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排序方式: 共有106条查询结果,搜索用时 31 毫秒
31.
Francesca P. A. Fabbiani Charlotte K. Leech Kenneth Shankland Andrea Johnston Philippe Fernandes Alastair J. Florence Norman Shankland 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(11):o659-o663
Bendroflumethiazide, or 3‐benzyl‐6‐(trifluoromethyl)‐3,4‐dihydro‐2H‐1,2,4‐benzothiadiazine‐7‐sulfonamide 1,1‐dioxide, is reported to crystallize as 1:1 solvates with acetone, C15H14F3N3O4S2·C3H6O, and N,N‐dimethylformamide, C15H14F3N3O4S2·C3H7NO. A detailed investigation of the crystal packing and intermolecular interactions is presented by means of Hirshfeld surface analysis. This analysis confirms the atomic positions of methyl H atoms of the solvent molecules that were inferred from the X‐ray data and provides a useful tool for structure validation. 相似文献
32.
We investigate nonlinear oscillations in a fourth-order partialdifferential equation which models a suspension bridge. Previouswork establishes multiple periodic solutions when a parameterexceeds a certain eigenvalue. In this paper, we use Leray-Schauderdegree theory to prove that if the parameter is increased further,beyond a second eigenvalue, then additional solutions are created. 相似文献
33.
P. Kittara A. Jiralucksanawong G. Yassin S. Wangsuya J. Leech 《International Journal of Infrared and Millimeter Waves》2007,28(12):1103-1114
We describe the design and performance of Potter horns at millimetre and submillimetre wavelength employing a novel software
package that we have developed, using Genetic Algorithm. The horn is easy to fabricate and exhibits excellent beam circularity
and low cross polarization over a 15% bandwidth which is sufficient for many applications. Excitation of the required higher
order modes is done by either a step or a flare discontinuity at the horn throat. In each case we provide design curves that
give the optimum parameters of the horn geometry as a function of frequency and beamwidth. The range of values provided covers
the parameters required for the design of horns for telescope feeds and various other instruments. The design curves show
clearly that the flare-step performance is superior to the traditional groove-step Potter horn. The simulations for designing
these horns were carried out at millimetre and submillimetre wavelengths but the results can be scaled to lower or higher
frequencies. A key component in the design method is the optimization software that searches for the correct magnitude and
location of the flare discontinuities. We have developed a software package based on the combination of modal matching, a
genetic algorithm (GA) and downhill simplex optimization. The genetic code is first used to locate the proximity of the global
minimum. The set of parameters obtained are then used as a starting point for the simplex method, which refines the parameters
to the required accuracy. 相似文献
34.
Kilner CA McInnes EJ Leech MA Beddard GS Howard JA Mabbs FE Collison D Bridgeman AJ Halcrow MA 《Dalton transactions (Cambridge, England : 2003)》2004,(2):236-243
Crystals of the title compound (1) contain two independent, centrosymmetric half-molecules per asymmetric unit. While both of these show Jahn-Teller elongated six-coordinate geometries, the lengths of the elongated Cu-N bonds in the two molecules differ by 0.117(2) A at 30 K. The structure of one of these molecules (molecule A) does not vary with temperature below 350 K. The other molecule (molecule B) shows Cu-N bond lengths that are temperature-dependent between 225 and 375 K, but do not vary further at lower temperature. This indicates a fluxional axis of Jahn-Teller elongation in this molecule at these higher temperatures. Consideration of the thermal parameters in these structures implies that the fluxionality in molecule B is frozen out near 150 K. This conclusion is supported by a Q-band powder EPR study. The d-d transition energies of molecules A and B have been calculated by several density function (DF) methods, including a time-dependent DF calculation. The crystallographic data have been reproduced using the vibronic coupling model of Burgi and Hitchman. This has shown that the different fluxionality regimes for molecules A and B are not a consequence of their different static molecular structures, but rather reflect their different local environments in the crystal. 相似文献
35.
Rochefort D Bourbonnais R Leech D Paice MG 《Chemical communications (Cambridge, England)》2002,(11):1182-1183
We have studied the oxidation of lignin model compounds by organic and transition metal-based mediators using either an enzyme or an electrolysis cell as the mediator oxidizing agent. Electrolysis of inorganic mediator seems a promising technology for pulp delignification. 相似文献
36.
Robert B. Leech 《Integral Equations and Operator Theory》2014,78(1):71-73
If A and B are contraction operators on a Hilbert space ${\mathcal{H}}$ that commute with a shift operator S, it is shown that A = BC for some contraction operator C on ${\mathcal{H}}$ that commutes with S if and only if ${AA^{*} \leq BB^{*}}$ . 相似文献
37.
38.
Jonathan Leech 《Semigroup Forum》2005,70(2):307-311
Given idempotents e and f in a ring R, if ef and fe are also idempotent, then e and f generate a skew lattice in R that splits, having order dividing 16. The skew Boolean algebra generated from e and f is also considered. 相似文献
39.
Neutron powder diffraction has been used to investigate the crystal and magnetic structure of the ionic ferromagnet Cs2CrCl4, Tc ~ 58K. Data taken at ambient temperature, 78 and 4.2K indicate the structure remains tetragonal at low temperatures. A ferromagnetic alignment of the spins is confirmed. The ordered moment at 4.2K is found to be 4.1 ± 0.2μB, and the best agreement between the calculated profile and the data suggests its direction lies at an angle of 56 ± 6° to the unique axis. 相似文献
40.
Rengaraj S Mani V Kavanagh P Rusling J Leech D 《Chemical communications (Cambridge, England)》2011,47(43):11861-11863
Layer-by-layer (LBL) assembly of alternate osmium redox polymers and glucose oxidase, at anode, and laccase, at cathode, using graphite electrodes form a membrane-less glucose/O(2) enzymatic fuel cell providing a power density of 103 μW cm(-2) at pH 5.5. 相似文献