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961.
This work concerns the nature of chaotic dynamical processes. Sheldon Newhouse wrote on dynamical processes (depending on a parameter )x
x+1=T(x
n
; ), wherex is in the plane, such as might arise when studying Poincaré return maps for autonomous differential equations in IR3. He proved that if the system is chaotic there will very often be existing parameter values for which there are infinitely many periodic attractors coexisting in a bounded region of the plane, and that such parameter values would be dense in some interval. The fact that infinitely many coexisting sinks can occur brings into question the very nature of the foundations of chaotic dynamical processes. We prove, for an apparently typical situation, that Newhouse's construction yields only a set of parameter values of measure zero.This research was supported in part by grants from the Air Force Office of Scientific Research AFOSR 81-0217, the Consiglio Nazionale delle Ricerche-Comitato per le Matematiche, and the National Science Foundation DMS 84-19110On leave from: Dipartimento di Matematica G. Castel nuovo Universita di Roma La Sapienza P. le Aldo Moro 5, I-00185 Rome, Italy 相似文献
962.
Alvaro M Corma A Das D Fornés V García H 《Chemical communications (Cambridge, England)》2004,(8):956-957
Preparation of hybrid organic-inorganic MCM-41 and SBA-15 silicas functionalized with perfluoroalkylsulfonic acid groups has been achieved in a single step by reacting the mesoporous silicas with 1,2,2-trifluoro-2-hydroxy-1-trifluoromethylethane sulfonic acid beta-sultone; the catalysts showed higher activity than commercial Nafion-silica composite for the esterification of long chain fatty acids with ethanol. 相似文献
963.
A. Caubet A. Labarta R. Rodríguez A. Fernandez E. Molins V. Moreno J. Tejada 《Hyperfine Interactions》1986,28(1-4):773-776
By means of57Co Mössbauer emission spectroscopy and magnetic susceptibility measurements, the local symmetries and electronic structure of the Co(II) ions in the Co-5IMO and Co-5GMP complexes in the hydrated and dehydrated forms have been determined. 相似文献
964.
965.
Mokhammad Arif G. V. Samoilenko Yu. G. Sergeev L. N. Blinov 《Russian Journal of Applied Chemistry》2005,78(9):1398-1402
The phase diagram of the system Sb2S3-AgI was constructed from data of the differential thermal and X-ray phase analyses. The physicochemical properties of glassy and crystalline alloys were studied. 相似文献
966.
967.
Ch. V. Subba Reddy Y. Y. Qi W. Jin Q. Y. Zhu Z. R. Deng W. Chen Sun-il Mho 《Journal of Solid State Electrochemistry》2007,11(9):1239-1243
Molybdenum trioxide (MoO3) xerogel films modified with poly(vinyl alcohol)+poly(vinyl pyrrolidone) (PVP+PVA) polyblends were obtained by ion-exchange
method with sol-gel technique. Investigations were conducted using X-ray “diffractometry”, Fourier transform infrared spectroscopy,
and cyclic voltammetry. The results show that the H atoms in polyblend are H-bonded with the O atoms in the Mo=O bonds of
MoO3 xerogel, which effectively shield the electrostatic interaction between MoO3 interlayer and Li+ ions when MoO3 xerogel is modified by the intercalation of (PVP+PVA). The reversibility of the insertion/extraction of Li+ ions is greatly improved by the modification with polyblend of MoO3 nanocomposite films. MoO3 and (PVP+PVA)
x
MoO3 (x = 0, 0.5) nanobelts were obtained by a simple hydrothermal process from MoO3 sol. The electrochemical cells with configuration Li/(LiPF6+EC+DMC)/MoO3 modified by (PVP+PVA) were fabricated and their discharge profiles studied. 相似文献
968.
Elías Molins Amílcar Labarta Javier Tejada Amparo Caubet Santiago Alvarez 《Transition Metal Chemistry》1983,8(6):377-380
Summary Magnetic moments and57Fe Mössbauer spectra at room temperature and at liquid nitrogen temperature of polynuclear ligand-bridged iron phthalocyanines, FePcL (L = pyrazine and 4,4-bipyridyl), are reported. The experimental data are in agreement with a pseudo-octahedral environment around the iron(II) cation. Partially oxidized derivatives, FePc(pz)I0.26 and FePc(bipy)I1.06 have been synthesized and their57Fe Mössbauer spectra and magnetic moments within the same temperature range obtained. Oxidation is shown to be metal centred and the iodine is found to be in I– form for FePc(pz)0.26 and as both I– and I
3
–
species for FePc(bipy)I1.06. While the magnetic moment of FePc(pz) increases upon oxidation, the opposite occurs for FePc(bipy). 相似文献
969.
970.
Leonard S Van Schepdael A Iványi T Lázár I Rosier J Vanstockem M Vermeersch H Hoogmartens J 《Electrophoresis》2005,26(3):627-632
A capillary electrophoretic (CE) method was developed for the separation of diastereoisomers of a new human immunodeficiency virus (HIV) protease inhibitor TMC114. In total 16 isomers of this drug have been synthesized (eight pairs of enantiomers). We succeeded in the separation of the eight diastereoisomers, but no enantiomers could be separated. Because of the high similarity and water-insolubility of these isomers, the separation is a real challenge. Different CE modes were tried out: capillary zone electrophoresis (CZE), nonaqueous capillary electrophoresis (NACE), micellar electrokinetic capillary chromatography (MEKC), and microemulsion electrokinetic capillary chromatography (MEEKC). Only MEEKC offered resolution of these compounds. 相似文献