17-channels S band multiwavelength Brillouin/Erbium Fiber Laser co-pump with Raman source

In this paper, we propose and demonstrate a stable Brillouin-Erbium Fibre Laser (BEFL) capable of generating up to 17 lasing wavelengths in the Short-Wave length (S-band) region. The proposed setup uses a 7.7 km Dispersion Compensating Fibre (DCF) to act as a non-linear gain medium and a 30 m long Depressed-Cladding Erbium Doped Fibre (DC-EDF) as an optical amplifier for amplification in the S-band region. The proposed BEFL has an optimum tuning range of 1499 to 1502 nm and is capable of generating 17 lasing wavelengths with peak powers of between −20 to −15 dBm when injected with a Brillouin Pump (BP) of 5 dBm at 1499 nm and a Raman Pump (RP) of 300 mW at 1420 nm.     

Computations for the familial analysis of binary traits

For familial aggregation of a binary trait, one method that has been used is the GEE2 (generalized estimating equation) method corresponding to a multivariate logit model. We solve the complex estimating equations for the GEE2 method using an automatic differentiation software which computes the derivatives of a function numerically using the chain rule of the calculus repeatedly on the elementary operations of the function. Based on this, we are able to show in a simulation study that the GEE2 estimates are quite close to the maximum likelihood estimates assuming a multivariate logit model, and that the GEE2 method is computationally faster when the dimension or family size is larger than four.     

Novel chalcones derived from 2‐chloro‐3‐formyl‐6‐methylquinoline

Molecules of (E)‐3‐(2‐chloro‐6‐methylquinolin‐3‐yl)‐1‐(5‐iodo‐2‐thienyl)prop‐2‐en‐1‐one, C₁₇H₁₁ClINOS, (I), and (E)‐3‐(2‐chloro‐6‐methylquinolin‐3‐yl)‐1‐(5‐methyl‐2‐furyl)prop‐2‐en‐1‐one, C₁₈H₁₄ClNO₂, (II), adopt conformations slightly twisted from coplanarity. Both structures are devoid of classical hydrogen bonds. However, nonclassical C—H...O/N interactions [with C...O = 3.146 (5) Å and C...N = 3.487 (3) Å] link the molecules into chains extended along the b axis in (I) and form dimers with an R₂²(8) motif in (II). The structural analysis of these compounds provides an insight into the correlation between molecular structures and intermolecular interactions in compounds for drug development.     

Carbonyl and thiocarbonyl compounds. XI. Synthesis of halogenated benzodioxoles by the action of tetrahalo-o-benzoquinones on benzophenone hydrazones and their cleavage by nucleophilic reagents

p,p′-Dichloro-, p,p′-dimethyl- and p,p′-dimethoxybenzophenone hydrazones react with tetrachloro- and tetrabromo-o-benzoquinone to give directly the halogenated benzodioxoles (IIIa-IIIf), respectively, together with the corresponding tetrahalocatechol. Cleavage of the dioxole ring by nucleophilic reagents depends markedly on the nature of the substituents. The dimethoxyderivatives (IIIc) and (IIIf) proved to be unusually reactive toward cleavage by dilute mineral acids, lithium aluminum hydride, hydrazines and malonitrile, whereas the dichloro analog behaves normally and is not cleaved under the same conditions.     

Oxazolidinone polycyclitols. Stereospecific synthesis of novel aminocarbasugars with oxazolidinone ring

Two new oxazolidinone polycyclitols, 4,5,7,8,9-pentahydroxy-3-tosyldecahydronaphtho [2,1-d]oxazol-2(9bH)-one and 4,5,6,7,8-pentahydroxy-3-tosyldecahydronaphtho [2,1-d]oxazol-2(9bH)-one were synthesized starting from p-benzoquinone. An endo selective Diels–Alder cycloaddition between p-benzoquinone and 1-acetoxybutadiene followed by stereoselective reduction with NaBH₄–CeCl₃·7H₂O led to the formation of an allylic cis-diol. The obtained diols were protected with p-TsNCO to yield bis-carbamates and then a palladium-catalyzed ionization/cyclization reaction produced two oxazolidinone derivatives. Oxidation of the two double bonds in either oxazolidinones with OsO₄ followed by acetylation produced oxazolidinone-pentaacetates whose exact configurations were determined by X-ray diffraction analysis. Controlled removal of the acetate groups furnished the desired two new oxazolidinone polycyclitols.     

