全文获取类型
收费全文 | 313894篇 |
免费 | 4271篇 |
国内免费 | 1091篇 |
专业分类
化学 | 170666篇 |
晶体学 | 4457篇 |
力学 | 13029篇 |
综合类 | 7篇 |
数学 | 36263篇 |
物理学 | 94834篇 |
出版年
2020年 | 1986篇 |
2019年 | 1954篇 |
2018年 | 1965篇 |
2017年 | 1875篇 |
2016年 | 3859篇 |
2015年 | 3236篇 |
2014年 | 4423篇 |
2013年 | 13978篇 |
2012年 | 10735篇 |
2011年 | 13366篇 |
2010年 | 8273篇 |
2009年 | 8257篇 |
2008年 | 12336篇 |
2007年 | 12574篇 |
2006年 | 12212篇 |
2005年 | 11155篇 |
2004年 | 10034篇 |
2003年 | 8850篇 |
2002年 | 8700篇 |
2001年 | 10111篇 |
2000年 | 7711篇 |
1999年 | 6115篇 |
1998年 | 4895篇 |
1997年 | 4735篇 |
1996年 | 4775篇 |
1995年 | 4364篇 |
1994年 | 4120篇 |
1993年 | 3942篇 |
1992年 | 4432篇 |
1991年 | 4296篇 |
1990年 | 4013篇 |
1989年 | 3831篇 |
1988年 | 4122篇 |
1987年 | 3784篇 |
1986年 | 3677篇 |
1985年 | 5320篇 |
1984年 | 5397篇 |
1983年 | 4380篇 |
1982年 | 4756篇 |
1981年 | 4796篇 |
1980年 | 4545篇 |
1979年 | 4667篇 |
1978年 | 4667篇 |
1977年 | 4647篇 |
1976年 | 4600篇 |
1975年 | 4509篇 |
1974年 | 4356篇 |
1973年 | 4524篇 |
1972年 | 2569篇 |
1971年 | 1879篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
951.
This paper presents a practical method for trimming the natural frequencies of an initially imperfect ring to simultaneously eliminate certain of the frequency splits present. Compared with previous work, the novel feature of this method is that the trimming masses are positioned at pre-selected locations on the ring. The basis for the proposed method is the concept of equivalent imperfection mass, which allows any imperfect ring to be considered as a perfect ring with equivalent imperfection masses attached. By considering this trimming problem it is deduced that it is possible to trim N pairs of modes simultaneously by removing (a minimum of) 2 N trimming masses at particular locations around the ring. By positioning the trimming masses at pre-selected locations, it is shown that a simple set of trimming masses can be calculated easily, and from this set an infinite number of solution sets can be found. Methods for generating these sets are outlined for the trimming of both a single and a dual pair of modes. In practice, it is likely that the trimming masses will be spaced regularly. For this special case, it is found that it is not possible to trim all single- and dual-mode pairs with any arrangement of masses. Validation of the derived simple solution set and the proposed procedure to generate further sets is achieved by studying a number of theoretical examples. 相似文献
952.
953.
L. Jackowska-Strumillo J. Sokolowski A. Żochowski A. Henrot 《Computational Optimization and Applications》2002,23(2):231-255
The new method is proposed for the numerical solution of a class of shape inverse problems. The size and the location of a small opening in the domain of integration of an elliptic equation is identified on the basis of an observation. The observation includes the finite number of shape functionals. The approximation of the shape functionals by using the so-called topological derivatives is used to perform the learning process of an artificial neural network. The results of computations for 2D examples show, that the method allows to determine an approximation of the global solution to the inverse problem, sufficiently closed to the exact solution. The proposed method can be extended to the problems with an opening of general shape and to the identification problems of small inclusions. However, the mathematical theory of the proposed approach still requires futher research. In particular, the proof of global convergence of the method is an open problem. 相似文献
954.
Backman Ulrika Jokiniemi Jorma K. Auvinen Ari Lehtinen Kari E.J. 《Journal of nanoparticle research》2002,4(4):325-335
We have prepared spherical non-agglomerated silver nanoparticles by an evaporation–condensation–dilution/cooling technique. Silver was evaporated from a crucible in a tubular flow reactor. A porous tube diluter was used to quench the carrier gas at the outlet of the reactor to enhance the formation of small particles and to suppress agglomeration and other particle growth mechanisms. The number size distribution of the prepared particles was measured with a differential mobility analyser–condensation nucleus counter combination and the size and the shape of the particles were analysed with transmission electron microscope. The system was modelled using a sectional aerosol dynamics computer code to estimate the importance of different aerosol processes. In all conditions the particles obtained were non-agglomerated and spherical. The mean particle diameter varied from 4 to 10-nm depending on boundary conditions. From the modelling studies it can be concluded that the nucleation rate is the most important parameter controlling the final particle size. 相似文献
955.
