太赫兹大气遥感技术

由于其独特的大气敏感特性,太赫兹波在大气遥感领域起着越来越重要的作用。国际上太赫兹大气遥感技术发展方兴未艾。2004年,美国NASA发射AURA卫星,探测仪器中包括了具有两种极化的2.5 THz辐射计;2007年,欧空局ESA研制了Marschals外差式光谱仪,采用临边探测方式探测气体成分在亚毫米波段热辐射的高光谱。我国在轨气象卫星风云三号已经具备毫米波段辐射计,风云四号卫星是世界上首颗搭载太赫兹遥感仪的地球静止轨道气象卫星。针对我国大气遥感的现状,在概述国内外太赫兹遥感应用和技术的基础上,提出发展自主知识产权的大气遥感技术的思路;大力发展自主知识产权的太赫兹关键器件、太赫兹探测仪系统集成,研究太赫兹大气探测的新原理和反演新方法,整体提升我国在大气遥感领域的技术水平。     

Multicritical behavior at the kosterlitz-thouless critical point

A multicritical critical point for the two dimensional planar model is analyzed by studying an exactly soluable limit of a related model—the generalized Villain model. The statistical mechanics of this model is written in terms of vortex and symmetry breaking excitations. In these terms, the problem reduces to a kind of two dimensional problem with interacting electric charges and magnetic monopoles. In this form, the problem is manifestly self-dual. The multicritical behavior is exhibited in a three-dimensional phase space in which the axes are the coupling strength of a “square” symmetry breaking which favors four possible directions for the planar model vectors. The analysis of this multicritical point shows that it is the intersection of at least six critical lines—each with continuously varying critical indices. Two of these lines are described by the exactly soluable gaussian model. The other four are isomorphic to one another, and each one has—as a point on the line—a critical point of the Ashkin-Teller model. We argue that each of these lines might be in an equivalent universality class to the line of critical points which occurs in the Baxter and Ashkin-Teller models. We make a suggestion about which point on these critical lines might be in the same universality class as our multicritical point. Correlation functions at the intersection point are calculated and used to develop an expansion of critical indices about this point. This expansion gives a potential method for calculating the critical behavior along the critical lines of the model.     

The structure and dissociation pathways of protonated methanol: An ab initio molecular orbital study

Ab initio molecular orbital calculations with moderately large polarization basis sets and including valence-electron correlation have been used to examine the structure and dissociation mechanisms of protonated methanol [CH₃OH₂]⁺. Stable isomers and transition structures have been characterized using gradient techniques. Protonated methanol is found to be the only stable isomer in the [CH₅O]⁺ potential surface. There is no evidence for a tightly-bound complex, [HOCH₂]⁺…?H₂, analogous to the preferred structure [CH₃]⁺…?H₂ of [CH₅]⁺. Protonated methanol is found to possess a pyramidal arrangement of bonds at the oxygen atom with a barrier to inversion of 8kJ mol^?1. The lowest energy fragmentation pathways are dissociation into methyl cation and water (predicted to require 284 kJ mol^?1 with zero reverse activation energy) and loss of molecular hydrogen (endothermic by 138 kJ mol^?1 but with a reverse activation barrier of 149 kJ mol^?1). The results offer a possible explanation as to why production of [CH₂OH]⁺ from the reaction of methyl cation with water is not observed. Other dissociation processes examined include loss of a hydrogen atom to yield the methylenoxonium radical cation or methanol radical cation (requiring 441 and 490 kJ mol^?1, respectively) and loss of a proton to yield neutral methanol (requiring 784 kJ mol^?1).     

Enantiomers of New Synthetic Pyrrolylphenylethanoneamine Mono-Amino Oxidase Inhibitor Compounds: Analytical and Semipreparative HPLC Separations, and Chiroptical Characteristics

The polysaccharide chiral stationary phases (CSPs) Chiralcel OD and Chiralpak AD, and the brush-type (R,R)-Whelk-01 chiral stationary phases have been evaluated to separate new synthetic pyrrolylphenylethanoneamine racemic compounds, potentially monoamine oxidase (MAO) inhibitors, under various mobile phase compositions, using various temperatures. The enantioseparation was evaluated by comparing the (R,R)-Whelk-01 column performance with those of Chiralpak AD and Chiralcel OD. Significant differences were observed in their chiral recognition, as revealed from their retention, selectivity, resolution and elution order. Performances of the Chiralpak AD column were superior to those of the Chiralcel OD and (R,R)-Whelk-01 columns. Some of the racemic compounds were resolved by semipreparative chromatography on Chiralpak AD column in order to study the chiroptical proprieties of the single enantiomers.     

The biochemiresistor: an ultrasensitive biosensor for small organic molecules

New sensation: A resistance-based biosensor uses gold-coated magnetic nanoparticles (Au@MNPs) functionalized with the antibiotic enrofloxin (see picture; purple), which bind to anti-enrofloxin as analyte (blue). The Au@MNPs can be magnetically assembled between electrodes, and the measured resistance R is a function of analyte concentration.     

Consistent and efficient particle tracking on curvilinear grids for environmental problems

Particle‐tracking models are often used for near field short‐term subgrid transport of substances. The consistency demand at the discrete level does not show up so dominantly for these applications. This demand refers to the use of a numerical advection scheme for particles that is fully compatible with the local mass conserving advection properties of the underlying flow field at the discrete level of that field. A noncompatible scheme will produce both local convergence and local divergence of particles in different parts of the model area and thus erroneous advection results and erroneous concentration patterns. This compatibility in particle tracking is especially important if smooth distributions over larger areas are modelled for longer times. These applications did not occur that often in the past because they require many particles and thus much computation time. These applications occur more frequently nowadays especially for environmental assessment such as for the modelling of transport of fish larvae growing during their journey in the model to juvenile stages. The advection scheme that is developed in this paper is shown to be exactly compatible with hydrodynamic flow fields computed by mass conserving curvilinear grid models. It is not only exact, it is fortunately also very simple to implement and fast, allowing for modelling a huge amount of particles with moderate computation time. Copyright © 2012 John Wiley & Sons, Ltd.     

Regiocontrolled C-8 Acylation of Castanospermine

A convenient route to previously unknown 8-acylated castanospermines is illustrated by synthesis of the butyryl derivative.     

Laser interaction with a dielectric block

Some optical experiments provide the easiest way to test quantum mechanical predictions. Such a situation applies to a laser beam traversing a dielectric structure. The dielectric structure mirroring quantum mechanical potentials. The simplest of these, studied in this paper, involves a single dielectric block. We exhibit both by analytic and numerical calculations explicit examples of total coherence and total incoherence phenomena. Which case appears depends upon the angle of incidence of the laser beam and/or the dimensions of beam vs. block width. Unlike our previous studies our calculations here are three-dimensional, although, with suitable approximations, somewhat simpler planar expressions can be derived.