Novel structurally characterized o-semiquinonato PCP-pincer nickel complexes

Structural study of dialkyl (PCP)-pincer o-semiquinonato nickel complexes indicated sloped relative positions of bi- and tri-dentate ligands. It became bright confirmation of propositions made on the base of their EPR spectra followed by molecular modelling.     

Study of the diffraction scattering 12C + 12C with the excitation of the 12C exotic state 0 2 + (the Hoyle state)

New results from a series of experiments dedicated to the study of the ¹²C exotic state (the so-called Hoyle state) are presented. In spite of the many investigations that have been carried out, the structure of this state (which lies above the threshold for breaking up into three alpha particles) is still unknown. The different models assume that the nucleus has an abnormally large size in this excited state. However, until recently, methods for measuring the radii of unbound states have not been suggested. The best way to solve this problem seems to be by measuring the angular distributions of elastic and inelastic scattering of ¹²C on different target nuclei, and the determination of the radii is based on the fact that, at small scattering angles, the cross sections for direct reactions at high enough energies behave like Frauenhofer diffraction on a black ball. Accordingly, an experiment was performed aimed at measuring the elastic and inelastic angular distributions of ¹²C with an energy of (121.5 ± 0.5) MeV on a ¹²C target. The elastic scattering was measured in the angular range from 18° to 50° in the c.m. system with uncertainty in the angle of measurement equal to Δθ = ± 0.6°. The inelastic cross section was measured for the ¹²C excited state 2⁺ (4.44 MeV) and 0⁺ (7.65 MeV). Estimates were made for the diffraction radii for the ground and excited states. An increase was observed in the radius of the state at 7.65 MeV compared to those of the ground and first excited states.     

Superelectrophilic activation of N-aryl amides of 3-arylpropynoic acids: synthesis of quinolin-2(1H)-one derivatives

The superelectrophilic activation of N-aryl amides of 3-arylpropynoic acids by Bronsted superacids (CF₃SO₃H, HSO₃F) or strong Lewis acids AlX₃ (X=Cl, Br) results in the formation of 4-aryl quinolin-2(1H)-ones in quantitative yields. The vinyl triflates or vinyl chlorides may be formed as additional reaction products. The investigated amides in reactions with benzene give 4,4-diaryl 3,4-dihydroquinolin-2-(1H)-ones under the superelectrophilic activation. 4-Aryl quinolin-2(1H)-ones in POCl₃ are converted into 4-aryl 2-chloroquinolines. 4-Fluorophenyl-4-phenyl 3,4-dihydroquinolin-2-(1H)-one give N-formylation products in a yield of 79% under the Vilsmeier–Haack reaction conditions.     

Two-level systems with relaxation

A method is presented for the coherent control of two-level systems when T2 relaxation is significant. The Bloch equations are rewritten as an equation of motion of the stereographic projection, Gamma, of the spin vector. This allows a Schur-type iteration used for the design of shaped pulses in magnetic resonance and coherent optics to be extended to include the effect of T2. In general, the effect of T2 on Gamma cannot be completely compensated for, although in practice it can be to a high degree. An example is presented of a driving field that produces a coherent superposition (no on-diagonal elements of the density matrix) over a chosen band of frequencies, in the presence of relaxation.     

Unusual self-assembled nanoaggregation of the thermally stable metal-free slipped-cofacial J-type phthalocyanine dimer

Nanoaggregation of the thermally stable bis(2-hydroxy-9(10),16(17),23(24)-tri-tert-butylphthalocyanine) of J-type was observed by the field emission scanning electron microscopy (FE-SEM). Ordered phases, represented as threads composed of about 200 nm diameter circles were discovered, unlike the parent dimeric magnesium complex, in which similar circles combine together to give visually distinguishable zones with widths of about 600 nm and the same distance between them.     

The reaction of tetrahydrochromeno[3,4-c]pyridines with activated alkynes. The first synthesis of tetrahydrochromeno[4,3-d]azocines

The first synthesis of tetrahydrochromeno[4,3-d]azocines via an alkyne-induced expansion reaction is described.     

Thermal behaviour of some new complexes with bismacrocyclic ligands as potential biological active species

Novel complexes of type [M₂LCl₄]·nH₂O ((1) M:Ni, n = 5; (2) M:Cu, n = 0 and (3) M:Zn, n = 2; L: ligand resulted from 1,2-phenylenediamine, 3,6-diazaoctane-1,8-diamine and formaldehyde template condensation) were synthesised and characterised. The features of complexes have been assigned from microanalytical, IR and UV–Vis data. The thermal analyses have evidenced the thermal intervals of stability and also the thermodynamic effects that accompany them. Processes as water or hydrochloric acid elimination as well as oxidative degradation of the organic ligand were observed. Complexes display a different thermal behaviour as result of dissimilar chemical interaction of metal ions with chloride anions. The final product of decomposition was metal(II) oxide as powder X-ray diffraction indicated.     

On a differential game in a nondamped distributed system

We study a differential game of approach in a system whose dynamics is described by a Sobolev‐type second‐order operator differential equation in Hilbert spaces. Solutions of the equation are represented by cosine and sine operator functions. To obtain solvability conditions of the game problem, we use support functionals of two sets, which defined by the behaviors of pursuer and evader. The results are applied to the investigation of conflicted‐controlled dynamics of bending waves in a rod.     

Rosin Derivatives as a Platform for the Antiviral Drug Design

The increased complexity due to the emergence and rapid spread of new viral infections prompts researchers to search for potential antiviral and protective agents for mucous membranes among various natural objects, for example, plant raw materials, their individual components, as well as the products of their chemical modification. Due to their structure, resin acids are valuable raw materials of natural origin to synthesize various bioactive substances. Therefore, the purpose of this study was to confirm the possibility of using resin acid derivatives for the drug design. As a result, we studied the cytotoxicity and biological activity of resin acid derivatives. It was shown that a slight decrease in the viral load in the supernatants was observed upon stimulation of cells (II) compared with the control. When using PASS-online modeling (Prediction of Activity Spectra for Substances), the prediction of the biological activity spectrum showed that compound (I) is capable of exhibiting antiviral activity against the influenza virus. The use of the SWISS-ADME webserver to reveal the drug-like properties of compounds did not directly indicate the presence of antiviral activity. These results indicate the potential of resin acid derivatives as a starting point for extensive research in the study of biological activity.