Petroleum

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Stability of droplets and channels on homogeneous and structured surfaces

Wetting of structured or imprinted surfaces which leads to a variety of different morphologies such as droplets, channels or thin films is studied theoretically using the general framework of surface or interface thermodynamics. The first variation of the interfacial free energy leads to the well-known Laplace equation and a generalized Young equation which involves spatially dependent interfacial tensions. Furthermore, we perform the second variation of the free energy for arbitrary surface patterns and arbitrary shape of the wetting morphology in order to derive a new and general stability criterion. The latter criterion is then applied to cylindrical segments or channels on homogeneous and structured surfaces. Received 4 August 1999     

Ein billiger Korkbohrer-Sch?rfer

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An optical study of phase transitions of poly (ethylene terephthalate-co-p-hydroxybenzoic acid) liquid crystal

The copolyester containing 40 mol % ethylene terephthalate (PET) and 60 mol % p-hydroxybenzoate (HB) units has been reported by several investigators to be biphasic in the solid and the liquid states. The reported thermal transitions in the two phases, however, are in part contradictory, perhaps partly due to different polymerization conditions. The present work is a study of the transitions in each of the two phases of this copolyester by polarized light microscopy and by light transmission measurements. By light transmission measurements, the two phases were found to have two different glass transition temperatures for the onset of segmental motion, consistent with two assignable temperatures (T.). Cold crystallization and melting in each of the two different phases was also detected. The results help clarify the nature of transitions and agree with the results of dynamic mechanical analysis on the same thermotropic liquid crystalline copolyester.     

Zur Verwendung der mikrochemischen Reagentien in der analytischen Chemie

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