全文获取类型
收费全文 | 1203篇 |
免费 | 60篇 |
国内免费 | 4篇 |
专业分类
化学 | 960篇 |
晶体学 | 7篇 |
力学 | 24篇 |
数学 | 132篇 |
物理学 | 144篇 |
出版年
2022年 | 11篇 |
2021年 | 15篇 |
2020年 | 18篇 |
2019年 | 10篇 |
2018年 | 19篇 |
2017年 | 12篇 |
2016年 | 36篇 |
2015年 | 32篇 |
2014年 | 32篇 |
2013年 | 66篇 |
2012年 | 93篇 |
2011年 | 92篇 |
2010年 | 60篇 |
2009年 | 49篇 |
2008年 | 95篇 |
2007年 | 67篇 |
2006年 | 83篇 |
2005年 | 83篇 |
2004年 | 55篇 |
2003年 | 61篇 |
2002年 | 39篇 |
2001年 | 15篇 |
2000年 | 16篇 |
1999年 | 11篇 |
1998年 | 8篇 |
1997年 | 10篇 |
1996年 | 15篇 |
1995年 | 8篇 |
1994年 | 8篇 |
1993年 | 4篇 |
1992年 | 8篇 |
1991年 | 5篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1987年 | 9篇 |
1986年 | 4篇 |
1985年 | 8篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 9篇 |
1980年 | 11篇 |
1979年 | 8篇 |
1978年 | 5篇 |
1977年 | 5篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 6篇 |
1973年 | 5篇 |
排序方式: 共有1267条查询结果,搜索用时 15 毫秒
41.
42.
43.
44.
Michèle Postel Félix Tomi Henri Li Kam Wah Laurence Mordenti Patricia Guillaume 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):453-457
Abstract Fe(NO)2XL and Fe(NO)X2L nitrosyl iron complexes, X = Cl, I, and L = HMPA, dppe, PPh3, activate molecular O2 to yield nitrato complexes. The phosphorous ligand is decisive for the oxidative power of these nitrates: with HMPA or dppe, oxygen transfer occurs only to phosphines. On going from HMPA to PPh3 the single nitrato complex obtained, Fe(NO)2X(OPPh3)2 selectively epoxidizes cyclohexene, and this is the first example of oxygen transfer from a nitrato ligand to an olefin. 相似文献
45.
46.
47.
Laurent Blasco Lucie Duracher Jean‐Pierre Forestier Laurence Vian Gilberte Marti‐Mestres 《Journal of Dispersion Science and Technology》2013,34(6):811-815
This work aims at presenting the viscoelastic behavior of bio‐mimetic monoglycerides used as emulsifier in a mixture made of two non‐miscible liquids, squalene and water. The measurement of the interfacial tension, carried out by the “pendant drop” method in “dynamic” mode, made it possible to characterize these amphiphilic molecules according to the value of their elastic modulus, ?, as well as their relaxation time, τR. The analysis of these parameters, as well as those developed in the previous publication [L. Blasco et al. (2006) Skin constituents as cosmetic ingredients. Part I: A Study of bio‐mimetic monoglyceride behavior at the squalene‐water interface by the “pendant drop” method in a static mode. J. Dispers. Sci. Technol., 27(6).] shows that the hydrocarbon chain structure, such as its length, the presence of one or more unsaturations, hydroxyl function, affects the behavior of surfactant molecules at the squalene/water interface. 相似文献
48.
A series of 9-(hetero)arylpurine derivatives has been prepared through N-arylation of 6-chloropurine with boronic acids in the presence of copper(II) acetate. Screening reaction conditions in terms of bases and solvents led to the successful coupling of a series of sterically demanding (hetero)arylboronic acids, never described so far. The coupling products were next readily converted into the target adenine derivatives. The described procedure provides easy access to original fragments for screening applications. Moreover these 9-aryl-6-chloropurine derivatives might be useful as intermediates for the preparation of purine derivatives with potential biological properties. 相似文献
49.
Abdelhouad Oukhrib Laurence Bonnafoux Armen Panossian Sandrine Waifang Duc Hanh Nguyen Martine Urrutigoity Françoise Colobert Maryse Gouygou Frédéric R. Leroux 《Tetrahedron》2014
A new family of non-symmetrical disubstituted dibenzophospholes possessing different steric and electronic effects have been synthesized and characterized. Their preliminary evaluation in rhodium-catalyzed hydroformylation reactions is presented. 相似文献
50.
Dr. Romain Ramozzi Dr. Nicolas Chéron Dr. Laurent El Kaïm Dr. Laurence Grimaud Dr. Paul Fleurat‐Lessard 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(29):9094-9099
Following our previous mechanistic studies of multicomponent Ugi‐type reactions, theoretical calculations have been performed to predict the efficiency of new substrates in Ugi–Smiles couplings. First, as predicted, 2,4,6‐trichlorophenol experimentally gave the corresponding aryl‐imidate. Theoretical predictions of nitrosophenols as good acidic partners were then successfully confirmed by experiments. In the latter case, the reaction offers a new access to benzimidazoles. 相似文献