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41.
Lejeune C Coelho C Bonhomme-Coury L Azaïs T Maquet J Bonhomme C 《Solid state nuclear magnetic resonance》2005,27(4):242-246
We show that it is possible to efficiently transfer magnetization from 31P to 29Si, using variable amplitude CP MAS experiment. This experiment is demonstrated by using Si5O(PO4)6, the synthesis protocol of which is described. From the obtained results, we show that the experiment allows the spectral edition of 29Si spectra from 31P→29Si CP, enabling the studies of derivatives involving Si–O–P linkages, such as phosphosilicate glasses, microporous silicoaluminophosphates (SAPO) and bioactive phosphosilicates. 相似文献
42.
Le Gal J Latapie L Gressier M Coulais Y Dartiguenave M Benoist E 《Organic & biomolecular chemistry》2004,2(6):876-883
Synthetic pathways to a range of novel semi-rigid tetradentate ligands, with sulfur, amido or amino donor groups, designed to coordinate technetium 99m have been developed. The technetium-99m complexes have been prepared and their stabilities in serum and by metathesis reaction via cysteine exchange reactions were compared. HPLC comparison of two (99m)Tc-complexes and their rhenium analogues led to the first proof of the nature of our radioactive complexes. 相似文献
43.
The efficiency of conventional diffractive optical elements with échelette-type profiles drops rapidly as the illumination wavelength departs from the blaze wavelength. We use high dispersion of artificial materials to synthesize diffractive optical elements that are blazed over a broad spectral range (approximately 1 octave) or for two different wavelengths. 相似文献
44.
Certain haloanisoles present at trace levels cause a large part of earthy-musty off-flavor problems in drinking water. These potent odorous chemicals come mainly through biomethylation of their corresponding halopenols. To enable the investigation of both families of compounds, a method involving solid-phase microextraction (SPME) was developed and the main parameters governing SPME were optimized. This method allows the simultaneous quantification of haloanisoles and halophenols at levels ranging from 1 to 100 or 250 ng/l, with detection limits of about 0.5 ng/l and could be applied to potable as well as raw surface waters. 相似文献
45.
Elayaraja Muthuswamy S. Sree Ramadevi H.N. Vasan Cécile Garcia Laure Noé Marc Verelst 《Journal of nanoparticle research》2007,9(4):561-567
A novel synthesis of inorganic–organic hybrid films containing well dispersed and almost uniform size Ag nanoparticles in
agar-agar matrix has been reported. The films are found to be highly stable for more than a year. The colloidal particles
of Ag can be obtained in large quantities in the form of a film or in the gel form when dispersed in agar-agar or by dissolving
in a suitable solvent as solution. Characterization has been done by UV–visible spectroscopy and TEM. The hybrid may be of
interest to study third-order non-linear susceptibility. 相似文献
46.
Joseph W. Rumer Sheng‐Yao Dai Matthew Levick Laure Biniek David J. Procter Iain McCulloch 《Journal of polymer science. Part A, Polymer chemistry》2013,51(6):1285-1291
Two novel dihydropyrroloindoledione (DPID)‐based copolymers have been synthesized in a two directional approach and characterized (gel permeation chromatography (GPC), ultraviolet‐visible (UV–vis), cyclic voltammetry, and computational models). These planar, broad absorption copolymers show promise for use in organic electronics, with deep energy levels and low bandgaps. The two‐directional Knoevenagel condensation used demonstrates the versatility of DPID as a useful yet underexploited conjugated unit. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
47.
48.
Two original dinuclear (LnYb, 3 and LnEr, 4) and one trinuclear CuIILnIIICuII (LnGd, 5) complexes derived from a polydentate non symmetrical Schiff base ligand H2L have been prepared. The ligand possesses two functions (phenol and oxime) able to coordinate the Ln ions, but structural studies (X-ray diffraction and powder X-ray diffraction) show that the CuII and LnIII ions are only bridged by the oximato (NO) pair. The missing phenoxo bridge is replaced by a surprising pseudo-bridge involving one oxygen atom of the nitrato anion linked to the Cu and Ln ions according to a η2: η1: μ mode. Although this latter contact has no role from the magnetic point of view, it introduces a large deformation of the unique bridging network. The CuYb complex 3 and the trinuclear CuGdCu complex 5 present antiferromagnetic interactions, with a JCuGd interaction equal to ?1.25 cm?1 in 5. The genuine single bridge can be considered as responsible for the antiferromagnetic character of the interaction. 相似文献
49.
Emi Evangelio Dr. Marie‐Laure Bonnet Dr. Miquel Cabañas Dr. Motohiro Nakano Dr. Jean‐Pascal Sutter Dr. Andrea Dei Prof. Vincent Robert Dr. Daniel Ruiz‐Molina Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(22):6666-6677
The different thermally induced intermolecular electron transfer (IET) processes that can take place in the series of complexes [M(Cat‐N‐BQ)(Cat‐N‐SQ)]/[M(Cat‐N‐BQ)2], for which M=Co ( 2 ), Fe ( 3 ) and Ni( 4 ), and Cat‐N‐BQ and Cat‐N‐SQ denote the mononegative (Cat‐N‐BQ?) or dinegative (Cat‐N‐SQ2?) radical forms of the tridentate Schiff‐base ligand 3,5‐di‐tert‐butyl‐1,2‐quinone‐1‐(2‐hydroxy‐3,5‐di‐tert‐butylphenyl)imine, have been studied by variable‐temperature UV/Vis and NMR spectroscopies. Depending on the metal ion, rather different behaviors are observed. Complex 2 has been found to be one of the few examples so far reported to exhibit the coexistence of two thermally induced electron transfer processes, ligand‐to‐metal (IETLM) and ligand‐to‐ligand (IETLL). IETLL was only found to take place in complex 3 , and no IET was observed for complex 4 . Such experimental studies have been combined with ab initio wavefunction‐based CASSCF/CASPT2 calculations. Such a strategy allows one to solicit selectively the speculated orbitals and to access the ground states and excited‐spin states, as well as charge‐transfer states giving additional information on the different IET processes. 相似文献
50.
Badr Benmansour Ludovic Stephan Jean-Yves Cabon Laure Deschamps Philippe Giamarchi 《Journal of fluorescence》2011,21(3):843-850
This work presents spectroscopic properties of some Endocrine Disrupting Compounds (EDCs), frequently found in food and in
natural water. Studied molecules belong to the groups of phenolic and phthalate EDCs. In a first part, we have examined their
absorption and fluorescence properties. Fluorescence emission wavelengths are about 300 nm for phenolic compounds and 360 nm
for phtalate compounds; main excitation wavelengths being comprised between 210 nm and 230 nm. Fluorescence lifetimes measured
are short (about 4 ns) and the fluorescence quantum yield has been determined. In a second part, to avoid the time consuming
solvent extraction step, an analytical application to evaluate the performance of a direct analysis by laser induced fluorescence
spectroscopy of ECDs traces in tap water and in raw water is presented. Good detection limits have been obtained, i.e.: 0.35 μg.L−1 of chlorophenol in tap water, which are always lower than the reported Predictive Non Efficient Concentration (PNEC). 相似文献