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141.
142.
Lang J Sloop DJ Lin TS 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2005,176(2):4731-256
We report a new technique to map the orientational anisotropy of paramagnetic systems without physically changing the crystal orientations in near zero-field (NZF) pulsed EPR experiments. By implementing three sets of orthogonal coils around the sample, we are ble to create a magnetic vector up to 2 mT in any three-dimensional orientation in space. In NZF region, the hyperfine tensor elements are comparable to the electronic Zeeman interaction energy, thus very rich spectral patterns can be obtained by "dialing" in a magnetic field vector without moving the sample. The technique further allows us to examine the site symmetry of organic crystals and powdered solids doped with chromophores which can be photo-excited to the triplet state by laser light. The technique is exemplified in the study of pentacene in p-terphenyl crystals. 相似文献
143.
Radical cyclization of vinyl iodides in 6-(pi-exo)-exo-dig mode were effected by SmI2 to give exo-cyclic dienes fused to six-membered rings. 相似文献
144.
Al-Anber M Vatsadze S Holze R Lang H Thiel WR 《Dalton transactions (Cambridge, England : 2003)》2005,(22):3632-3637
Electrochemical reduction potentials of a broad selection of nitrogen-containing molecules suitable as bridging (dipodal and tripodal) ligands in coordination and organometallic chemistry are reported and compared with results of semiempirical calculations. Trends of electrode potentials observed experimentally agree with respective calculated data, deviations can be explained by invoking peculiarities of the involved molecular orbitals and ligand-electrode surface interactions. 相似文献
145.
Yaschenko S Dymov S Kacharava A Komarov V Macharashvili G Rathmann F Barsov S Gebel R Hartmann M Khoukaz A Kulessa P Kulikov A Kurbatov V Lang N Lehmann I Lorentz B Mersmann T Merzliakov S Mikirtytchiants S Mussgiller A Nioradze M Ohm H Prasuhn D Schleichert R Seyfarth H Steffens E Stein HJ Ströher H Uzikov Y Zalikhanov B Zhuravlev N 《Physical review letters》2005,94(7):072304
A measurement of the analyzing power A(y) of the p-->d--> (p p) + n reaction was carried out at the ANKE spectrometer at COSY at beam energies of 0.5 and 0.8 GeV by detection of a fast forward proton pair of small excitation energy E(pp) < 3 MeV. The S-wave dominance in the fast diproton is experimentally demonstrated in this reaction. While at T(p) = 0.8 GeV the measured analyzing power almost vanishes, it rises to nearly unity at T(p) = 0.5 GeV for neutrons emitted at theta(c.m.)(n) = 167 degrees. The results are compared with a model taking into account one-nucleon exchange, single scattering, and Delta(1232) excitation in the intermediate state. The model describes fairly well the unpolarized cross section obtained earlier and the analyzing power at 0.8 GeV; it fails to reproduce A(y) at 0.5 GeV. 相似文献
146.
Although Josephson junction qubits show great promise for quantum computing, the origin of dominant decoherence mechanisms remains unknown. Improving the operation of a Josephson junction based phase qubit has revealed microscopic two-level systems or resonators within the tunnel barrier that cause decoherence. We report spectroscopic data that show a level splitting characteristic of coupling between a two-state qubit and a two-level system. Furthermore, we show Rabi oscillations whose "coherence amplitude" is significantly degraded by the presence of these spurious microwave resonators. The discovery of these resonators impacts the future of Josephson qubits as well as existing Josephson technologies. 相似文献
147.
A. Khoukaz I. Geck C. Quentmeier H.-H. Adam A. Budzanowski R. Czyżykiewicz D. Grzonka L. Jarczyk K. Kilian P. Kowina N. Lang T. Lister P. Moskal W. Oelert C. Piskor-Ignatowicz T. Rożek R. Santo G. Schepers T. Sefzick S. Sewerin M. Siemaszko J. Smyrski A. Strzałkowski A. Täschner P. Winter M. Wolke P. Wüstner W. Zipper 《The European Physical Journal A - Hadrons and Nuclei》2004,20(2):345-350
The
-meson production in the reaction
has been studied at excess energies of Q = 26.5, 32.5 and 46.6 MeV using the internal beam facility COSY-11 at the cooler synchrotron COSY. The total cross-sections as well as one angular distribution for the highest Q-value are presented. The excitation function of the near-threshold data can be described by a pure s-wave phase space distribution with the inclusion of the proton-proton final-state interaction and Coulomb effects. The obtained angular distribution of the
-mesons is also consistent with pure s-wave production.Received: 11 August 2003, Revised: 14 November 2003, Published online: 6 April 2004PACS:
13.60.Le Meson production - 13.75.-n Hadron-induced low- and intermediate-energy reactions and scattering (energy
GeV) - 13.85.Lg Total cross-sections - 25.40.-h Nucleon-induced reactions 相似文献
148.
