Spectroscopic and Structural Study of the 1：2 Aluminium（Ⅲ） Complex of Quercetin

Complex formation between aluminium and quercetin（Q） in methanol was investigated by means of 27^Al solid-state, 13^C and 1^H NMR and MS（ESI）, UV and IR spectra. Formation of the 1：2 complex was favored in methanol relative to all other solvent and the predominant species observed of Al（Ⅲ） has a 1：2 stoichiometry. The fine structure of 1：2 aluminum complex of quercetin was that the aluminum central atom chelated with two quereetin molecules and two methoxyl groups between two five membered rings, its coordination is six, the chelated site was 3-hydroxy-4-carbonyl.     

A note on acyclic domination number in graphs of diameter two

A subset S of the vertex set of a graph G is called acyclic if the subgraph it induces in G contains no cycles. S is called an acyclic dominating set of G if it is both acyclic and dominating. The minimum cardinality of an acyclic dominating set, denoted by γ_a(G), is called the acyclic domination number of G. Hedetniemi et al. [Acyclic domination, Discrete Math. 222 (2000) 151-165] introduced the concept of acyclic domination and posed the following open problem: if δ(G) is the minimum degree of G, is γ_a(G)?δ(G) for any graph whose diameter is two? In this paper, we provide a negative answer to this question by showing that for any positive k, there is a graph G with diameter two such that γ_a(G)-δ(G)?k.     

在线滤波技术在光纤马赫-德尔交叉复用器中的应用

为构造出与理想梯形滤波器接近的滤波形状，在单级光纤马赫-德尔交叉复用器的基础上，引入在线滤波技术；通过增加干涉级数和调整2对干涉臂的干涉长度和耦合器的耦合比，实现了逼近宽带陡沿的滤波输出。通过与梯形滤波器傅里叶展开式的比较，计算得到了器件的最佳参数，器件的滤波性能以及温度稳定性相对于单级结构得到了明显提高。根据理论计算，成功制作出通道间隔为50GHz的样品器件。其输出为-0.5dB，带宽大于0.185nm，相邻通道隔离度大于30dB，满足了DWDM系统指标要求。     

表面活性剂对均相沉淀法制备单晶Ce2O(CO3)2￠H2O微粉形貌及 形成机理的影响

在尿素及硝酸铈的混合溶液中分别加入表面活性剂CTAB、 PEG19000、OP-10,利用均相沉淀法合成了不同形貌的CeO2超细前驱体Ce2O(COa)2·H2O,采用X射线衍射及透射电子显微镜等测试手段,对产品的物相和形貌进行了表征．实验结果表明,所得产品均为斜方晶系的单晶Ce2O(CO3)2·H2O,且表面活性剂的加入使晶体的晶化程度明显提高;添加不同的表面活性剂得到不同形貌尺寸的产物: 阳离子型表面活性剂CTAB对Ce2O(CO3)2·H2O晶体的形貌影响不大,所得产物尺寸变小,且分散性得到一定的改善;非离子型表面活性剂对所得产物的形貌影响显著．加入PEG19000和OP-10分别得到了形状排列有序的、尺寸较均匀的、较规则无团聚的微米棒及具有紧密结合中心的发散状的花样微粒．不同形貌前驱体的形成与晶粒形成生长机理的改变有关．     

广义凸集的支撑函数

本文讨论了笔者在[1]中提出的伪凸集,拟凸集的支撑函数与障碍锥的性质,并通过这些性质得出了二个闭性准则。     

Effects of target gas in collision-induced dissociation using a double quadrupole mass spectrometer and radiofrequency

Collision-induced dissociation (CID) of polyatomic ions sampled from an rf-powered glow discharge is examined by using three target gases including atomic (Ar and Xe) and molecular species (N2). Collisions with these targets in the first quadrupole of the double quadrupole system result in the loss of discharge species by dissociation, symmetric and asymmetric charge exchange, and scattering, each to varying degrees. These processes are seen to be a function of the relative mass, size... and ionization potentials of the target species, as well as the collision center-of-mass energies. In light of the comparisons, xenon appears to be the best collision target for both CID and charge exchange because of its relatively low ionization potential and high dissociation efficiency of polyatornic species. Evidence for both symmetric and asymmetric charge exchange is presented for Ar and Xe target gases.     

离子束引起的在Al／Cr双层薄膜界面处的原子混合

用600keV的Kr~ 离子轰击Al/Cr双层薄膜样品进行界面原子反应及相互混合的研究。实验样品是在单晶硅上蒸镀约500nm厚的铝膜,相继再蒸上所需厚度的铬膜而制成的。轰击剂量为2.0×10~(15)-2.5×10~(16)Kr~ /cm~2。用2.0MeVa粒子对轰击前后的样品进行了卢瑟福背散射(RBS)分析,发现界面处有明显的原子混合存在;当轰击剂量≥1.0×10~(16)Kr~ /cm~2时,RBS谱出现有明显的坪台,经拟合计算和x射线衍射(XRD)测量证实确有化合物Al_(13)Cr_2存在;还分别得到了原子混合量及混合效率与轰击剂量的关系;最后对界面处的原子混合机制进行了讨论。