全文获取类型
收费全文 | 1062篇 |
免费 | 21篇 |
国内免费 | 3篇 |
专业分类
化学 | 639篇 |
晶体学 | 10篇 |
力学 | 16篇 |
数学 | 123篇 |
物理学 | 298篇 |
出版年
2020年 | 7篇 |
2019年 | 8篇 |
2017年 | 7篇 |
2016年 | 17篇 |
2015年 | 22篇 |
2014年 | 23篇 |
2013年 | 48篇 |
2012年 | 41篇 |
2011年 | 48篇 |
2010年 | 25篇 |
2009年 | 23篇 |
2008年 | 43篇 |
2007年 | 48篇 |
2006年 | 46篇 |
2005年 | 62篇 |
2004年 | 39篇 |
2003年 | 44篇 |
2002年 | 26篇 |
2001年 | 32篇 |
2000年 | 29篇 |
1999年 | 28篇 |
1998年 | 15篇 |
1997年 | 12篇 |
1996年 | 19篇 |
1995年 | 25篇 |
1994年 | 15篇 |
1993年 | 17篇 |
1992年 | 29篇 |
1991年 | 9篇 |
1990年 | 14篇 |
1989年 | 8篇 |
1988年 | 8篇 |
1987年 | 23篇 |
1986年 | 15篇 |
1985年 | 22篇 |
1984年 | 12篇 |
1983年 | 12篇 |
1982年 | 9篇 |
1981年 | 9篇 |
1980年 | 12篇 |
1979年 | 5篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 13篇 |
1975年 | 10篇 |
1974年 | 13篇 |
1973年 | 21篇 |
1972年 | 5篇 |
1970年 | 5篇 |
1969年 | 8篇 |
排序方式: 共有1086条查询结果,搜索用时 15 毫秒
991.
Bearden IG Beavis D Besliu C Blyakhman Y Brzychczyk J Budick B Bøggild H Chasman C Christensen CH Christiansen P Cibor J Debbe R Gaardhøje JJ Grotowski K Hagel K Hansen O Holm A Holme AK Ito H Jakobsen E Jipa A Jørdre JI Jundt F Jørgensen CE Keutgen T Kim EJ Kozik T Larsen TM Lee JH Lee YK Løvhøiden GL Majka Z Makeev A McBreen B Murray M Natowitz J Nielsen BS Olchanski K Olness J Ouerdane D Planeta R Rami F Röhrich D Samset BH Sanders SJ Sheetz RA Sosin Z Staszel P Thorsteinsen TF Tveter TS 《Physical review letters》2001,87(11):112305
Measurements, with the BRAHMS detector, of the antiproton-to-proton ratio at midrapidities and forward rapidities, are presented for Au+Au reactions at square root of [s(NN)] = 130 GeV, and for three different collision centralities. For collisions in the 0%-40% centrality range, we find N(&pmacr;)/N(p) = 0.64+/-0.04((stat))+/-0.06((syst)) at y approximately 0, 0.66+/-0.03+/-0.06 at y approximately 0.7, and 0.41+/-0.04+/-0.06 at y approximately 2. The ratios are found to be nearly independent of collision centrality and transverse momentum. The antiproton and proton rapidity densities vary differently with rapidity, and indicate a significant degree of collision transparency, although a net-baryon free midrapidity plateau (Bjorken limit) is not yet reached. 相似文献
992.
Bearden IG Beavis D Besliu C Budick B Bøggild H Chasman C Christensen CH Christiansen P Cibor J Debbe R Enger E Gaardhøje JJ Germinario M Hagel K Hansen O Holm A Holme AK Ito H Jipa A Jundt F Jørdre JI Jørgensen CE Karabowicz R Kim EJ Kozik T Larsen TM Lee JH Lee YK Løvhøiden G Majka Z Makeev A Mikelsen M Murray M Natowitz J Nielsen BS Norris J Olchanski K Ouerdane D Płaneta R Rami F Ristea C Röhrich D Samset BH Sandberg D Sanders SJ Scheetz RA Staszel P Tveter TS Videbaek F Wada R Yin Z 《Physical review letters》2004,93(10):102301
Transverse momentum spectra and rapidity densities, dN/dy, of protons, antiprotons, and net protons (p-p) from central (0%-5%) Au+Au collisions at square root of S(NN)=200 GeV were measured with the BRAHMS experiment within the rapidity range 0=y=3. The proton and antiproton dN/dy decrease from midrapidity to y=3. The net-proton yield is roughly constant for y<1 at dN/dy approximately 7, and increases to dN/dy approximately 12 at y approximately 3. The data show that collisions at this energy exhibit a high degree of transparency and that the linear scaling of rapidity loss with rapidity observed at lower energies is broken. The energy loss per participant nucleon is estimated to be 73+/-6 GeV. 相似文献
993.
994.
