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排序方式: 共有498条查询结果,搜索用时 15 毫秒
91.
Di Hu Dr. Yungen Liu Dr. Yau‐Tsz Lai Ka‐Chung Tong Dr. Yi‐Man Fung Dr. Chun‐Nam Lok Prof. Dr. Chi‐Ming Che 《Angewandte Chemie (International ed. in English)》2016,55(4):1387-1391
Identification of the molecular target(s) of anticancer metal complexes is a formidable challenge since most of them are unstable toward ligand exchange reaction(s) or biological reduction under physiological conditions. Gold(III) meso‐tetraphenylporphyrin ( gold‐1 a ) is notable for its high stability in biological milieux and potent in vitro and in vivo anticancer activities. Herein, extensive chemical biology approaches employing photo‐affinity labeling, click chemistry, chemical proteomics, cellular thermal shift, saturation‐transfer difference NMR, protein fluorescence quenching, and protein chaperone assays were used to provide compelling evidence that heat‐shock protein 60 (Hsp60), a mitochondrial chaperone and potential anticancer target, is a direct target of gold‐1 a in vitro and in cells. Structure–activity studies with a panel of non‐porphyrin gold(III) complexes and other metalloporphyrins revealed that Hsp60 inhibition is specifically dependent on both the gold(III) ion and the porphyrin ligand. 相似文献
92.
93.
Inspired by Durfee Conjecture in singularity theory, Yau formulated the Yau number theoretic conjecture(see Conjecture 1.3) which gives a sharp polynomial upper bound of the number of positive integral points in an n-dimensional(n≥3) polyhedron. It is well known that getting the estimate of integral points in the polyhedron is equivalent to getting the estimate of the de Bruijn function ψ(x, y), which is important and has a number of applications to analytic number theory and cryptography. We prove the Yau number theoretic conjecture for n = 6. As an application, we give a sharper estimate of function ψ(x, y) for 5≤y 17, compared with the result obtained by Ennola. 相似文献
94.
We use the polynomial formulation of the holomorphic anomaly equations governing perturbative topological string theory to derive the free energies in a scaling limit to all orders in perturbation theory for any Calabi–Yau threefold. The partition function in this limit satisfies an Airy differential equation in a rescaled topological string coupling. One of the two solutions of this equation gives the perturbative expansion and the other solution provides geometric hints of the non-perturbative structure of topological string theory. Both solutions can be expanded naturally around strong coupling. 相似文献
95.
This work describes a new microfluidic device developed for the rapid screening of solubility diagrams. In several parallel channels, hundreds of nanolitre volume droplets of a given solution are first stored with a gradual variation in the solute concentration. Then, the application of a temperature gradient along these channels enables us to read directly and quantitatively phase diagrams, concentration vs. temperature. We show, using a solution of adipic acid, that we can measure ten points of the solubility curve in less than 1 hr and with only 250 microL of solution. 相似文献
96.
This report describes a method to simultaneously determine 11 low-molecular-weight (LMW) organic acids and 16 chlorinated acid herbicides within a single run by a portable CE system with contactless conductivity detection (CCD) in a poly(vinyl alcohol) (PVA)-coated capillary. Under the optimized condition, the LODs of CE-CCD ranged from 0.056 to 0.270 ppm, which were better than for indirect UV (IUV) detection of the 11 LMW organic acids or UV detection of the 16 chlorinated acid herbicides. Combined with an on-line field-amplified sample stacking (FASS) procedure, sensitivity enhancement of 632- to 1078-fold was achieved, with satisfactory reproducibility (RSDs of migration times less than 2.2%, and RSDs of peak areas less than 5.1%). The FASS-CE-CCD method was successfully applied to determine the two groups of acidic pollutants in two kinds of environmental water samples. The portable CE-CCD system shows advantages such as simplicity, cost effectiveness, and miniaturization. Therefore, the method presented in this report has great potential for onsite analysis of various pollutants at the trace level. 相似文献
97.
We consider random Schr?dinger equations on
for d ≥ 3 with identically distributed random potential. Denote by λ the coupling constant and ψt the solution with initial data ψ0. The space and time variables scale as
with 0 < κ < κ0(d). We prove that, in the limit λ → 0, the expectation of the Wigner distribution of ψt
converges weakly to a solution of a heat equation in the space variable x for arbitrary L
2 initial data. The diffusion coefficient is uniquely determined by the kinetic energy associated to the momentum υ.
This work is an extension to the lattice case of our previous result in the continuum [8,9]. Due to the non-convexity of the
level surfaces of the dispersion relation, the estimates of several Feynman graphs are more involved.
Submitted: April 18, 2006. Accepted: October 12, 2006.
László Erdős: Partially supported by NSF grant DMS-0200235 and EU-IHP Network ‘Analysis and Quantum’ HPRN-CT-2002-0027.
Manfred Salmhofer: Partially supported by DFG grant Sa 1362/1-1 and an ESI senior research fellowship.
Horng-Tzer Yau: Partially supported by NSF grant DMS-0307295 and MacArthur Fellowship. 相似文献
98.
László Erdős Manfred Salmhofer Horng-Tzer Yau 《Communications in Mathematical Physics》2007,271(1):1-53
We consider random Schrödinger equations on \({\mathbb{R}^{d}}\) for d≥ 3 with a homogeneous Anderson-Poisson type random potential. Denote by λ the coupling constant and ψ t the solution with initial data ψ0. The space and time variables scale as \({x\sim \lambda^{-2 -\kappa/2}, t \sim \lambda^{-2 -\kappa}}\) with 0 < κ < κ0(d). We prove that, in the limit λ → 0, the expectation of the Wigner distribution of ψ t converges weakly to the solution of a heat equation in the space variable x for arbitrary L 2 initial data. The proof is based on a rigorous analysis of Feynman diagrams. In the companion paper [10] the analysis of the non-repetition diagrams was presented. In this paper we complete the proof by estimating the recollision diagrams and showing that the main terms, i.e. the ladder diagrams with renormalized propagator, converge to the heat equation. 相似文献
99.
Yau Shu Wong 《计算数学(英文版)》1989,7(2):209-216
Preconditionings have proved to be a powerful technique for accelerating the rate of convergence of an iterative method. This paper, which is concerned with the conjugate gradient algorithm for large matrix computations, investigates an approximate polynomial preconditioning strategy. The method is particularly attractive for implementation on vector computers. 相似文献
100.
Felix Finster Joel Smoller Shing-Tung Yau 《Communications in Mathematical Physics》1999,205(2):249-262
We consider for j=?, … a spherically symmetric, static system of (2j+1) Dirac particles, each having total angular momentum j. The Dirac particles interact via a classical gravitational and electromagnetic field.
The Einstein–Dirac–Maxwell equations for this system are derived. It is shown that, under weak regularity conditions on the
form of the horizon, the only black hole solutions of the EDM equations are the Reissner–Nordstr?m solutions. In other words,
the spinors must vanish identically. Applied to the gravitational collapse of a “cloud” of spin-?-particles to a black hole,
our result indicates that the Dirac particles must eventually disappear inside the event horizon.
Received: 2 November 1998 / Accepted: 23 February 1999 相似文献