Energy transport in one-dimensional thermoelectric systems

The efficiency of thermoelectric power generators and the coefficient of performance of thermoelectric refrigerators increase rapidly in the region of small ZT, and then level off to a flat curve in the region of large ZT, where ZT is the figure of merit. Therefore, simply because one-dimensional thermoelectric materials have high ZT predicted theoretically does not imply that efficient thermoelectric devices can be built with such one-dimensional systems. Our numerical analysis, based on the fundamental thermodynamics which is independent of material systems, with emphasis on energy transport has confirmed this conjecture.     

Minimum detection efficiency for a loophole-free atom-photon bell experiment

In Bell experiments, one problem is to achieve high enough photodetection to ensure that there is no possibility of describing the results via a local hidden-variable model. Using the Clauser-Horne inequality and a two-photon nonmaximally entangled state, a photodetection efficiency higher than 0.67 is necessary. Here we discuss atom-photon Bell experiments. We show that, assuming perfect detection efficiency of the atom, it is possible to perform a loophole-free atom-photon Bell experiment whenever the photodetection efficiency exceeds 0.50.     

Influence of non-singular stress terms and specimen geometry on small-scale yielding at crack tips in elastic-plastic materials

The plane strain elastic-plastic state at a crack tip is determined for compact tension, bend, double edge-cracked and centre-cracked specimens using a finite element method with triangular constant-strain elements. The solutions are found to differ by 10 to 30 per cent at the ASTM-limit as regards fracture surface displacement, normal stress and plastic zone size. In order to bring the boundary layer solution for the crack problem into agreement with the solution for a specific specimen one has to modify this solution. The modification consists of an addition to the boundary tractions for the boundary layer problem of tractions corresponding to the non-singular, constant second term in a series expansion of the normal stress parallel to the crack plane.     

Low-Energy Collisions of Protonated Enantiopure Amino Acids with Chiral Target Gases

Here we report on the gas-phase interactions between protonated enantiopure amino acids (l- and d-enantiomers of Met, Phe, and Trp) and chiral target gases [(R)- and (S)-2-butanol, and (S)-1-phenylethanol] in 0.1–10.0 eV low-energy collisions. Two major processes are seen to occur over this collision energy regime, collision-induced dissociation and ion-molecule complex formation. Both processes were found to be independent of the stereo-chemical composition of the interacting ions and targets. These data shed light on the currently debated mechanisms of gas-phase chiral selectivity by demonstrating the inapplicability of the three-point model to these interactions, at least under single collision conditions.

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Graphical Abstract

     

Instability and failure of internally pressurized ductile metal cylinders

Forlong, ductile, thick-walled tubes under internal pressure instabilities and final failure modes are studied experimentally and theoretically. The test specimens are closed-end cylinders made of an aluminum alloy and of pure copper and the experiments have been carried out for a number of different initial external radius to internal radius ratios. The experiments show necking on one side of the tubes at a stage somewhat beyond the maximum internal pressure. All tubes, except for one aluminum alloy tube, failed by shear fracture under decreasing pressure. The aluminum alloy tubes exhibited localized shear deformations in the neck region prior to fracture and also occasionally surface wave instabilities. The numerical investigation is based on an elastic-plastic material model for a solid that develops a vertex on the yield surface, using representations of the uniaxial stress-strain curves found experimentally. In contrast to the simplest flow theory of plasticity this material model predicts shear band instabilities at a realistic level of strain. A rather sharp vertex is used in the material model for the aluminum alloy, while a more blunt vertex is used to characterize copper. The theoretically predicted bifurcation into a necking mode, the cross-sectional shape of the neck, and finally the initiation and growth of shear bands from the highly strained internal surface in the neck region are in good agreement with the experimental observations.     

Hollow fiber liquid phase microextraction as a preconcentration and clean-up step after pressurized hot water extraction for the determination of non-steroidal anti-inflammatory drugs in sewage sludge

A method for the quantitative determination of non-steroidal anti-inflammatory drugs (NSAIDs) in sewage sludge was developed and validated. The target compounds were extracted using pressurized hot water extraction (PHWE) and then purified and preconcentrated by three-phase hollow fiber liquid phase microextraction (HF-LPME) followed by LC–ESI-MS analysis. The PHWE was optimized with regard to the pH of solvent as well as other operational parameters. The optimum conditions were 0.01 M NaOH as the extraction solvent, temperature of 120 °C, pressure of 100 bar, static time 5 min, 5 cycles, flush volume 90% and purge time 60 s. Spike recoveries for sludge samples spiked at 200 ng g⁻¹ were in the range of 101–109% but for the native drugs in non-spiked sludge samples, recoveries were 38.9%, 59.8%, 90.3% and 47.8% for ketoprofen, naproxen, diclofenac and ibuprofen, respectively. Donor phase pH, ionic strength and extraction time were optimized for HF-LPME after PHWE. The optimum conditions were 2 h extraction at pH 1.5 without salt addition. Enrichment factors in the range of 947–1213 times were achieved (extraction recoveries were 23.6–30.3%) for HF-LPME after PHWE. The matrix effect on the ionization of drugs in LC–ESI-MS was also investigated. The results show that there is a smaller matrix effect (−8.9% to +14.6%) in comparison with other published values obtained using solid phase extraction (SPE) for clean-up after pressurized liquid extraction (PLE). Method detection limits (MDLs) and method quantification limits (MQLs) for different drugs were in the range of 0.4–3.7 ng g⁻¹ and 1.5–12.2 ng g⁻¹ in dried sludge samples, respectively. The characteristics of the proposed method were compared with those of other published works. The considerably lower ion suppression/enhancement and minimum use of organic solvents (a few microliters of di-n-hexyl ether) in the sample preparation step are two highlighted advantages of the proposed method in comparison with previously published works. The method was applied to determine NSAIDs in sewage sludge from Källby wastewater treatment plant (Lund, Sweden) in April, June, August and October 2010. The highest concentration level was recorded for ibuprofen in the April sewage sludge sample (588 ng g⁻¹) and all of the selected NSAIDs were detected in all the samples analyzed.     

Porphyrin analogs in bacterial photosynthesis

The electron transfer process in bacterial reaction centers is investigated. It is found that the side indole group Trp M252 in Rb sphaeroides (Trp M250 in Rps viridis) assists tunneling electron transfer by a distance of ∼14Å from pheophytin to quinone. Reported at the VIIIth International Conference on Spectroscopy of Porphyrins and Their Analogs, Minsk, September 22–26, 1998. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 4, pp. 496–500, July–August, 1999.