Dr. Dennis Larsen Prof. Dr. Sophie R. Beeren 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(48):11032-11038
Enzyme-mediated dynamic combinatorial chemistry combines the concept of thermodynamically controlled covalent self-assembly with the inherent biological relevance of enzymatic transformations. A system of interconverting cyclodextrins has been explored, in which the glycosidic linkage is rendered dynamic by the action of cyclodextrin glucanotransferase (CGTase). External factors, such as pH, temperature, solvent, and salinity are reported to modulate the composition of the dynamic cyclodextrin library. Dynamic libraries of cyclodextrins (CDs) could be obtained in wide ranges of pH (5.0–9.0), temperature (5–37 °C), and salinity (up to 7.5 m NaNO3), and with high organic solvent content (50 % by volume of ethanol), showing that enzyme-mediated dynamic systems can be robust and not limited to physiological conditions. Furthermore, it is demonstrated how strategic choice of reaction conditions can enhance template effects, in this case, to achieve highly selective production of α-CD, an otherwise challenging target due to competition from the structurally similar β-CD. 相似文献
995.
In yttrium iron garnet, Y3Fe5O12, the oxygen vacancy concentration at high temperatures depends on the partial oxygen pressure. Due to the electron donating nature of the vacancies, changes in the oxygen vacancy concentration can be measured by electrical conductivity measurements. We discuss a dynamic method for studying the diffusion of oxygen vacancies by measurements of the time dependence of the electrical conduction after a change in the oxygen partial pressure has taken place. It is shown that the interpretation of the measurements is straightforward if the relative change in conductivity remains small (? 10%). Measurements were performed on single crystals and on polycrystalline samples at temperatures 900–1400°C. The samples were made n-type by substitution with Si or p-type by substitution with Ca, Zn or Pb. The partial oxygen pressure was changed between 1 and 0.1 atm. For all samples the diffusion coefficient D of the oxygen vacancies can be represented by , where A = 8400 cm2s?1 and Q = 2.90 eV. It is shown that the activation energy of 2.90 eV is due to the migration enthalpy of the vacancies only. 相似文献
996.
Song W Woodworth JF Grassian VH Larsen SC 《Langmuir : the ACS journal of surfaces and colloids》2005,21(15):7009-7014
Nanocrystalline NaZSM-5 zeolites with systematically varied particle sizes (15, 60, and 200 nm) were functionalized with organosilanes. Through the systematic variation of particle size and therefore external surface area of NaZSM-5, the extent of functionalization and location of functional groups were spectroscopically verified. 29Si magic-angle spinning (MAS) NMR and Fourier transform infrared (FTIR) spectroscopy provided conclusive evidence that the silanol groups located on the external surface of NaZSM-5 were functionalized through reaction with the organosilanes. The 29Si NMR results provided quantitative information about the extent of functionalization on NaZSM-5. A nitroxide spin label was adsorbed on the external surface of NaZSM-5 to probe the surface properties by electron paramagnetic resonance (EPR) spectroscopy. The macroscopic and microscopic properties, such as the behavior of functionalized NaZSM-5 in different solvents, and the specific surface areas were also investigated. The hydrophobicity of the functionalized NaZSM-5 was found to increase relative to the parent NaZSM-5 as expected for an organic surface coating. 相似文献
997.
998.
The existence of large cyclodextrins, cyclic -D-(1 4) glucans with a degree of polymerisation higher than eight, has been proven during the past decade. A number of 4- -glucanotransferases have been shown to be able to produce large cyclodextrins consisting of up to several hundred glycosyl units, from both amylose and amylopectin. Large cyclodextrins with degree of polymerisation up to 31 have been isolated to purity by use of elaborate purification schemes, enabling studies of their structural and complex forming properties. The solid state structures of the large cyclodextrins with a degree of polymerisation 10, 14 and 26, respectively, have revealed interesting new structural features of this family of molecules. This review summarises the studies of the large cyclodextrins, a varied and highly interesting group of molecules. 相似文献
999.
Capillary electrophoresis frontal analysis was applied to 12 low molecular weight compounds including 8 drug substances displaying a range of different properties with respect to binding affinity, binding location, structure, lipophilicity, charge at physiological pH, and electrophoretic mobility. It was found that capillary electrophoresis frontal analysis can be used as a general method to study and quantify drug-human serum albumin interactions. The binding parameters obtained were consistent with literature values. Dextran was in some cases added to the run buffer to improve separation of the drug and human serum albumin plateau peaks. Results indicate that mobility differences between free and complexed human serum albumin give rise to only minor errors. Capillary electrophoresis frontal analysis was also found applicable to the study of human serum albumin drug displacement reactions. Low sensitivity of the UV-detection system was found to be the major limitation of capillary electrophoresis frontal analysis. The method is simple, and minimal effort has to be put into method development, which makes it well suited for screening in early drug development. 相似文献
1000.