NOESY技术在地胆草倍半萜内酯化合物结构鉴定中的应用（I）

明确从地胆草中分离得到的两对牦牛儿内酯型的立体异构体即地胆草种内酯（scabertopin）、异地胆草种内酯（isoscabertopin）、异去氧地胆草内酯（isodeoxyelephantopin）和去氧地胆草内酯（deoxyelephantopin）的C-2相对构型；方法 NOESY技术，并结合这4个化合物的¹H NMR，¹³C NMR，HMQC谱；结果 两对立体异构体的NOESY谱有明显差异；结论 通过分析NOESY谱，找寻H-1相关信息，若发现H-1与H-8，H-9β和14-CH₃有NOE相关，可以判断化合物的C-2为α构型，若H-1与H-5，H-7，H-3α及H-9α之间有NOE相关，则化合物的C-2为β构型.     

Detection of low caloric power of coal by pulse fast-thermal neutron analysis

This paper introduces the analysis method and principle of pulse fast-thermal neutron analysis (PFTNA). A system for the measurement of low caloric power of coal by PFTNA is also presented. The 14 MeV pulse neutron generator and BGO detector and 4096 MCA were applied in this system. A multiple linear regression method applied to the data solved the interferential problem of multiple elements. The error of low caloric power between chemical analysis and experiment was less than 0.4 MJ/kg. This revised version was published online in July 2006 with corrections to the Cover Date.     

Investigation on nonradiative decay of I13/2→I15/2 transition of Er-doped oxide glasses

Nonradiative decay of ⁴I_13/2→⁴I_15/2 transition of Er³⁺ has been investigated in a series of oxide glasses. For Er³⁺-doped glass samples, the Judd-Ofelt analysis on absorption spectra was performed and the fluorescence lifetime was determined by extrapolating to zero Er³⁺ concentration limit. Infrared spectra were measured in order to investigate the influence of OH⁻ groups in different glasses. The effects of glass matrix on the decay rate were discussed from the viewpoint of phonon energy, variations of effective fields, and OH⁻ groups. Compared to other glasses, phosphate glass presents low quantum efficiency and large nonradiative decay rate due to its high phonon energy and hygroscopic behavior.     

稀磁半导体Zn1-xMnxTe吸收光谱压力红移的理论研究

以自由Mn²⁺离子的径向波函数为基础,通过引入电子云延伸效应系数κ来修正这一径向波函数,得到了稀磁半导体Zn_1-xMn_xTe晶体中Mn²⁺离子的径向波函数.以此波函数为基础,研究了Zn1-xMnxTe晶体吸收光谱的高压谱移特性,并且得到了吸收谱中四条谱线随压力的红移规律.     

The solvability conditions for inverse eigenproblem of symmetric and anti‐persymmetric matrices and its approximation

The problem of generating a matrix A with specified eigen‐pair, where A is a symmetric and anti‐persymmetric matrix, is presented. An existence theorem is given and proved. A general expression of such a matrix is provided. We denote the set of such matrices by ??????_Eⁿ. The optimal approximation problem associated with ??????_Eⁿ is discussed, that is: to find the nearest matrix to a given matrix A* by A∈??????_Eⁿ. The existence and uniqueness of the optimal approximation problem is proved and the expression is provided for this nearest matrix. Copyright © 2002 John Wiley & Sons, Ltd.     

大焦深成像系统仿真实验研究

如何增大非相干光学成像系统的焦深是应用光学研究领域的热点问题.本文对采用高次非球面光学掩模板与图像处理相结合增大成像光学系统焦深的新方法进行了深入分析,建立了大焦深成像系统仿真实验模型,并进行了大焦深成像系统仿真实验.实验结果证明了该方法在维持原相对孔径的同时使光学系统在较大的离焦范围内有好的成像质量.实际应用中还要综合考虑模板参量、信噪比等关键因素.     

基于分形维数的液体爆炸分散中界面破碎形态研究

通过对爆炸抛撒图象的处理,得到液体界面的曲线.采用盒维数的计算方式,计算界面曲线的分形维数.通过对各时刻液体界面分形维数的变化研究,分析爆炸抛撒近场阶段的变化过程,同时观察到蘑菇状尖顶的出现与破碎,以及空化区域的形成和消失现象。     

A New Pathway to Synthesize Cyclomercurated Ferrocenylimines Containing Heterocyclic Ring

The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine.This procedure provides an efficient method for the synthesis of cyclomerucurated ferrocenylimines containing heterocyclic ring which are difficultly synthesized by the conventional method.The reaction mechanism is proposed.     

陆地棉体细胞胚胎的发生和遗传转化条件初探

以陆地棉（冀棉20）下胚轴为外植体，在含KT0．3mg／L和2，4－D0．08mg／L的MS培养基上，诱导产生了胚性愈伤组织，继代培养不需要添加激素，胚性愈伤组织即分化为胚状体，并萌发出小芽，胚状体萌发过程与合子胚相似，但出现了一些畸形胚，解剖学方法观察发现，这些畸形胚的维管束系统不明显或形态异常，以农杆菌介导法对冀棉20胚状体及胚性愈伤组织进行了雪花莲凝集素（GNA）基因的遗传转化条件探索，并以GUS基域瞬间进行检测加以证实，得出农杆菌的浓度为O．D600＝0．8时，浸染时间为5min，共培养时间为3d，筛选培养基中卡那霉素浓度为75mg／L，对冀棉20胚状体及胚性愈伤组织转化是较为适合的。     

A Class of Cauchy Problem for Quasilinear Hyperbolic Systems with the Weakly Dissipative Terms

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