The effect of substances as possible inhibitors of the K+(Na+)/H+ exchanger in the human red cell membrane has been tested on the (ouabain+bumetanide+EGTA)-resistant K+ influx in both physiological (HIS) and low ionic strength (LIS) solution with tracer kinetic methods. It is demonstrated that high concentrations of quinacrine (1 mM) and chloroquine (2 mM) inhibit the residual K+ influx in LIS solution to 60% and 85%, respectively, but activate it in HIS solution. Thus, chloroquine suppressed the 10-fold LIS-induced activation of the flux nearly completely. Amiloride derivatives were able to inhibit the K+ influx in both HIS and LIS solution. EIPA (75 microM) reduced the flux by about 20% and 55% in HIS and LIS solution, respectively. Newly developed drugs (HOE 642, 1 mM; HOE 694, 0.5 mM) designed to inhibit Na+/H+ exchanger isoforms showed an inhibition of the residual K+ influx of 40% and 33% in HIS and 65% and 44% in LIS solution, respectively, without haemolysis. The inhibitory effect of HOE 642 persisted in HIS (24%) and LIS (48%) solutions when Cl- was replaced by CH3SO4-. The K(+)-Cl- cotransport inhibitor DIOA (100 microM) stimulated the residual K+ influx in both solutions. It is, therefore, concluded that the K(+)-Cl- cotransporter does not contribute to the residual K+ influx both in HIS and LIS media. Okadaic acid decreased the residual K+ influx by 40% and 25% in HIS and LIS solution, respectively, showing that the residual K+ influx is affected by phosphatases like other ion transport pathways. The results show that the residual K+ influx can be decreased further by inhibiting the K+(Na+)/H+ exchanger. It remains still unclear to what extent the K+(Na+)/H+ exchanger is inhibited by the different substances used. However, the ground state membrane permeability for K+ is much smaller than assumed so far. 相似文献
149.
Xu Qing-Feng Lang Jian-Ping Wei Qiao-Hua Chen Zhong-Ning 《Transition Metal Chemistry》2004,29(5):483-487
A novel heterobimetallic sulfide cluster [(
5-C5Me5)WS3Au(dppms)][dppms = bis(diphenylphosphino)methane monosulfide] was prepared by the reaction of [PPh4][(
5-C5Me5)WS3] with AuI and dppm [dppm = bis(diphenylphosphino)methane] in MeCN. The title compound was fully characterized by elemental analysis, i.r., u.v.–vis., 1H-n.m.r. spectra, and by single crystal X-ray crystallography. In the molecular structure, the Au atom is trigonally coordinated by two bridging S atoms of a [(
5-C5Me5)WS3]– anion and a P atom of the dppms molecule. The formation mechanism for this compound is discussed. 相似文献
150.
Dutz H Helbing K Krimmer J Speckner T Zeitler G Ahrens J Altieri S Annand JR Anton G Arends HJ Beck R Bock A Bradtke C Braghieri A v Drachenfels W Frommberger F Godo M Goertz S Grabmayr P Hasegawa S Hansen K Harmsen J Heid E Hillert W Holvoet H Horikawa N Iwata T Van Hoorebeke L d'Hose N Jennewein P Kiel B Klein F Kondratiev R Lang M Lannoy B Leukel R Lisin V Menze D Meyer W Michel T Naumann J Panzeri A Pedroni P Pinelli T Preobrajenski I Radtke E Reicherz G Rohlof C Rostomyan T Sauer M 《Physical review letters》2003,91(19):192001
To verify the fundamental Gerasimov-Drell-Hearn (GDH) sum rule for the first time experimentally, we measured the helicity dependent total photoabsorption cross section with circularly polarized real photons and longitudinally polarized nucleons in the photon energy range 0.68-1.82 GeV with the tagged photon facility at ELSA. The experiment was carried out with a 4pi detection system, a circularly polarized tagged photon beam, and a frozen spin polarized proton target. The contribution to the GDH sum rule in this photon energy range is [49.9+/-2.4(stat)+/-2.2(syst)] microb. 相似文献