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181.
Di Wu Xun Chen Shenghui Chen Shunxing Lu Fenghua Wang Yumei Zhang 《Journal of Macromolecular Science: Physics》2013,52(3):504-511
Steadyshear and oscillatory shear rheological measurements were performed to characterize the solution rheological behavior of poly(3,3′-diaminodiphenylsulfone terephthaloylchloride) (P(3,3′-DDS-TPC)) in dimethyl sulfoxide (DMSO). The effects of temperature, concentration, and weight-average molar mass () on the rheological properties were investigated. From the temperature dependence of zero-shear viscosity, the flow activation energies, Eη, of P(3,3′-DDS-TPC)/DMSO solutions were calculated. Both the overlap concentration, C*, and the entanglement concentration, Ce, were determined from the concentration dependence of the specific viscosity ηsp. All the P(3,3′-DDS-TPC) solutions, we studied, can be separated into three regimes: the dilute, semidilute-unentangled, and entangled regime with slopes of 1, 1.3, and 3.9, of concentration versus ηsp plots, respectively, which are consistent with scaling predictions for flexible polymers in a good solvent. 相似文献
182.
The paper deals with the riskiness analysis for a large portfolio of life annuities. By means of the limiting distribution of the present value of the portfolio, in the first part of the paper a model for evaluating the investment and the projection risks is presented. In the second part, with regard to the investment risk's effects, the insolvency risk is measured considering the cumulative probability distribution function of the discounted average cost per policy. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
183.
在本文中 ,我们讨论了指数为 α的 LNDp - Stable过程的象集 ,获得了 Salem集 .也就是说 ,对任意的紧集 E R ,如果 dim E <α ,那么 X(E) a.s.是一个维数为 1 /αdim E的 Salem集 . 相似文献
184.
Consider the Bayes problem in which one has to discriminate if the random unknown initial state of a stochastic process is distributed according to either of two preassigned distributions, on the base of the observation of the first‐passage time of the process through 0. For processes whose first‐passage times to state 0 are increasing in the initial state according to the likelihood ratio order, such problem is solved by determining the Bayes decision function and the corresponding Bayes error. The special case of fixed initial values including a family of first‐passage times with proportional reversed hazard functions is then studied. Finally, various applications to birth‐and‐death and to diffusion processes are discussed. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
185.
在线偏振飞秒激光激发下, 菌紫质通过双光子光化学反应可以生成具有永久光致各向异性的蓝移产物F540态. 基于F540态的永久光致各向异性, 通过调控飞秒激光空间光场分布, 可以在菌紫质薄膜中实现永久光信息存储. 本文使用纯相位型空间光调制器调制飞秒激光光场, 在物镜焦平面上生成光学点阵图案, 可以将信息快速记录在菌紫质薄膜中. 同时, 通过改变入射激光偏振方向, 可以实现偏振复用光存储, 这在高密度光存储和数据加密领域具有潜在应用. 相似文献
186.
A bordering procedure is here proposed to evaluate the eigensystem of hermitian matrices, and more in general of normal matrices, when the spectral decomposition is known of then–1×n–1 principal minor. The procedure is also applicable to special real and nonsymmetric matrices here named quasi-symmetric. The computational cost to write the characteristic polynomial isO(n
2), using a new set of recursive formulas. A modified Brent algorithm is used to find the roots of the polynomial. The eigenvectors are evaluated in a direct way with a computational cost ofO(n
2) for each one. Some numerical considerations indicate where numerical difficulties may occur. Numerical results are given comparing this method with the Givens-Householder one. 相似文献
187.
LetK be ak-set of class [0, 1,m,n]1 of anr-dimensional projective Galois space PG(r, q) of orderq. We prove that: Ifr = 2s (s 2),k = 2s–1 and if through each point ofK there are exactlyq
2(s–1) tangent lines and at most 2s–3
n-secant lines, thenK is a non singular quadric of PG(2s,q). Ifr = 2s–1 (s2),k=2(s–1) +q
s–1 and if at each point ofK there are exactlyq
2s–3 –q
s–2 tangents and at most 2(s–2)+q
s–2
n-secant lines, thenK is a hyperbolic quadric of PG(2s–1,q). 相似文献
188.
The proportional reversed hazards model consists in describing random failure times by a family {[F(x)]θ, θ>0} of distribution functions, where F(x) is a baseline distribution function. We show various results on this model related to some topics in reliability theory, including ageing notions of random lifetimes, comparisons based on stochastic orders, and relative ageing of distributions. 相似文献
189.
Giampiero Mei Almerinda Di Venere Eleonora Nicolai Nicola Rosato Alessandro Finazzi Agro' 《Journal of fluorescence》2003,13(1):33-39
Tryptophan fluorescence is extremely useful to monitor structural conformational transitions in proteins. Denaturant-induced unfolding of azurin and ascorbate oxidase has been studied by dynamic fluorescence measurements in the frequency domain and the results have been interpreted in terms of continuous distribution of lifetimes. The data add new information on the unfolding mechanism that was previously analyzed by steady-state emission spectroscopy. In particular, the existence of multiple, parallel unfolding pathways may be envisaged and correlated, in both cases, to the two protein structures. The effect of metal depletion has been also characterized by fluorescence lifetime measurements. In the case of azurin, a monomeric protein, the data demonstrate that copper removal yields a totally different unfolding pathways with respect to the holo protein, indicating that metal ion plays a fundamental structural role in the wild type, native protein. In the case of ascorbate oxidase a dimer of 140 kDa, only minor effects have been detected by copper removal. However, the analysis of the fluorescence decay in presence of different amounts of guanidinium hydrochloride gives new important insights on the unfolding intermediates. In particular the data support the hypothesis of a partial exposure of an outer layer of dimer at intermediate denaturant concentration. This ability of dynamic fluorescence to pinpoint the presence of structural micro-heterogeneity in the unfolding pathways of proteins demonstrates the greater power of this technique compared to the most commonly used steady-state measurements. 相似文献
190.
Egidio Di Gialleonardo Francesco Braghin Stefano Bruni 《Journal of sound and vibration》2012,331(19):4246-4258
This paper investigates the effect of different models for track flexibility on the simulation of railway vehicle running dynamics on tangent and curved track. To this end, a multi-body model of the rail vehicle is defined including track flexibility effects on three levels of detail: a perfectly rigid pair of rails, a sectional track model and a three-dimensional finite element track model. The influence of the track model on the calculation of the nonlinear critical speed is pointed out and it is shown that neglecting the effect of track flexibility results in an overestimation of the critical speed by more than 10%. Vehicle response to stochastic excitation from track irregularity is also investigated, analysing the effect of track flexibility models on the vertical and lateral wheel–rail contact forces. Finally, the effect of the track model on the calculation of dynamic forces produced by wheel out-of-roundness is analysed, showing that peak dynamic loads are very sensitive to the track model used in the simulation. 相似文献