An Efficient and Facile Synthesis of Novel Benzimid-(Thi) Azole Dicarboxaldehydes as a Versatile Precursors for new Ox-, Thi-and Diazepine Derivatives

Abstract

Novel 2-cyanomethylbenzimid-(thi)-azole-2,2-dicarboxaldehydes were prepared in quantitative yields and reacted easily with o-aminophenol derivatives to yield new multi-functionallized ox-, thi- and diazepine derivatives in one-pot reaction.     

Molecular imprinted membrane biosensor for pesticide detection: Perspectives and challenges

Polymers are crucial component for modern sensor devices. However, comprehensive research on polymer sensor technology is still going strong. Molecular imprinted membrane (MIM) is a great design that demonstrates acceptable recognition ability when integrated with a sensing transducer. Generally, the detection technique that has been widely and sparingly used for pesticide is mass spectrometry merged with gas and/or liquid chromatography. Nevertheless, this review focuses not on these common methods but on the specific methodology of MIM biosensor for the analysis of pesticides. Finally, the transduction schemes of the MIM sensor are reviewed. The interest of this article is sketched to the trends and challenges present in this field of study.     

Irradiation effects on copper

Copper, one of the most significant metals, is exposed to IR radiation. A Nd:YAG laser (1064 nm, 1.1 MW, 12 ns) has been used to irradiate fine polished and annealed samples (4 N, 1×1×0.3 cm³) with 100 laser shots under a vacuum of ～10^?6 torr. The laser focal spot size and power density on the target were 12 μm and 3×10¹² Wm^?2 respectively. The surface and structural studies were performed by analyzing scanning electron micrographs and X-ray diffractograms (XRDs), respectively. Laser ablation results in boiling, splashing, hydrodynamical sputtering and exfoliation along with other relevant phenomena. The XRD patterns of the exposed sample indicate a change in diffraction intensity and grain sizes. The atomic planes remain undisturbed for the irradiated target. The information collected is useful for investigating the complexities found in radiation–metal interactions.     

QCM gas phase detection with ceramic materials—VOCs and oil vapors

Titanate sol–gel layers imprinted with carbonic acids were used as sensitive layers on quartz crystal microbalance. These functionalized ceramics enable us detection of volatile organic compounds such as ethanol, n-propanol, n-butanol, n-hexane, n-heptane, n-/iso-octane, and n-decane. Variation of the precursors (i.e., tetrabutoxy titanium, tetrapropoxy titanium, tetraethoxy titanium) allows us to tune the sensitivity of the material by a factor of 7. Sensitivity as a function of precursors leads to selective inclusion of n-butanol vapors down to 1 ppm. The selectivity of materials is optimized to differentiate between isomers, e.g., n- and iso-octane. The results can be rationalized by correlating the sensor effects of hydrocarbons with the Wiener index. A mass-sensitive sensor based on titanate layer was also developed for monitoring emanation of degraded engine oil. Heating the sensor by a meander avoids vapor condensation. Thus, a continuously working oil quality sensor was designed.     

Multivalued generalized nonlinear contractive maps and fixed points

We introduce some notions of generalized nonlinear contractive maps and prove some fixed point results for such maps. Consequently, several known fixed point results are either improved or generalized including the corresponding recent fixed point results of Ciric [L.B. Ciric, Multivalued nonlinear contraction mappings, Nonlinear Anal. 71 (2009) 2716-2723], Klim and Wardowski [D. Klim, D. Wardowski, Fixed point theorems for set-valued contractions in complete metric spaces, J. Math. Anal. Appl. 334 (2007) 132-139], Feng and Liu [Y. Feng, S. Liu, Fixed point theorems for multivalued contractive mappings and multivalued Caristi type mappings, J. Math. Anal. Appl. 317 (2006) 103-112] and Mizoguchi and Takahashi [N. Mizoguchi, W. Takahashi, Fixed point theorems for multivalued mappings on complete metric spaces, J. Math. Anal. Appl. 141 (1989) 177-188].