Sonya V. Roberson Albert J. Fahey Amit Sehgal Alamgir Karim 《Applied Surface Science》2002,200(1-4):150-164
We present a simple method for chemical modification of chlorosilane self-assembled monolayers (SAMs) on Si surfaces by exposure to a gradient of UV-ozone radiation to create stable substrates with a range of contact angles (θH2O≈5–95°) and surface energies on a single substrate. These gradient energy substrates are developed to potentially generate libraries for combinatorial studies of thin film phenomenology, where a systematic variation of interfacial surface energy represents one of the significant parameters along one axis. The graded oxidation process presents a systematic variation of surface chemical composition. We have utilized contact angle measurements and time-of-flight secondary ion mass spectrometry (ToF-SIMS) to investigate this variation for a series of ions, among which are SiCH3+, SiOH+ and COOH−. We show that the macroscopic measurements of surface free energy/contact angle correlate with the detailed analysis of surface chemistry (as assessed by ToF-SIMS) on these test substrates. 相似文献
956.
The oxidation behaviour of LnSiAlON (Ln=Y, La) glasses was studied at different temperatures (990-1150 °C) and under different water vapour pressures (360-2690 Pa). These results were also compared with those obtained under O2, N2/H2O or O2/H2O mixtures. When glasses are treated under a N2/H2O mixture, optical and SEM observations show porous scales. Transformations of the reaction rate data and a kinetic model show that there is only one limiting process occurring during oxidation. This rate limiting step is the progress of the chemical reaction at the internal interface. Determination of the pressure law dependence and thermodynamics calculations of water vapour molecules dissociation at the investigated temperatures allow us to suggest that the mechanism of oxidation corresponds to decomposition of water molecules on the oxynitride glass surface. 相似文献
957.
The pressure dependence of the experimental 7Li NMR spectra is reported for first stage lithium graphite (LiC6) intercalation compound at temperatures T = 232 and 293 K. This experiment together with the presented point charge model calculation of the 7Li quadrupole coupling constant allows an unambiguous determination of the sign of e2qQ/h which is negative: at p = 1 bar and T = 232 K. The averaged location of the electrons transferred from the Li intercalant to the graphite layers, as estimated in this study, is in excellent agreement with earlier theoretical energy-band calculations. The compressibility of LiC6 in the c-direction is predicted to be kc = 1.7 × 10-12cm2dyn-1, it agrees with estimates derived from the available phonon dispersion relations. 相似文献
958.
S. M. J. Kelly 《Optics Communications》1989,70(6):495-501
The effect of incorporating an empty external cavity into the feedback loop of a mode-locked laser is investigated. Particular attention is paid to the response of the mode-locking as the external cavity is detuned by a fraction of a wavelength from the round trip transit time associated with the laser. The results for two regimes of operation are presented. In the first case a series of short lived transients develop whereas the other case leads to a persistent intermittent Q-switching scenario, where mode-locking fails. The role of coupling between the cavities and the laser's memory time in relation to the results is discussed. A mechanism for the improved mode-locking observed with non-linear external cavities is suggested. 相似文献
959.
Simple and convenient methods for determining surface chemical composition of lignocellulosic materials are described. The
methods are based on vapor phase fluorine surface derivatization with either trifluoro acetic anhydride (TFAA), tri-fluoro
ethanol (TFE) or pentafluorophenyl hydrazine (PFPH) and subsequent Electron Spectroscopy for Chemical Analysis (ESCA). Model
cellulosic surfaces with well defined functionalities were used to optimize the derivatization reaction conditions. Detection
and accessibility of surface hydroxyl functional groups were investigated in cotton and regenerated cellulose as models. Carboxymethyl
cellulose (CMC) was used as a model surface for detection and quantification of carboxylic acid groups. Theoretical conversion
curves for derivatization reactions were calculated and used to evaluate the extent of the reactions on the model surfaces.
It was found that the conversion was higher for the regenerated cellulose and CMC than for cotton. The protocols developed
using the model surfaces were applied to a case study on wood fibers with different degrees of complexity, namely dissolving
and chemithermomechanical (CTMP) pulp. Untreated and oxygen-plasma modified pulps were compared with respect to the surface
composition of functional groups. According to the derivatization reactions, functionalities containing oxygen were significantly
increased on the plasma-treated samples. The effect of the treatment was found to be dependent on the type of pulp. Fluorine
derivatization is shown to be an unambiguous method for clear assessment of the chemical functionalities of cellulosic surfaces. 相似文献
960.
Cluster ions have been recognized as a superb primary species in time of flight secondary ion mass spectroscopy (ToF-SIMS) compared with monatomic primary ions, as they significantly enhance the secondary ion yields from bulk samples. Self-assembled monolayers provide an important system for studying the fundamental mechanism involved in the yield enhancement.We used a gold cluster ion source to analyze a new type of self-assembled monolayer: a fluorocarbon-grafted polyethylene terephthalate. In addition to the structure details, which helped to understand the grafting mechanism, ToF-SIMS analysis revealed that fluorocarbon secondary ion yield enhancements by cluster ions were due to the enhanced sputter efficiency. A larger information depth may also be expected from the enhancement. Both mathematical definitions of damage cross-section and disappearance cross-section were revisited under a new context. Another cross-section parameter, sputter cross-section, was introduced to differentiate the beam induced sputter process from damage process. 相似文献