleic acid copolymer and chitosan: preparation and characterization

Polyelectrolyte complex films were prepared with polyethyleneoxide-maleic acid copolymer and chitosan using a casting/solvent evaporation method. The films were examined in terms of their IR spectra, surface and cross-section morphologies, cytotoxicity, and swelling behavior at different pH levels. To assess the potential of these films as a biomedical device, the profiles of the release of model drug from the CS/PEOMA films were examined at pH 4.8. The surface morphology of the films was quite smooth and uniform, and the cross-sectional morphology was dense and homogeneous. The swelling behaviors of CS/PEOMA films were found to depend on the pH of the solution as well as on the CS/PEOMA composition. Drug release from different CS/PEOMA films at pH 4.8 was found to be dependent on film composition. The results showed the potential applicability of CS/PEOMA film as a drug delivery vehicle.     

Encouraging problem-solving disposition in a Singapore classroom

In this article, we share our learning experience as a Lesson Study team. The Research Lesson was on Figural Patterns taught in Year 7. In addition to helping students learn the skills of the topic, we wanted them to develop a problem-solving disposition. The management of these two objectives was a challenge to us. From the lesson observation and the students’ classwork, it turned out better than we expected.     

Generalized eigenproblem of hybrid matrix for Floquet wave propagation in one-dimensional phononic crystals with solids and fluids

A method based on the solution to a generalized eigenproblem of hybrid matrix is presented for stable analysis of Floquet wave propagation in one-dimensional phononic crystals with solids and fluids. The method overcomes the numerical instability in the standard eigenproblem of transfer matrix, thus enabling Floquet waves to be determined reliably. The recursion relations of hybrid matrix for periodic multilayered structure of various solid and/or fluid phases are formulated. Dispersion relation and omnidirectional reflection for one-dimensional phononic crystals with solids and fluids are discussed. The frequency-thickness range of phononic bandgap is determined conveniently based on the Floquet wavenumbers.     

Optical time-domain reflectometry for distributed sensing of the structural strain and deformation

A unique structure of microbend optical fiber sensor (MOFS) for measuring tensile and compressive strain is described in this paper. The average measuring sensitivity for tensile strain is 35μ using 3 MOFS arrays. The repeatability and stability of MFOS are better than 18μ. The loss sensitivity of single-mode (SM) fiber and multi-mode (MM) fiber used in MOFS, as well as the relationship between the pulse width of diode laser and loss sensitivity are also studied in this paper. From these studies, some conclusions have been obtained. They are (1) the loss sensitivity and repeatability of SM fiber are better when compared to MM fiber in MOFS, and (2) the variation of pulse width of laser would only influent the signal-to-noise ratio and dynamic range, but has no contribution to loss sensitivity. Experimental results also show that loss of SM fiber highly depends on the wavelength of laser, but MM fiber has no such property. The loss of SM fiber between the wavelength of 1550 and 1310 nm is about the ratio of 6.5. Therefore, the experiments reported in this paper used a wavelength of 1310 nm to measure tensile strain and 1550 nm to measure compressive strain based on the above property of SM fiber, without changing the configuration of MOFS.     

A ruthenium catalyst that does not require an N-H ligand to achieve high enantioselectivity for hydrogenation of an alkyl-aryl ketone

Ruthenium catalysts of the form trans-RuCl2((R)-(S)-Josiphos)L2 where L2 = pyridine or 1,2-diamine, have been synthesized that display high catalytic activity towards the hydrogenation of 1'-acetonaphthone.