全文获取类型
收费全文 | 367篇 |
免费 | 5篇 |
专业分类
化学 | 228篇 |
晶体学 | 6篇 |
力学 | 9篇 |
数学 | 50篇 |
物理学 | 79篇 |
出版年
2022年 | 5篇 |
2021年 | 7篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 5篇 |
2014年 | 8篇 |
2013年 | 25篇 |
2012年 | 27篇 |
2011年 | 35篇 |
2010年 | 9篇 |
2009年 | 11篇 |
2008年 | 10篇 |
2007年 | 28篇 |
2006年 | 14篇 |
2005年 | 16篇 |
2004年 | 11篇 |
2003年 | 15篇 |
2002年 | 15篇 |
2001年 | 6篇 |
2000年 | 2篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1985年 | 3篇 |
1984年 | 5篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 3篇 |
1975年 | 7篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1972年 | 3篇 |
1970年 | 2篇 |
1962年 | 3篇 |
1960年 | 2篇 |
1959年 | 2篇 |
1955年 | 2篇 |
1948年 | 9篇 |
1947年 | 2篇 |
1945年 | 2篇 |
1939年 | 3篇 |
1936年 | 2篇 |
排序方式: 共有372条查询结果,搜索用时 15 毫秒
31.
P. Pardhasaradhi D. Madhavi Latha P. V. Datta Prasad G. Padmaja Rani P. R. Alapati V. G. K. M. Pisipati 《Journal of Thermal Analysis and Calorimetry》2013,111(2):1483-1490
As a part of the systematic studies on symmetric liquid crystal dimer homologous series, α,ω-bis-(4-n-alkylaniline benzylidene-4′-oxy) alkanes, (referred to as m.OnO.m with m = 3, 4, and 5; and n = 8, 9, and 10), we present in this article the nature of phase transitions across isotropic–nematic and nematic–smectic-A (N–SmA) phases exhibited by the just mentioned compounds. The methods employed are differential scanning calorimetry and dilatometry. The compounds studied were 3.O8O.3, 4.O8O.4, and 5.O8O.5; and 3.O9.03, 5.O9O.5, 3.O10O.3, 4.O10O.4, and 5.O10O.5. Different from the case of their corresponding monomers, all these compounds exhibit a nematic phase only with the exception of 5.O8O.5 which exhibits a SA phase in addition to the nematic phase. The phase transitions viz., isotropic–nematic transitions studied in all these compounds were confirmed to be of first-order nature, whereas the N–SmA transition exhibited by the compound 5.O8O.5 only was found to be of second-order nature. We also report in this article the calculated density jumps, thermal expansion coefficient maxima, and pressure dependence of transition temperatures which are analyzed in the light of the available literature data. 相似文献
32.
33.
34.
35.
36.
Arvind Venkataraman Miriam Rosenbaum Jan B.A. Arends Rayko Halitschke Largus T. Angenent 《Electrochemistry communications》2010,12(3):459-462
Here, we show that quorum sensing (QS) modulates the current generation of the anode-respiring bacterium Pseudomonas aeruginosa because it controls the production of phenazines, which mediate the electron transfer to the anode. The current generation by a wildtype (WT) strain P. aeruginosa PA14 and the GacS/GacA protein-regulatory mutant retS was investigated under different environmental conditions. The retS mutant generated significantly higher current (45-fold) than the WT under anaerobic conditions. Anaerobic current generation by the WT was 28-fold higher with extraneously supplied lactones (a QS-signaling molecule). Compared to anaerobic conditions, the WT with some oxygen (microaerobic conditions) exhibited enhanced phenazine production (39-fold) and current levels (48-fold). Iron-rich medium and microaerobic conditions had a negative impact on current generation by retS. All these results were directly linked to QS activity in P. aeruginosa, thus, demonstrating the importance of this bacterial communication system for current generation in BESs. We also show that BESs represent a new tool for real-time investigation of phenazine-related QS activity. 相似文献
37.
Syahmi AR Vijayarathna S Sasidharan S Latha LY Kwan YP Lau YL Shin LN Chen Y 《Molecules (Basel, Switzerland)》2010,15(11):8111-8121
Elaeis guineensis (Arecaceae) is widely used in West African traditional medicine for treating various ailments. An evaluation on the toxicity of extracts of this plant is crucial to support the therapeutic claims. The acute oral toxicity and brine shrimp lethality of a methanolic extract of this plant was tested. Oral administration of crude extract at the highest dose of 5,000 mg/kg resulted in no mortalities or evidence of adverse effects, implying that E. guineensis is nontoxic. Normal behavioral pattern, clinical signs and histology of vital organs confirm this evidence. The E. guineensis extracts screened for toxicity against brine shrimp had 50% lethal concentration (LC??) values of more than 1.0 mg/mL (9.00 and 3.87 mg/mL, at 6 and 24 h, respectively), confirming that the extract was not toxic. Maximum mortalities occurred at 100 mg/mL concentration while the least mortalities happened to be at 0.195 mg/mL concentration. The results of both tests confirm that E. guineensis is nontoxic and hence safe for commercial utilization. 相似文献
38.
We propose and demonstrate a technique for electrical detection of polarized spins in semiconductors in zero applied magnetic fields. Spin polarization is generated by optical injection using circularly polarized light which is modulated rapidly using an electro-optic cell. The modulated spin polarization generates a weak time-varying magnetic field which is detected by a sensitive radio-frequency coil. Using a calibrated pickup coil and amplification electronics, clear signals were obtained for bulk GaAs and Ge samples from which an optical spin orientation efficiency of 4.8% could be determined for Ge at 1342 nm excitation wavelength. In the presence of a small external magnetic field, the signal decayed according to the Hanle effect, from which a spin lifetime of 4.6±1.0 ns for electrons in bulk Ge at 127 K was extracted. 相似文献
39.
K. Madhavi Latha 《Journal of Quantitative Spectroscopy & Radiative Transfer》2006,101(2):367-379
The extent to which airborne particles penetrate into the human respiratory system is determined mainly by their size, with possible health effects. The research over the scientific evidence of the role of airborne particles in adverse health effects has been intensified in recent years. In the present study, seasonal variations of PM10 and its relation with anthropogenic activities have been studied by using the data from UK National Air Quality Archive over Reading, UK. The diurnal variation of PM10 shows a morning peak during 7:00-10:00 LT and an evening peak during 19:00-22:00 LT. The variation between 12:00 and 17:00 LT remains more or less steady for PM10 with the minimum value of ∼16 μg m−3. PM10 and black smoke (BS) concentrations during weekdays were found to be high compared to weekends. A reduction in the concentration of PM10 has been found during the Christmas holidays compared to normal days during December. Seasonal variations of PM10 showed high values during spring compared to other seasons. A linear relationship has been found between PM10 and NOx during March, July, November and December suggesting that most of the PM10 is due to local traffic exhaust emissions. PM10 and SO2 concentrations showed positive correlation with the correlation coefficient of R2=0.65 over the study area. Seasonal variations of SO2 and NOx showed high concentrations during winter and low concentrations during spring. Fraction of BS in PM10 has been found to be 50% during 2004 over the study area. 相似文献
40.
The propagation of a first-order electromagnetic discontinuity is discussed. Expressions are obtained for the possible velocities of propagation as functions of the field strengths ahead of the surface of discontinuity. Expressions are also obtained for the growth in the magnitude of the discontinuity as the wave progresses. 相似文献